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The increasing sensitivity and resolution of ground-based telescopes have enabled the detection of gas-phase complex organic molecules (COMs) across a variety of environments. Many of the detected species are expected to form on the icy…

Astrophysics of Galaxies · Physics 2022-09-14 Marina G. Rachid , Will Rocha , Harold Linnartz

Context. Infrared spectroscopy of star and planet forming regions is at the dawn of a new age with the upcoming James Webb Space Telescope. In support of these observations, laboratory spectra are required to identify complex organic…

Despite the organic molecule inventory detected in Orion KL, acetaldehyde (CH3CHO) -- one of the most ubiquitous interstellar aldehydes -- has not been firmly identified with mm-wave interferometry. We analyze extensive ALMA archival…

Deuterium fractionation is highly efficient during the early stages of star formation, particularly in starless and prestellar cores where temperatures are low (<10 K) and molecular freeze-out onto dust grains is significant. Methanol forms…

The destiny of complex organic molecules (COMs) in star-forming regions is interlinked with various evolutionary phases. Therefore, identifying these species in diversified environments of identical star-forming regions would help to…

Cold gas-phase water has recently been detected in a cold dark cloud, Barnard 5 located in the Perseus complex, by targeting methanol peaks as signposts for ice mantle evaporation. Observed morphology and abundances of methanol and water…

Astrophysics of Galaxies · Physics 2017-11-08 Vianney Taquet , Eva Wirström , Steven B. Charnley , Alexandre Faure , Ana López-Sepulcre , Carina M. Persson

Complex Organic Molecules (COMs) have been detected in the interstellar medium (ISM). However, it is not clear whether their synthesis occurs on the icy surfaces of interstellar grains or via a series of gas-phase reactions. As a test case…

Earth and Planetary Astrophysics · Physics 2016-03-31 Joan Enrique-Romero , Albert Rimola , Cecilia Ceccarelli , Nadia Balucani

The formation of complex organic molecules (COMs) in protostellar environments is a hotly debated topic. In particular, the relative importance of the gas phase processes as compared to a direct formation of COMs on the dust grain surfaces…

Earth and Planetary Astrophysics · Physics 2015-06-23 C. Codella , F. Fontani , C. Ceccarelli , L. Podio , S. Viti , R. Bachiller , M. Benedettini , B. Lefloch

Methanol (CH$_{3}$OH) is a key complex organic molecule (COM) in the interstellar medium, widely used as a tracer of dense gas and hot molecular cores (HMCs). Using high-resolution ALMA observations from the ATOMS survey, we investigate the…

Methanol ice is embedded in interstellar ice mantles present in dense molecular clouds. We aim to measure the sputtering efficiencies starting from different ice mantles of varying compositions experimentally, in order to evaluate their…

Astrophysics of Galaxies · Physics 2020-02-19 E. Dartois , M. Chabot , A. Bacmann , P. Boduch , A. Domaracka , H. Rothard

The occurrence of complex organic molecules (COMs) in the gas phase at low temperature in the dense phases of the ISM suggests that a non-thermal desorption mechanism is at work because otherwise, COMs should condense within a short…

Astrophysics of Galaxies · Physics 2019-07-17 E. Dartois , M. Chabot , T. Id Barkach , H. Rothard , B. Augé , A. N. Agnihotri , A. Domaracka , P. Boduch

The complex organic molecules (COMs) detected in star-forming regions are the precursors of the prebiotic molecules that can lead to the emergence of life. By studying COMs in more evolved protoplanetary disks we can gain a better…

Earth and Planetary Astrophysics · Physics 2022-03-08 Nashanty G. C. Brunken , Alice S. Booth , Margot Leemker , Pooneh Nazari , Nienke van der Marel , Ewine F. van Dishoeck

Infrared spectroscopic observations have established the presence of hydrocarbon ices on Pluto and other TNOs, but the abundances of such molecules cannot be deduced without accurate optical constants (n, k) and reference spectra. In this…

Instrumentation and Methods for Astrophysics · Physics 2015-02-10 R. L. Hudson , P. A. Gerakines , M. H. Moore

The abundances of deuterated molecules with respect to their main isotopologue counterparts have been determined to be orders of magnitude higher than expected from the cosmic abundance of deuterium relative to hydrogen. The increasing…

Astrophysics of Galaxies · Physics 2023-03-01 J. Ferrer Asensio , S. Spezzano , L. H. Coudert , V. Lattanzi , C. P. Endres , J. K. Jørgensen , P. Caselli

Complex Organic Molecules (COMs) are considered crucial molecules, since they are connected with organic chemistry, at the basis of the terrestrial life. More pragmatically, they are molecules in principle difficult to synthetize in the…

Solar and Stellar Astrophysics · Physics 2015-06-22 Ali A. Jaber , C. Ceccarelli , C. Kahane , E. Caux

The simultaneous detection of organic molecules of the form C$_2$H$_{\text{n}}$O, such as ketene (CH$_2$CO), acetaldehyde (CH$_3$CHO), and ethanol (CH$_3$CH$_2$OH), toward early star-forming regions offers hints of shared chemical history.…

Astrophysics of Galaxies · Physics 2021-06-16 K. -J. Chuang , G. Fedoseev , C. Scirè , G. A. Baratta , C. Jäger , Th. Henning , H. Linnartz , M. E. Palumbo

Acetic acid (CH3COOH) was detected in the gas toward interstellar clouds, hot cores, protostars and comets. Its formation in ice mantles was proposed and acetic acid awaits detection in the infrared spectra of the ice as most other COMs…

Instrumentation and Methods for Astrophysics · Physics 2023-12-05 C. del Burgo Olivares , H. Carrascosa , B. Escribano , G. M. Muñoz Caro , R. Martín-Doménech

Context: HCOOH is one of the more common species in interstellar ices with abundances of 1-5% with respect to solid H2O. Aims: This study aims at characterizing the HCOOH spectral features in astrophysically relevant ice mixtures in order…

Astrophysics · Physics 2009-11-13 S. E. Bisschop , G. W. Fuchs , A. C. A. Boogert , E. F. van Dishoeck , H. Linnartz

Context. The molecular composition of interstellar ice mantles is defined by gas-grain processes in molecular clouds, with the main components being $H_2O$, $CO$, and $CO_2$. $CH_3OH$ ice is detected towards the denser regions, where large…

Astrophysics of Galaxies · Physics 2021-08-25 B. Müller , B. M. Giuliano , M. Goto , P. Caselli

We present the first census of the interstellar Complex Organic Molecules (iCOMs) in the low-mass Class I protostar SVS13-A, obtained by analysing data from the IRAM-30m Large Project ASAI (Astrochemical Surveys At IRAM). They consist of an…

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