Related papers: Laboratory measurements and astronomical search fo…
The detection E-cyanomethanimine (E-HNCHCN) towards Sagittarius B2(N) is made by comparing the publicly available Green Bank Telescope (GBT) PRIMOS survey spectra (Hollis et al.) to laboratory rotational spectra from a reaction product…
We report the first detection in the interstellar medium of $N$-cyanomethanimine (H$_2$CNCN), the stable dimer of HCN of highest energy, and the most complex organic molecule identified in space containing the prebiotically relevant NCN…
Thioacetamide (CH3CSNH2) is the sulfur analog to acetamide (CH3CONH2) and it is a viable candidate to search for in astronomical environments specifically toward regions where other S-bearing molecules have been found and, if possible, that…
We have performed reaction product screening measurements using broadband rotational spectroscopy to identify rotational transition matches between laboratory spectra and the Green Bank Telescope PRIMOS radio astronomy survey spectra in…
In this work, we present the results of our investigation into the chemistry of Z- and E-cyanomethanimine (HNCHCN), both of which are possible precursors to the nucleobase adenine. Ab initio quantum chemical calculations for a number of…
The saturated n-propyl cyanide was recently detected in Sagittarius B2(N). The next larger unbranched alkyl cyanide is n-butyl cyanide. We provide accurate rest frequency predictions beyond the millimeter wave range to search for this…
We report here the first detection in the interstellar medium of the cyanomidyl radical (HNCN). Using the Yebes 40m and the IRAM 30m telescopes, we have targeted the doublets of the $N$=2$-$1, 4$-$3, 5$-$4, 6$-$5, and 7$-$6 transitions of…
We report the first detection in the interstellar medium of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of Z-cyanomethanimine, along with five transitions of…
We present the detection of cyanothioketene, NCCHCS, in the laboratory and toward TMC-1. This transient species was produced through a discharge of a gas mixture of CH2CHCN and CS2 using argon as carrier gas, and its rotational spectrum…
We report the discovery of two unsaturated organic species, trans-(E)-cyanovinylacetylene and vinylcyanoacetylene, using the second data release of the GOTHAM deep survey towards TMC-1 with the 100 m Green Bank Telescope. For both…
We report on the detection of hydromagnesium isocyanide, HMgNC, in the laboratory and in the carbon rich evolved star IRC+10216. The J=1-0 and J=2-1 lines were observed in our microwave laboratory equipment in Valladolid with a spectral…
Cyanoformaldehyde (HCOCN) molecule has recently been suspected towards the Sagittarius B2(N) by the Green Bank telescope, though a confirmation of this observation has not yet been made. In and around a star forming region, this molecule…
We present laboratory rotational spectroscopy of five isomers of cyanoindene (2-, 4-, 5-, 6-, and 7-cyanoindene) using a cavity Fourier-transform microwave spectrometer operating between 6-40 GHz. Based on these measurements, we report the…
The reaction between carbon atoms and vinyl cyanide, CH2CHCN, is a formation route to interstellar 3-cyano propargyl radical, CH2C3N, a species that has recently been discovered in space. The 1-cyano propargyl radical (HC3HCN), an isomer of…
The rotational spectra of singly substituted $^{13}$C and $^{15}$N isotopic species of vinyl cyanide have been studied in natural abundances between 64 and 351 GHz. In combination with previous results, greatly improved spectroscopic…
In the interstellar medium (ISM), the complex prebiotic molecule cyanamide (NH$_{2}$CN) plays a key role in producing adenine (C$_{5}$H$_{5}$N$_{5}$), purines (C$_{5}$H$_{4}$N$_{4}$), pyrimidines (C$_{4}$H$_{4}$N$_{2}$), and other…
The rotational line survey by ALMA (Atacama Large Millimeter/submillimeter Array) recently revealed the presence of i-C3H7CN (i-PrCN) and n-C3H7CN (n-PrCN) in 3-mm atmospheric window between 84 to 111 GHz towards the hot core region…
The rotational spectrum of silyl isocyanide (SiH$_3$NC), an isomer of the well studied silyl cyanide (SiH$_3$CN), has been detected in the laboratory in a supersonic molecular beam, and the identification was confirmed by observations of…
Up to date, only 6 imines have been detected in the interstellar medium. The 3-carbon imine, 2-propanimine ((CH$_3$)$_2$C=NH), is predicted to be the structural isomer with the lowest energy in the C$_3$H$_7$N group, and appears to be a…
Aims. Our aim is to confirm the interstellar detection of cyanic acid, HOCN, in the Galactic center clouds. It has previously been tentatively detected only in Sgr B2(OH). Methods. We used a complete line survey of the hot cores Sgr B2(N)…