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Herbertsmithite, ZnCu3(OH)6Cl2, is the prototype candidate for a spin liquid behavior on a geometrically perfect kagome lattice. Its discovery and the absence of any evidence for spin-freezing down to the lowest probed temperature to-date…

Strongly Correlated Electrons · Physics 2015-05-28 P. Mendels , F. Bert

Nearest-neighbor interacting S = 1/2 spins on the ideal Kagom\'{e} lattice are predicted to form a variety of novel quantum entangled states, including quantum spin-liquid (SL) and valence bond solid (VBS) phases. In real materials, the…

Strongly Correlated Electrons · Physics 2019-10-31 N. J. Laurita , A. Ron , J. W. Han , A. Scheie , J. P. Sheckelton , R. W. Smaha , W. He , J. -J. Wen , J. S. Lee , Y. S. Lee , M. R. Norman , D. Hsieh

Frustrated magnetism on the kagome lattice has been a fertile ground for rich and fascinating physics, ranging from experimental evidence of a spin liquid to theoretical predictions of exotic superconductivity. Among experimentally realized…

Strongly Correlated Electrons · Physics 2015-12-16 Yasir Iqbal , Harald O. Jeschke , Johannes Reuther , Roser Valentí , I. I. Mazin , Martin Greiter , Ronny Thomale

Neutron scattering measurements have been performed on deuterated powder samples of claringbullite and Zn-doped claringbullite (Zn$_x$Cu$_{4-x}$(OD)$_{6}$FCl). At low temperatures, claringbullite Cu$_4$(OD)$_{6}$FCl forms a distorted…

Strongly Correlated Electrons · Physics 2023-01-26 M. Georgopoulou , B. Fåk , D. Boldrin , J. R. Stewart , C. Ritter , E. Suard , J. Ollivier , A. S. Wills

Barlowite Cu$_4$(OH)$_6$FBr shows three-dimensional (3D) long-range antiferromagnetism, which is fully suppressed in Cu$_3$Zn(OH)$_6$FBr with a kagome quantum spin liquid ground state. Here we report systematic studies on the evolution of…

Materials with a perfect kagome lattice structure of magnetic ions are intensively sought for, because they may exhibit exotic ground states like the a quantum spin liquid phase. Barlowite is a natural mineral that features perfect kagome…

Strongly Correlated Electrons · Physics 2016-09-22 Daniel Guterding , Roser Valenti , Harald O. Jeschke

The most recent discovery, the Cu-doped lead apatite LK-99, is a proposed room-temperature superconductor operating under ambient pressure. However, this discovery has brought a slew of conflicting results from different scientific groups.…

Superconductivity · Physics 2023-09-18 Jun Li , Qi An

Quantum spin liquids attract great interest due to their exceptional magnetic properties characterized by the absence of long-range order down to low temperatures despite the strong magnetic interaction. Commonly, these compounds are…

Strongly Correlated Electrons · Physics 2018-05-01 Martin Dressel , Andrej Pustogow

Spin-$1/2$ kagome antiferromagnets are leading candidates for realizing quantum spin liquid (QSL) ground states. While QSL ground states are predicted for the pure Heisenberg model, understanding the robustness of the QSL to additional…

Strongly Correlated Electrons · Physics 2026-02-16 Shengtao Jiang , Arthur C. Campello , Wei He , Jiajia Wen , Daniel M. Pajerowski , Young S. Lee , Hong-Chen Jiang

Recently Han et al. have provided an analysis of the observed behavior of $\rm ZnCu_{3}(OH)_6Cl_2$ Herbertsmithite based on a separation of the contributions to its thermodynamic properties due to impurities from those due to the kagome…

Strongly Correlated Electrons · Physics 2016-09-20 V. R. Shaginyan , M. Ya. Amusia , J. W. Clark , G. S. Japaridze , A. Z. Msezane , K. G. Popov

A quantum spin liquid (QSL) is an exotic quantum state of matter characterized by fluctuating spins which may exhibit long-range entanglement. Among the possible host candidates for a QSL ground state, the $S$=1/2 kagome lattice…

Iridates are characterized by a fascinating interplay of spin-orbit and electron-electron interactions. The honeycomb-lattice materials A2IrO3 (A=Na,Li) have been proposed to realize pseudospin-1/2 Mott insulating states with strongly…

Strongly Correlated Electrons · Physics 2014-11-11 Eric C. Andrade , Matthias Vojta

The structural-magnetic models of 25 AFM kagome cuprates similar to herbertsmithite (ZnCu3(OH)6Cl2) - a perspective spin liquid - have been calculated and analyzed. Main correlations between the structure and magnetic properties of these…

Materials Science · Physics 2021-08-13 L. M. Volkova , D. V. Marinin

We investigate the structural, electronic and magnetic properties of the newly synthesized mineral barlowite Cu4(OH)6FBr which contains Cu2+ ions in a perfect kagome arrangement. In contrast to the spin-liquid candidate herbertsmithite…

The kagome Heisenberg antiferromagnet is a leading candidate in the search for a spin system with a quantum spin-liquid ground state. The nature of its ground state remains a matter of great debate. We conducted 17-O single crystal NMR…

Strongly Correlated Electrons · Physics 2015-11-09 M. Fu , T. Imai , T. -H. Han , Y. S. Lee

It has long been believed that doped quantum spin liquids (QSLs) can give rise to fascinating quantum phases, including the possibility of high-temperature superconductivity (SC) as proposed by P. W. Anderson's resonating valence bond (RVB)…

Strongly Correlated Electrons · Physics 2024-04-09 Zheng-Tao Xu , Zheng-Cheng Gu , Shuo Yang

Doping lithium-ion battery electrode materials LiMO$_2$ (M = Co, Ni, Mn) with impurities has been shown to be an effective way to optimize their electrochemical properties. Here, we report a detailed first-principles study of layered oxides…

Materials Science · Physics 2017-12-07 Khang Hoang

Synthetic barlowite, Cu4(OH)6BrF, has emerged as a new quantum spin liquid (QSL) host, containing kagome layers of S=1/2 Cu2+ ions separated by interlayer Cu2+ ions. Similar to synthetic herbertsmithite, ZnCu3(OH)6Cl2, it has been reported…

Strongly Correlated Electrons · Physics 2018-05-02 C. M. Pasco , B. A. Trump , Thao T. Tran , Z. A. Kelly , C. Hoffmann , I. Heinmaa , R. Stern , T. M. McQueen

We study the effects of doping a Mott insulator on the honeycomb lattice where spins interact via direction dependent Kitaev couplings J_K, and weak antiferromagnetic Heisenberg couplings J. This model is known to have a spin liquid ground…

Strongly Correlated Electrons · Physics 2012-08-30 Yi-Zhuang You , Itamar Kimchi , Ashvin Vishwanath

We employ real-space variational quantum Monte Carlo methods with resonating valence bond many-body wave functions to investigate electron correlation effects in the Kagome system $Zn_xCu_{4-x}O_6$. Using three trial wave functions of the…

Strongly Correlated Electrons · Physics 2025-11-07 Sam Azadi , Kühne