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We study the combined effects of electrostatic and hydrodynamic interactions (HI) on the short-time dynamics of charge-stabilized colloidal spheres. For this purpose, we calculate the translational and the rotational self-diffusion…

Soft Condensed Matter · Physics 2008-02-03 M. Watzlawek , G. Naegele

Intermediate Scattering Functions (ISF's) are measured for colloidal hard sphere systems using both Dynamic Light Scattering (DLS) and X-ray Photon Correlation Spectroscopy (XPCS). We compare the techniques, and discuss the advantages and…

Soft Condensed Matter · Physics 2015-05-19 V. A. Martinez , J. H. J Thijssen , F. Zontone , W. van Megen , G. Bryant

Diffusion in bidisperse Brownian hard-sphere suspensions is studied by Stokesian Dynamics (SD) computer simulations and a semi-analytical theoretical scheme for colloidal short-time dynamics, based on Beenakker and Mazur's method [Physica…

Soft Condensed Matter · Physics 2015-05-06 Mu Wang , Marco Heinen , John F. Brady

We study self-diffusion and sedimentation in colloidal suspensions of nearly-hard spheres using the multiparticle collision dynamics simulation method for the solvent with a discrete mesh model for the colloidal particles (MD+MPCD). We…

Soft Condensed Matter · Physics 2022-01-26 Yashraj M. Wani , Penelope Grace Kovakas , Arash Nikoubashman , Michael P. Howard

The dynamic behavior of a hard-sphere colloidal suspension was studied by X-ray Photon Correlation Spectroscopy and Small Angle X-ray Scattering over a wide range of particle volume fractions. The short-time mobility of the particles was…

Theoretical calculations for colloidal charge-stabilized and hard sphere suspensions show that hydrodynamic interactions yield a qualitatively different particle concentration dependence of the short-time self-diffusion coefficient. The…

Soft Condensed Matter · Physics 2009-10-31 E. Overbeck , Ch. Sinn , M. Watzlawek

We have performed confocal microscopy experiments and computer simulations of colloidal suspensions with moderate volume fraction confined between two quasi-parallel, rough walls [A. Villada-Balbuena et al., Soft Matter, 2022, 18,…

Soft Condensed Matter · Physics 2025-04-30 Gerhard Jung , Alejandro Villada-Balbuena , Thomas Franosch

We describe experimentally observed collective dynamics in colloidal suspensions of model hard-sphere particles using a modified mode coupling theory (MCT). This rescaled MCT is capable to describe quantitatively the wave-vector and…

Soft Condensed Matter · Physics 2024-03-08 Joel Diaz Maier , Joachim Wagner

We report on depolarized and non-depolarized dynamic light scattering, static light scattering, and static viscosity measurements on interacting charged gibbsite platelets suspended in dimethyl sulfoxide (DMSO). The average collective and…

Soft Condensed Matter · Physics 2012-02-03 Dzina Kleshchanok , Marco Heinen , Gerhard Nägele , Peter Holmqvist

In this article we report on a study of the near-wall dynamics of suspended colloidal hard spheres over a broad range of volume fractions. We present a thorough comparison of experimental data with predictions based on a virial…

We present an experimental study of short-time diffusion properties in fluid-like suspensions of monodisperse charge-stabilized silica spheres suspended in DMF. The static structure factor S(q), the short-time diffusion function, D(q), and…

Soft Condensed Matter · Physics 2009-11-13 J. Gapinski , A. Patkowski , A. J. Banchio , J. Buitenhuis , P. Holmqvist , M. P. Lettinga , G. Meier , G. Naegele

We study a homogeneously driven granular fluid of hard spheres at intermediate volume fractions and focus on time-delayed correlation functions in the stationary state. Inelastic collisions are modeled by incomplete normal restitution,…

Statistical Mechanics · Physics 2013-05-29 Katharina Vollmayr-Lee , Timo Aspelmeier , Annette Zippelius

We analyze the slow, glassy structural relaxation as measured through collective and tagged-particle density correlation functions obtained from Brownian dynamics simulations for a polydisperse system of quasi-hard spheres in the framework…

Soft Condensed Matter · Physics 2010-10-18 F. Weysser , A. M. Puertas , M. Fuchs , Th. Voigtmann

We present an easy-to-use analytic toolbox for the calculation of short-time transport properties of concentrated suspensions of spherical colloidal particles with internal hydrodynamic structure, and direct interactions described by a…

Soft Condensed Matter · Physics 2015-03-02 Jonas Riest , Thomas Eckert , Walter Richtering , Gerhard Nägele

We report on calculations of the translational and rotational short-time self-diffusion coefficients $D^t_s$ and $D^r_s$ for suspensions of charge-stabilized colloidal spheres. These diffusion coefficients are affected by electrostatic…

Soft Condensed Matter · Physics 2009-10-30 M. Watzlawek , G. Naegele

The rotational Brownian motion of colloidal spheres in dense suspensions reflects local hydrodynamics and friction, both key to non-linear rheological phenomena such as shear-thickening and jamming, and transport in crowded environments,…

Soft Condensed Matter · Physics 2021-06-23 Taiki Yanagishima , Yanyan Liu , Hajime Tanaka , Roel Dullens

In our recent work on concentrated suspensions of uniformly porous colloidal spheres with excluded volume interactions, a variety of short-time dynamic properties were calculated, except for the rotational self-diffusion coefficient. This…

Soft Condensed Matter · Physics 2015-05-27 Gustavo C. Abade , Bogdan Cichocki , Maria L. Ekiel-Jezewska , Gerhard Naegele , Eligiusz Wajnryb

We study structural relaxation of colloidal hard spheres undergoing Brownian motion using dynamical density functional theory. Contrary to the partial linearization route [Stopper {\em et al.}, Phys. Rev. E {\bf 92}, 022151 (2015)] which…

Soft Condensed Matter · Physics 2018-01-16 Daniel Stopper , Roland Roth , Hendrik Hansen-Goos

Molecular dynamics simulations are carried out to investigate the diffusion behavior of penetrable-sphere model fluids characterized by a finite energy barrier $\epsilon$. The self-diffusion coefficient is evaluated from the time-dependent…

Soft Condensed Matter · Physics 2010-11-22 Soong-Hyuck Suh , Chun-Ho Kim , Soon-Chul Kim , Andrés Santos

A comprehensive study is presented on the short-time dynamics in suspensions of charged colloidal spheres. The explored parameter space covers the major part of the fluid-state regime, with colloid concentrations extending up to the…

Soft Condensed Matter · Physics 2011-10-20 Marco Heinen , Adolfo J. Banchio , Gerhard Nägele
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