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The low-lying n(=3,4,5)d $^2D_{5/2}$ states alkaline earth ions are of vital importance in a number of different physical applications. The hyperfine structure constants of these states are characterized by unusually strong electron…

Atomic Physics · Physics 2015-06-26 B. K. Sahoo , C. Sur , T. Beier , B. P. Das , R. K. Chaudhuri , D. Mukherjee

We report the implementation of equation-of-motion coupled-cluster (EOMCC) method in the four-component relativistic framework with the spherical atomic potential to generate the excited states from a closed-shell atomic configuration. This…

Atomic Physics · Physics 2015-06-19 D. K. Nandy , Yashpal Singh , B. K. Sahoo

This work presents a first time accurate calculation of the magnetic dipole hyperfine structure constants for the ground state and some low-lying excited states of Pb$^+$. By comparing different levels of approximation with experimental…

Atomic Physics · Physics 2009-11-10 Bijaya K. Sahoo , Rajat K. Chaudhuri , B. P. Das , Holger Merlitz , Debashis Mukherjee

Ionization potentials, excitation energies, transition properties, and hyperfine structure constants of the low-lying $3p^6 3d^{9} \ ^2D_{5/2}$, $3p^6 3d^{9} \ ^2D_{3/2}$, $3p^5 3d^{10} \ ^2P_{3/2}$ and $3p^5 3d^{10} \ ^2P_{1/2}$ atomic…

Atomic Physics · Physics 2021-12-01 Dillip K. Nandy , B. K. Sahoo

This chapter discusses contemporary quantum chemical methods and provides general insights into modern electronic structure theory with a focus on heavy-element-containing compounds. We first give a short overview of relativistic…

Chemical Physics · Physics 2020-02-18 Aleksandra Leszczyk , Paweł Tecmer , Katharina Boguslawski

In this paper, we investigate the effects of full electronic correlation on the high harmonic generation in the helium atom subjected to laser pulses of extremely high intensity. To do this, we perform real-time propagations of the helium…

Chemical Physics · Physics 2022-05-18 Aleksander P. Woźniak , Michał Przybytek , Maciej Lewenstein , Robert Moszyński

We present systematic calculations of energy levels of the $1s^22l$ and $1s2l2l'$ states of ions along the lithium isoelectronic sequence from carbon till chlorine. The calculations are performed by using the…

Atomic Physics · Physics 2017-12-29 V. A. Yerokhin , A. Surzhykov , A. Müller

In this article, the molecular permanent electric dipole moments and components of static dipole polarizabilities for the electronic ground state of singly charged aluminum monohalides are reported. The coupled-cluster method by considering…

Atomic Physics · Physics 2024-06-18 Ankush Thakur , Renu Bala , H. S. Nataraj , V. S. Prasannaa

We numerically study models of $\mathrm{H}_2$ and $\mathrm{LiH}$ molecules, aligned collinearly with the linear polarization of the external field, to elucidate the possible role of correlation in the enhanced-ionization phenomena.…

Atomic Physics · Physics 2016-01-06 S. Chattopadhyay , S. Bauch , L. B. Madsen

We have investigated energies and spectroscopic properties such as lifetimes, $g_J$ factors, and hyperfine structure constants of the neutral atoms P through Mc belonging to Group-15, singly ionized atoms S$^+$ through Lv$^+$ of Group-16…

Atomic Physics · Physics 2023-06-29 H. X. Liu , Y. M. Yu , B. B. Suo , Y. Liu , B. K. Sahoo

We develop a time-dependent theory to investigate electron dynamics and photoionization processes of diatomic molecules interacting with strong laser fields including electron-electron correlation effects. We combine the recently formulated…

Chemical Physics · Physics 2016-02-02 Henrik R. Larsson , Sebastian Bauch , Lasse Kragh Sørensen , Michael Bonitz

We develop a theoretical method within the framework of relativistic many-body theory to accurately treat correlation corrections in atoms with few valence electrons. This method combines the all-order approach currently used in precision…

Atomic Physics · Physics 2009-09-01 M. S. Safronova , M. G. Kozlov , W. R. Johnson , Dansha Jiang

We use recently developed method of accurate atomic calculations which combines linearized single-double coupled cluster method with the configuration interaction technique to calculate ionisation potentials, excitation energies, static…

Atomic Physics · Physics 2017-02-01 V. A. Dzuba , V. V. Flambaum

The open-shell reference relativistic equation-of-motion coupled-cluster method within its four-component description is successfully implemented with the consideration of single- and double- excitation approximation. The one-body and…

Atomic Physics · Physics 2016-09-21 Himadri Pathak , Sudip Sasmal , Malaya K. Nayak , Nayana Vaval , Sourav Pal

Molecules and atomic highly charged ions provide powerful low-energy probes of the fundamental laws of physics: Polar molecules possess internal fields suitable to enhance fundamental symmetry violation by several orders of magnitudes,…

Excitation energies, term designations, and $g$-factors of Th, Th$^{+}$ and Th$^{2+}$ are determined using a relativistic hybrid configuration interaction (CI) + all-order approach that combines configuration interaction and linearized…

Atomic Physics · Physics 2015-06-22 M. S. Safronova , U. I. Safronova , Charles W. Clark

Here we investigate ground and metastable negative ion formation in low-energy electron collisions with the actinide atoms Th, Pa, U, Np and Pu through the elastic total cross sections (TCSs) calculations. For these atoms, the presence of…

Atomic Physics · Physics 2018-11-09 Z. Felfli , A. Z. Msezane

Using the complex scaling and the stabilization method combined with the stochastic variational approach, we have shown that there are narrow resonance states in two-dimensional three particle systems of electrons and holes interacting via…

Mesoscale and Nanoscale Physics · Physics 2020-07-01 Jun Jan , Kalman Varga

The electronic structures of several actinide solid systems are calculated using the self-interaction corrected local spin density approximation. Within this scheme the $5f$ electron manifold is considered to consist of both localized and…

Strongly Correlated Electrons · Physics 2007-05-23 L. Petit , A. Svane , Z. Szotek , W. M. Temmerman

The region surrounding the excitonic insulator phase is a three-component plasma composed of electrons, holes, and excitons. Due to the extended nature of the excitons, their presence influences the surrounding electrons and holes. We…

Strongly Correlated Electrons · Physics 2015-06-22 B Zenker , D Ihle , F X Bronold , H Fehske
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