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We compute molecular continuum orbitals in the single center expansion scheme. We then employ these orbitals to obtain molecular Auger rates and single-photon ionization cross sections to study the interaction of N2 with Free-Electron-Laser…

Atomic Physics · Physics 2017-10-11 H. I. B. Banks , D. A. Little , J. Tennyson , A. Emmanouilidou

We study the interaction of a heteronuclear diatomic molecule, carbon monoxide, with a free-electron laser (FEL) pulse. We compute the ion yields and the intermediate states by which the ion yields are populated. We do so using rate…

Atomic Physics · Physics 2020-12-02 Henry I B Banks , Antonis Hadjipittas , Agapi Emmanouilidou

We propose an imaging technique to follow core-hole wave-packet oscillations in the nitrogen molecule. In this scheme, an attosecond x-ray pulse core-ionizes the nitrogen molecule and a subsequent attosecond x-ray pulse probes the evolution…

Chemical Physics · Physics 2019-08-15 Ludger Inhester , Loren Greenman , Artem Rudenko , Daniel Rolles , Robin Santra

We investigate the creation of double K-shell holes in N2 molecules via sequential absorption of two photons on a timescale shorter than the core-hole lifetime by using intense x-ray pulses from the Linac Coherent Light Source free electron…

We present the implementation of an electronic-structure approach dedicated to ionization dynamics of molecules interacting with x-ray free-electron laser (XFEL) pulses. In our scheme, molecular orbitals for molecular core-hole states are…

Chemical Physics · Physics 2015-05-18 Yajiang Hao , Ludger Inhester , Kota Hanasaki , Sang-Kil Son , Robin Santra

Understanding the interaction of intense, femtosecond X-ray pulses with heavy atoms is crucial for gaining insights into the structure and dynamics of matter. One key aspect of nonlinear light-matter interaction was, so far, not studied…

We experimentally investigate generation of molecular nitrogen-ion lasers with two femtosecond laser pulses at different wavelengths. The first pulse serves as the pump which ionizes the nitrogen molecules and excites the molecular ions to…

We investigate molecular dynamics of multiple ionization in N2 through multiple core-level photoabsorption and subsequent Auger decay processes induced by intense, short X-ray free electron laser pulses. The timing dynamics of the…

We explore the formation by Free-Electron-Laser radiation of Ar hollow states with two or three inner-shell holes. We find that even charged Ar ion states can be more populated than odd charged Ar ion states. This depends on the pulse…

Atomic Physics · Physics 2015-02-04 A. O. G. Wallis , H. Banks , A. Emmanouilidou

We study theoretically the quantum dynamics of nitrogen molecules (N$_2$) exposed to intense and ultrafast x-rays at a wavelength of 1.1 nm (1100 eV photon energy) from the Linac Coherent Light Source (LCLS) free electron laser. Molecular…

We study the ultrafast dynamics initiated by a coherent superposition of core-excited states of nitrous oxide molecule. Using high-level \textit{ab-initio} methods, we show that the decoherence caused by the electronic decay and the nuclear…

Intense few-to-sub-femtosecond soft x-ray pulses can produce neutral, two-site excited double-core-hole states by promoting two core electrons to the same unoccupied molecular orbital. We theoretically investigate double nitrogen K-edge…

Chemical Physics · Physics 2023-06-28 Adam E. A. Fouda , Dimitris Koulentianos , Linda Young , Gilles Doumy , Phay J. Ho

Results of the most sophisticated measurements in coincidence of the angular resolved K-shell photo- and Auger-electrons, and of two atomic ions produced by dissociation of N2 molecule, are analyzed. Detection of photoelectrons at certain…

X-ray assisted nuclear excitation by electron capture (NEEC) into inner-shell atomic holes in a plasma environment generated by strong optical lasers is investigated theoretically. The considered scenario involves the interaction of a…

Plasma Physics · Physics 2019-12-18 Yuanbin Wu , Christoph H. Keitel , Adriana Pálffy

To exploit the high intensity of laser radiation, we propose to select frequencies at which single-photon absorption is of too low energy and two or more photons are needed to produce states of an atom that can undergo interatomic Coulombic…

Atomic and Molecular Clusters · Physics 2012-01-04 Philipp V. Demekhin , Spas D. Stoychev , Alexander I. Kuleff , Lorenz S. Cederbaum

Molecular rotational spectroscopy based on strong-field-ionization-induced nitrogen laser is employed to investigate the time evolution of the rotational wave packet composed by a coherent superposition of quantum rotational states created…

We theoretically examine neon atoms in ultrashort and intense x rays from free electron lasers and compare our results with data from experiments conducted at the Linac Coherent Light Source (LCLS). For this purpose, we treat in detail the…

Correlation-function expressions are derived for the coherent nonlinear response of molecules to three resonant ultrafast pulses in the x-ray regime. The ability to create two-core-hole states with controlled attosecond timing in…

Strongly Correlated Electrons · Physics 2009-11-11 Shaul Mukamel

We explore the interactions between Argon and extreme ultraviolet (XUV) laser pulses across photon energies of 200 eV, 260 eV, and 315 eV, scrutinizing the influence of photon energy on Argon ion yields and unraveling the associated…

Atomic Physics · Physics 2024-04-15 Linhao Xiong
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