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Structural rearrangement of polystyrene colloidal crystals under dry sintering conditions has been revealed by in situ grazing incidence X-ray scattering. Measured diffraction patterns were analysed using distorted wave Born approximation…

The advances in new technologies have prompted the need for functional systems smaller than the gyration radius of polymer chains. Thus, understanding how nanoconfinement affects polymer properties has been the focus of a lot of research…

Soft Condensed Matter · Physics 2010-07-27 Fabrice Cousin , Jérémie Gummel , Daniel Clemens , Isabelle Grillo , François Boué

We investigate by scattering techniques the structure of water-based soft composite materials comprising a crystal made of Pluronic block-copolymer micelles arranged in a face-centered cubic lattice and a small amount (at most 2% by volume)…

Soft Condensed Matter · Physics 2012-06-07 Elisa Tamborini , Neda Ghofraniha , Julian Oberdisse , Luca Cipelletti , Laurence Ramos

Ferroelectric glass-ceramics are promising composite materials with dual properties, of high dielectric permittivity and high dielectric breakdown strength. In this context, new phosphate glass-ceramics 2BaO-0.5Na2O 2.5[(1-x)Nb2O5…

Small-Angle Scattering (SAS) investigates structures in samples that generally range from approximately 0.5 nm to a few 100 nm. This can both be done for isotropic samples such as blends and liquids, as well as anisotropic samples such as…

Instrumentation and Detectors · Physics 2023-09-22 Sebastian Jaksch

We examine nanoparticles (NPs) forming polyhedral sections of the ideal cubic lattice, simple (sc), body centered (bcc), and face centered (fcc) cubic, which are confined by facets characterized by densest and second densest {h k l}…

Mesoscale and Nanoscale Physics · Physics 2021-01-13 Klaus E. Hermann

Nickel oxide nanoparticles of different sizes are prepared and characterized by x-ray diffraction and transmission electron microscopy. A.C. susceptibility measurements as a function of temperature are carried out for various particle sizes…

Soft Condensed Matter · Physics 2007-05-23 S. D. Tiwari , K. P. Rajeev

We are presenting a new method of processing polystyrene-silica nanocomposites, which results in a very well-defined dispersion of small primary aggregates (assembly of 15 nanoparticles of 10 nm diameter) in the matrix. The process is based…

Materials Science · Physics 2009-04-02 Nicolas Jouault , Perrine Vallat , Florent Dalmas , Sylvère Said , Jacques Jestin , François Boué

We demonstrate a remarkable equivalence in structure measured by total X-ray scattering methods between very small metallic nanoparticles and bulk metallic glasses (BMGs), thus connecting two disparate fields, shedding new light on both.…

This work reports aspect related to chemical capping synthesis of nano-sized particles of nickel oxide. It is a simple, novel and cost effective method. The average particle size, specific surface area, crystallinity index are estimated…

Chemical Physics · Physics 2014-02-04 M. Nowsath rifaya , T. Theivasanthi , M. Alagar

Single-crystal nanoparticles of silicon, several tens of nm in diameter, may be suitable as building blocks for single-nanoparticle electronic devices. Previous studies of nanoparticles produced in low-pressure plasmas have demonstrated the…

We present a laboratory study of silicate glasses of astrophysically relevant compositions including olivines, pyroxenes and melilites. With emphasis on the classic Si-O stretching feature near 10 microns, we compare infrared spectra of our…

Instrumentation and Methods for Astrophysics · Physics 2015-05-30 Angela K. Speck , Alan G. Whittington , Anne. M. Hofmeister

Transparent SrO-0.5Li2O-4.5B2O3 (SLBO) and BaO-0.5Na2O-4.5B2O3 (BNBO) glasses were fabricated via the conventional melt-quenching technique. The amorphous and glassy characteristics of the as-quenched samples were respectively confirmed by…

Materials Science · Physics 2010-07-13 Rahul Vaish , Vincent Rodriguez , Mario Maglione , J. Etourneau , K. B. R. Varma

Small angle neutron and x-ray scattering methods are used to investigate the structure of dilute suspensions of two different ferrofluid systems dispersed in soft polyacrylamide hydrogels. It is found that the particles in the fluid are…

Using molecular dynamics simulations we investigate the dependence of the structural and vibrational properties of the surfaces of sodo-silicate glasses on the sodium content as well as the nature of the surface. Two types of glass surfaces…

Disordered Systems and Neural Networks · Physics 2020-10-28 Zhen Zhang , Simona Ispas , Walter Kob

The quantum dots of semiconductor display novel and interesting phenomena that have not been in the bulk material. The color tunability is one of the most attractive characteristics in II-VI semiconductor nanoparticles such as CdS, ZnS,…

General Physics · Physics 2012-04-05 M. Alagar , T. Theivasanthi , A. Kubera Raja

Semiconducting nanoparticles are the building blocks of optical nanodevices as their electronic states, and therefore light absorption and emission, can be controlled by modifying their size and shape. CdSe is perhaps the most studied of…

Materials Science · Physics 2015-06-25 Silvana Botti , Miguel A. L. Marques

Many low-density nanoparticles show a radial inner structure. This work proposes a novel approach to contrast variation with SAXS based on the constitution of a solvent density gradient in a glass capillary in order to resolve this internal…

Soft Condensed Matter · Physics 2014-10-28 Raul Garcia-Diez , Christian Gollwitzer , Michael Krumrey

The nucleation and growth of CdS nanoparticles within a polymer matrix was followed by in-situ synchrotron X-ray diffraction. The nanoparticles form by effect of the thermolysis of thiolate precursors at temperatures between 200 and 300…

Materials Science · Physics 2007-05-23 T. Di Luccio , A. M. Laera , L. Tapfer , S. Kempter , R. Kraus , B. Nickel

A potassium alumina borosilicate glass with the composition 13K2O*13Al2O3*16B2O3*43SiO2*15Fe2O3-x was melted using Fe2O3 as raw material. The melt was dumped from a Pt-crucible with a downpipe in water which resulted in the formation of…

Materials Science · Physics 2011-09-01 M. Büttner , C. Worsch , F. Schmidl , C. Rüssel , P. Seidel