Related papers: CO diffusion and desorption kinetics in CO$_2$ ice…
Spectroscopic studies of ices in nearby star-forming regions indicate that ice mantles form on dust grains in two distinct steps, starting with polar ice formation (H2O rich) and switching to apolar ice (CO rich). We test how well the…
CO line emission represents the most accessible and widely used tracer of the molecular interstellar medium. This renders the translation of observed CO intensity into total H2 gas mass critical to understand star formation and the…
Aims. In this paper we investigate the detectability of the molecular oxygen in icy dust grain mantles towards astronomical objects. Methods. We present a systematic set of experiments with O2-H2O ice mixtures designed to disentangle how…
Freeze-out of the gas phase elements onto cold grains in dense interstellar and circumstellar media builds up ice mantles consisting of molecules that are mostly formed in situ (H2O, NH3, CO2, CO, CH3OH, and more). This review summarizes…
Context: Diffusion of species on the dust surface is a key process for determining the chemical composition of interstellar ices. On the dust surface, adsorbed species diffuse from one potential well to another and react with other adsorbed…
The energy to desorb atomic oxygen from an interstellar dust grain surface, $E_{\rm des}$, is an important controlling parameter in gas-grain models; its value impacts the temperature range over which oxygen resides on a dust grain.…
Context. While radiative cooling of interstellar grains is a well-known process, little detail is known about the cooling of grains with an icy mantle that contains volatile adsorbed molecules. Aims. We explore basic details for the cooling…
ORFEUS far UV echelle spectra have been used to investigate HI, H_2 and CO absorption lines along the line of sight towards LH 10:3120 in the LMC, extending the study presented by de Boer et al. (1998). While H_2 absorption is clearly…
Context. The diffusion of volatile species on amorphous solid water ice affects the chemistry on dust grains in the interstellar medium as well as the trapping of gases enriching planetary atmospheres or present in cometary material. Aims.…
Ices imprint strong absorption features in the near- and mid-infrared, but until recently they have been studied almost exclusively with spectroscopy toward small samples of bright sources. We show that JWST photometry alone can reveal and…
Carbon monoxide (CO) is the second most abundant molecule in the gas-phase of the interstellar medium. In dense molecular clouds, it is also present in the solid-phase as a constituent of the mixed water-dominated ices covering dust grains.…
The gas-phase CO abundance (relative to hydrogen) in protoplanetary disks decreases by up to 2 orders of magnitude from its ISM value ${\sim}10^{-4}$, even after accounting for freeze-out and photo-dissociation. Previous studies have shown…
Infrared stellar photometry from 2MASS and spectral line imaging observations of 12CO and 13CO J = 1-0 line emission from the FCRAO 14m telescope are analysed to assess the variation of the CO abundance with physical conditions throughout…
CO2 ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study…
We measure the CO-to-H$_2$ conversion factor ($\alpha_\mathrm{CO}$) in 37 galaxies at 2~kpc resolution, using dust surface density inferred from far-infrared emission as a tracer of the gas surface density and assuming a constant…
The properties of the ices that form in dense molecular clouds represent an important set of initial conditions in the evolution of interstellar and preplanetary matter in regions of active star formation. Of the various spectral features…
Physisorbed atoms on the surface of interstellar dust grains play a central role in solid state astrochemistry. Their surface reactivity is one source of the observed molecular complexity in space. In experimental astrophysics, the high…
We present observations of CO, 13CO and of H2O in the middle and far-infrared taken with the ISO-SWS and ISO-LWS spectrometers toward two positions in the Galactic Center region (Sgr A* and GCS-3). Both ice and gas phase molecules are…
Ice is ubiquitous in the interstellar medium. We model the formation of the main constituents of interstellar ices, including H2O, CO2 , CO, and CH3 OH. We strive to understand what physical or chemical parameters influence the final…
The adsorption of volatile molecules onto dust grain surfaces fundamentally influences dust-related processes, including condensation of gas-phase molecules, dust coagulation, and planet formation in protoplanetary disks. Using advanced…