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Graphene modifications with oxygen or hydrogen are well known in contrast to carbon attachment to the graphene lattice. The chemical modification of graphene sheets with aromatic diazonium ions (carbon attachment) is analyzed by confocal…

Materials Science · Physics 2010-06-23 Fabian M. Koehler , Arnhild Jacobsen , Klaus Ensslin , Christoph Stampfer , Wendelin J. Stark

We synthesize large-area graphene via atmospheric-pressure (AP) chemical vapor deposition (CVD) on copper, and transfer to SiO2 wafers. In contrast to low-pressure (LP) CVD on copper, optical contrast and atomic force microscopy…

Materials Science · Physics 2011-07-15 Daniel R. Lenski , Michael S. Fuhrer

The generation of nanoscale square and stripe patterns is of major technological importance since they are compatible with industry-standard electronic circuitry. Recently, a blend of diblock copolymer interacting via hydrogen-bonding was…

Soft Condensed Matter · Physics 2009-11-13 Carlos I. Mendoza , Erasmo Batta

The development of novel sub-nanometer clusters (SNCs) catalysts with superior catalytic performance depends on the precise control of clusters' atomistic sizes, shapes, and accurate deposition onto surfaces. The intrinsic complexity of the…

Materials Science · Physics 2024-11-06 Yao Wei , Alejandro Santana-Bonilla , Lev Kantorovich

We report on a large improvement in the wetting of Al2O3 thin films grown by un-seeded atomic layer deposition on monolayer graphene, without creating point defects. This enhanced wetting is achieved by greatly increasing the nucleation…

Materials Science · Physics 2014-11-14 Bruno Dlubak , Piran R. Kidambi , Robert S. Weatherup , Stephan Hofmann , John Robertson

Here we develop a class off face centred cubic structure of metallic silver nanocrystals, to enable high ORR activity process. Silver nanoparticles deposited within different carbon supports: carboxylated-graphene, SiO2-doted reduced-…

Non-planar aromatic molecules are interesting systems for organic electronics and optoelectronics applications due to their high stability and electronic properties. By using scanning tunneling microscopy and spectroscopy, we investigated…

Controlled atomic scale fabrication of functional devices is one of the holy grails of nanotechnology. The most promising class of techniques that enable deterministic nanodevice fabrication are based on scanning probe patterning or surface…

We demonstrate a new technique for creating unique forms of pure sp2-bonded carbon and unprecedented hetero-molecules. These new structures, which we refer to as sculpturenes, are formed by sculpting selected shapes from bilayer graphene,…

Materials Science · Physics 2015-12-02 L. Algharagholy , S. Bailey , T. Pope , C. J. Lambert

Direct growth of flat micrometer-sized bilayer graphene islands in between molybdenum disulfide sheets is achieved by chemical vapor deposition of ethylene at about 800 {\deg}C. The temperature assisted decomposition of ethylene takes place…

We develop two new amphiphilic molecules that are shown to act as efficient surfactants for carbon nanotubes in non-polar organic solvents. The active conjugated groups, which are highly attracted to graphene nanotube surface, are based on…

Materials Science · Physics 2009-07-21 Y. Ji , Y. Y. Huang , A. R. Tajbakhsh , E. M. Terentjev

It is far well accepted that the morphology of nanoparticles and nanoalloys is of paramount importance to understand their properties. Furthemore, the morphology depends on the growth mechanism with coalescence generally accepted as one the…

Mesoscale and Nanoscale Physics · Physics 2023-07-27 Sofia Zinzani , Francesca Baletto

Metal nano-aerogels combine a large surface area, a high structural stability, and a high catalytic activity towards a variety of chemical reactions. The performance of such nanostructures is underpinned by the atomic-level distribution of…

Monolithic structures can be built into graphene by the addition and subsequent re-arrangement of carbon atoms. To this end, ad-dimers of carbon are a particularly attractive building block because a number of emerging technologies offer…

Materials Science · Physics 2010-09-09 Mark T. Lusk , L. D. Carr

Density functional theory modelling of the reduction of realistic nanographene molecules (C42H18, C48H18 and C60H24) by molecular hydrogen evidences for the presence of limits in the hydrogenation process. These limits caused the…

Materials Science · Physics 2011-11-08 D. W. Boukhvalov , X. Feng , K. Müllen

We use ab initio density functional calculations to study the chemical functionalization of single-wall carbon nanotubes and graphene monolayers by silyl (SiH3) radicals and hydrogen. We find that silyl radicals form strong covalent bonds…

Materials Science · Physics 2009-11-13 Kiseok Chang , Savas Berber , David Tomanek

The quantum-mechanochemical-reaction-coordinate simulations have been performed to investigate the mechanical properties of hydrogen functionalized graphene. The simulations disclosed atomically matched peculiarities that accompany the…

Materials Science · Physics 2011-08-22 N. A. Popova , E. F. Sheka

Emergence of $\pi$-magnetism in open-shell nanographenes has been theoretically predicted decades ago but their experimental characterization was elusive due to the strong chemical reactivity that makes their synthesis and stabilization…

Mesoscale and Nanoscale Physics · Physics 2022-09-07 Dimas G. de Oteyza , Thomas Frederiksen

Thermal decomposition of silicon carbide is a promising approach for the fabrication of graphene. However, the atomistic growth mechanism of graphene remains unclear. This paper describes the development of a new charge-transfer interatomic…

Materials Science · Physics 2018-03-13 So Takamoto , Takahiro Yamasaki , Jun Nara , Takahisa Ohno , Chioko Kaneta , Asuka Hatano , Satoshi Izumi

Lubricants can affect quasicrystalline coatings surfaces by modifying commensurability of the interfaces. We report results of the first computer simulation studies of physically adsorbed hydrocarbons on a quasicrystalline surface: methane,…

Materials Science · Physics 2014-12-24 Wahyu Setyawan , Renee D. Diehl , Stefano Curtarolo
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