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We describe mathematically the apparently paradoxical phenomenon that an electronic current in a semiconductor can flow because of collisions, and not despite them. A transport model of charge transport in a one-dimensional semiconductor…

Statistical Mechanics · Physics 2020-06-25 Luigi Barletti

The interaction of electrons with a periodic potential of atoms in crystalline solids gives rise to band structure. The band structure of existing materials can be measured by photoemission spectroscopy and accurately understood in terms of…

The band gap, a key concept in solid-state physics, is traditionally explained by the Bragg diffraction of electron waves in the periodic potential of a crystal. Although widely accepted, this framework raises fundamental issues in…

Materials Science · Physics 2025-08-28 Koichi Kajiyama

Natural optical activity is the paradigmatic example of an effect originating in the weak spatial inhomogeneity of the electromagnetic field on the atomic scale. In molecules, such effects are well described by the multipole theory of…

Materials Science · Physics 2023-05-31 Óscar Pozo , Ivo Souza

Koopmans-compliant functionals provide an orbital-density-dependent framework for an accurate evaluation of spectral properties; they are obtained by imposing a generalized piecewise-linearity condition on the total energy of the system…

Materials Science · Physics 2022-07-06 Riccardo De Gennaro , Nicola Colonna , Edward Linscott , Nicola Marzari

A central goal of condensed-matter physics is to understand how the diverse electronic and optical properties of crystalline materials emerge from the wavelike motion of electrons through periodically arranged atoms. However, more than 90…

Materials Science · Physics 2021-11-09 J. B. Costello , S. D. O'Hara , Q. Wu , D. C. Valovcin , L. N. Pfeiffer , K. W. West , M. S. Sherwin

Defects determine many important properties and applications of materials, ranging from doping in semiconductors, to conductivity in mixed ionic-electronic conductors used in batteries, to active sites in catalysts. The theoretical…

Materials Science · Physics 2024-04-17 Irea Mosquera-Lois , Seán R. Kavanagh , Johan Klarbring , Kasper Tolborg , Aron Walsh

A space-time crystal is defined as a quantum mechanical system with both spatial and temporal periodicity. Such a system can be described by the Floquet-Bloch (FB) theory. We first formulate a semiclassical theory by constructing a…

Mesoscale and Nanoscale Physics · Physics 2023-01-02 Qiang Gao , Qian Niu

We use semiconductors as an example to show that quantum chaos manifests itself in the energy spectrum of crystals. We analyze the {\it ab initio} band structure of silicon and the tight-binding spectrum of the alloy $Al_xGa_{1-x}As$, and…

Condensed Matter · Physics 2009-10-22 E. R. Mucciolo , R. B. Capaz , B. L. Altshuler , J. D. Joannopoulos

We develop a quantum mechanical theory to describe the optical response of semiconductor nanostructures with a particular emphasis on higher-order harmonic Generation. Based on a tight-binding approach we take all two-particle correlations…

Optics · Physics 2023-01-04 Ulf Peschel , Thomas Lettau , Stefanie Gräfe , Kurt Busch

I present a theory of electron dynamics in semiconductors with slowly varying composition. I show that the frequency-dependent conductivity, required for the description of transport and optical properties, can be obtained from a knowledge…

Condensed Matter · Physics 2016-08-31 Michael R. Geller

Band theory provides the foundation for understanding electronic structure in crystalline materials, but its reliance on exact translational symmetry limits its applicability to systems with defects, disorder, incommensurate modulations, or…

Materials Science · Physics 2026-05-08 Christopher A. Bairnsfather , Ralph M. Kaufmann , Terry A. Loring , Alexander Cerjan

In solid state physics, it is an unsaid (tacit) assumption that the Bloch theorem is applicable to a crystal lattice even if it is of the macroscopic dimensions, provided periodicity is maintained. However, in a realistic situation,…

Quantum Physics · Physics 2025-08-28 Navinder Singh

The semi-classical Bloch-Boltzmann theory is at the heart of our understanding of conduction in solids, ranging from metals to semi-conductors. Physical systems that are beyond the range of applicability of this theory are thus of…

Materials Science · Physics 2009-04-10 G. Trambly de Laissardière , J. P. Julien , D. Mayou

The homogeneous electron gas is a cornerstone of quantum condensed matter physics, providing the foundation for developing density functional theory and understanding electronic phases in semiconductors. However, theoretical understanding…

Strongly Correlated Electrons · Physics 2025-12-12 Filippo Gaggioli , Pierre-Antoine Graham , Liang Fu

The semi-classical Bloch-Boltzmann theory is at the heart of our understanding of conduction in solids, ranging from metals to semi-conductors. Physical systems that are beyond the range of applicability of this theory are thus of…

Materials Science · Physics 2007-12-18 Didier Mayou , Guy Trambly De Laissardière

Analytic representation formulas and power series are developed describing the band structure inside non-magnetic periodic photonic three-dimensional crystals made from high dielectric contrast inclusions. Central to this approach is the…

Analysis of PDEs · Mathematics 2021-10-26 Robert Lipton , Robert Viator , Silvia Jimenez Bolanos , Abiti Adili

Quantum embedding theories are promising approaches to investigate strongly-correlated electronic states of active regions of large-scale molecular or condensed systems. Notable examples are spin defects in semiconductors and insulators. We…

Materials Science · Physics 2021-12-14 He Ma , Nan Sheng , Marco Govoni , Giulia Galli

In this paper we solve the Cattaneo-Vernotte Equation for a periodic heterostructure made of alternate layers of different materials. The solutions describe thermal waves traveling in a periodic system, and it allows us to introduce the…

Mesoscale and Nanoscale Physics · Physics 2020-10-13 A. Camacho de la Rosa , D. Becerril , G. Gómez-Farfán , R. Esquivel-Sirvent

Quasicrystals remain among the most intriguing materials in physics and chemistry. Their structure results in many unusual properties including anomalously low friction as well as poor electrical and thermal conductivity but it also…

Quantum Gases · Physics 2020-05-01 Guido Pupillo , Primoz Ziherl , Fabio Cinti
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