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We investigate the fine and spin structure of ultralong-range Rydberg molecules exposed to a homogeneous magnetic field. Each molecule consists of a $^{87}$Rb Rydberg atom whose outer electron interacts via spin-dependent $s$- and p-wave…

Atomic Physics · Physics 2018-05-02 Frederic Hummel , Christian Fey , Peter Schmelcher

We have performed high resolution photoassociation spectroscopy of rubidium ultra long-range Rydberg molecules in the vicinity of the 25$P$ state. Due to the hyperfine interaction in the ground state perturber atom, the emerging mixed…

Atomic Physics · Physics 2017-08-24 Thomas Niederprüm , Oliver Thomas , Tanita Eichert , Herwig Ott

The interaction between a Rydberg electron and a neutral atom situated inside its extended orbit is described via contact interactions for each atom-electron scattering channel. In ultracold environments, these interactions lead to…

Atomic Physics · Physics 2017-05-10 Matthew T Eiles , Chris H Greene

Quantum information processing with neutral atoms relies on Rydberg excitation for entanglement generation. While the use of heavy divalent or open-shell elements, such as strontium or ytterbium, has benefits due to their optically active…

Ultralong-range Rydberg molecules, composed of an excited Rydberg atom and a ground-state atom, are characterized by large bond lengths, dipole moments, sensitivity to external fields, and an unusual binding mechanism based on low-energy…

Atomic Physics · Physics 2025-05-13 Agata Wojciechowska , Michał Tomza , Matthew T. Eiles

We examine interactions between atoms continuously and coherently driven between the ground state and a Rydberg state, producing "Rydberg-dressed atoms." Because of the large dipolar coupling between two Rydberg atoms, a small admixture of…

Atomic Physics · Physics 2015-05-19 J. E. Johnson , S. L. Rolston

We theoretically investigate trapped ions interacting with atoms that are coupled to Rydberg states. The strong polarizabilities of the Rydberg levels increases the interaction strength between atoms and ions by many orders of magnitude, as…

Quantum Physics · Physics 2016-07-27 Thomas Secker , Rene Gerritsma , Alexander W. Glaetzle , Antonio Negretti

We investigate theoretically the long-range electrostatic interactions between a ground-state homonuclear alkali-metal dimer and an excited alkali-metal atom taking into account its fine-structure. The interaction involves the combination…

Chemical Physics · Physics 2017-09-13 Maxence Lepers , Olivier Dulieu

The formation of ultralong-range Rydberg molecules is a result of the attractive interaction between Rydberg electron and polarizable ground state atom in an ultracold gas. In the nondegenerate case the backaction of the polarizable atom on…

Atomic Physics · Physics 2015-07-10 A. Gaj , A. T. Krupp , P. Ilzhöfer , R. Löw , S. Hofferberth , T. Pfau

A Rydberg and a ground-state atom can form ultralong range diatomic molecules provided the interaction between the ground-state atom and the Rydberg electron is attractive [C. H. Greene, et al., Phys. Rev. Lett. 85, 2458 (2000)]. A…

Atomic Physics · Physics 2008-07-15 Ivan C. H. Liu , Jovica Stanojevic , Jan M. Rost

Atoms in highly excited Rydberg states exhibit remarkable properties and constitute a powerful tool for studying quantum phenomena in strongly interacting many-particle systems. We investigate alkali atoms that are held in a ring lattice…

Atomic Physics · Physics 2017-09-13 Beatriz Olmos , Igor Lesanovsky

We introduce a class of spin models with long-range interactions---in the sense that they extend significantly beyond nearest neighbors---whose ground states can be constructed analytically and have a simple matrix product state…

Strongly Correlated Electrons · Physics 2015-06-19 Emanuele Levi , Igor Lesanovsky

Optically trapped Rydberg atoms are a suitable platform to explore quantum many-body physics mediated by long-range atom--atom interactions that can be engineered through externally applied light fields. However, this approach is limited to…

We review ultralong-range Rydberg molecules (ULRM), which are bound states between a Rydberg atom and one or more ground-state atoms with bond lengths on the order of thousands of Bohr radii. The binding originates from multiple…

Atomic Physics · Physics 2020-03-18 Christian Fey , Frederic Hummel , Peter Schmelcher

Rydberg molecule, formed by one or more Rydberg atoms, exhibits remarkable properties, including an exceptionally large spatial extent, rich rovibrational level structures, permanent electric dipole moments, and a pronounced sensitivity to…

Atomic Physics · Physics 2026-03-11 Jingxu Bai , Yuechun Jiao , Xiao-Qiang Shao , Weibin Li , Jianming Zhao

We consider two clouds of ground state alkali atoms in two distinct hyperfine ground states. Each level is far off-resonantly coupled to a Rydberg state, which leads to dressed ground states with a weak admixture of the Rydberg state…

Atomic Physics · Physics 2014-04-30 M. Genkin , S. Wüster , S. Möbius , A. Eisfeld , J. M. Rost

We unravel some peculiar properties of ultralong-range Rydberg molecules formed by an $s$-state $^{87}$Rb Rydberg atom and a corresponding ground-state atom whose electronic orbitals are spherically symmetric and therefore should not be…

Atomic Physics · Physics 2019-02-06 Frederic Hummel , Christian Fey , Peter Schmelcher

We show that the recently observed class of long-range ion-Rydberg molecules can be divided into two families of states, which are characterised by their unique electronic structures resulting from the ion-induced admixture of quantum…

Atomic Physics · Physics 2023-02-14 Daniel J. Bosworth , Frederic Hummel , Peter Schmelcher

We present experimental evidence for spin-orbit interaction of an electron as it scatters from a neutral atom. The scattering process takes place within a Rb$_2$ ultralong-range Rydberg molecule, consisting of a Rydberg atomic core, a…

Cold Rydberg atoms exposed to strong magnetic fields possess unique properties which open the pathway for an intriguing many-body dynamics taking place in Rydberg gases consisting of either matter or anti-matter systems. We review both the…

Atomic Physics · Physics 2015-05-14 T. Pohl , H. R. Sadeghpour , P. Schmelcher
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