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Bulk amorphous materials have been studied extensively and are widely used, yet their atomic arrangement remains an open issue. Although they are generally believed to be Zachariasen continuous random networks, recent experimental evidence…

To help provide insight into the remarkable catalytic behavior of the oxygen/silver system for heterogeneous oxidation reactions, purely sub-surface oxygen, and structures involving both on-surface and sub-surface oxygen, as well as…

Materials Science · Physics 2009-11-10 Wei-Xue Li , Catherine Stampfl , Matthias Scheffler

Amorphous boron nitride (\textrm{$\alpha$}-BN) is a promising ultrathin barrier for nanoelectronics, yet the atomistic mechanisms governing its chemical stability remain poorly understood. Here, we investigate the structure-property…

We have analyzed the atomic arrangements and quantum conductance of silver nanowires generated by mechanical elongation. The surface properties of Ag induce unexpected structural properties, as for example, predominance of high aspect ratio…

Materials Science · Physics 2009-11-07 V. Rodrigues , J. Bettini , A. R. Rocha , L. G. C. Rego , D. Ugarte

We studied the electronic band structure of the low-index fcc Ag surfaces (001), (110) and (111), by using the empirical tight-binding method in addition with the surface Green function matching method. We report the energy values for…

Materials Science · Physics 2013-11-26 H. J. Herrera-Suarez , A. Rubio-Ponce , D. Olguin

A series of well-defined hydrophilic and hydrophobic polyelectrolytes of various chain lengths $N$ and effective charge fractions $f_{eff}$ have been adsorbed onto oppositely charged solid surfaces immersed in aqueous solutions. \emph{In…

Photonic band structure of metal-dielectric and semiconductor-dielectric layered structures are studied in the presence of a strong absorption. It is shown that absorption can enlarge some gaps by as much as 50%.

Condensed Matter · Physics 2007-05-23 Alexander Moroz , Adriaan Tip , Jean-Michel Combes

The microstructure, electronic structure, and chemical bonding of chromium carbide thin films with different carbon contents have been investigated with high-resolution transmission electron microscopy, electron energy loss spectroscopy and…

Mesoscale and Nanoscale Physics · Physics 2012-05-04 Martin Magnuson , Matilda Andersson , Jun Lu , Lars Hultman , Ulf Jansson

The paper presents the results of investigation of the structure of porous condensates of Ag-NaCl and Cu-NaCl composition; chemical and phase compositions and dimensions of nanoparticles, produced from the vapour phase by EBPVD method.…

Materials Science · Physics 2019-01-04 Yu. A. Kurapov , S. E. Litvin , S. M. Romanenko , G. G. Didikin , N. N. Belyavina

The durability of passivable metals and alloys is often limited by the stability of the surface oxide film, the passive film, providing self-protection against corrosion in aggressive environments. Improving this stability requires to…

Materials Science · Physics 2019-07-26 Li Ma , Frederic Wiame , Vincent Maurice , Philippe Marcus

We show the first evidence of dissociation during resonant inelastic soft X-ray scattering. Carbon and oxygen K-shell and sulfur L-shell resonant and non-resonant X-ray emission spectra were measured using monochromatic synchrotron…

Chemical Physics · Physics 2012-01-06 M. Magnuson , J. Guo , C. Såthe , J. -E. Rubensson , J. Nordgren , P. Glans , L. Yang , P. Salek , H. Ågren

Silver nanocrystals have been prepared by reacting silver nitrate with ascorbic acid in aqueous solution containing a low concentration of a commercial polynaphtalene sulphonate polymer (Daxad 19). Various crystalline morphologies have been…

To investigate chemical reactivity of Cu atomic-scale structures, we performed simulations based on the generalized gradient approximation in the density functional theory. An atomic layer of Cu forming a triangular lattice (TL) was found…

Materials Science · Physics 2011-05-16 S Nogami , H Kizaki , K Kusakabe

Hydrophobic solid-water interfaces underpin processes in nanofluidics, electrochemistry, and energy technologies. Microscopic insights into these systems are often inferred from our understanding of the air-water interface, which is assumed…

Based on first-principles calculations we performed a systematic study of the energetic stability, structural characterization, and electronic properties of the fully oxidized $A_{2}B$, electrenes, with the following combinations, (i)…

Materials Science · Physics 2022-06-15 Pedro H. Souza , Danilo Kuritza , José E. Padilha , Roberto H. Miwa

Controlling light-matter interactions is central to photonic technologies ranging from lasers to optical information processing. Suitably designed photonic structures give rise to flat (dispersionless) bands, where the density of states…

The spatial structure of the transition region between an insulator and an electrolyte solution was studied with x-ray scattering.The electron density profile across the n-hexane/silica sol interface (solutions with 5-nm, 7-nm, and 12-nm…

Soft Condensed Matter · Physics 2009-11-11 Aleksey M. Tikhonov

We present electronic band structure of Ag$_5$Pb$_2$O$_6$ with layered hexagonal structure containing one-dimensional chains and two-dimensional Kagom\'{e} layers of silver. A half-filled conduction band shows extremely simple, single…

Strongly Correlated Electrons · Physics 2009-11-11 Tamio Oguchi

Atomic and electronic structures of a polar surface of MgO formed on Ag(111) was investigated by using reflection high energy electron diffraction (RHEED), Auger electron spectroscopy, electron energy loss spectroscopy (EELS), and…

Materials Science · Physics 2009-11-10 Manabu Kiguchi , Shiro Entani , Koichiro Saiki , Takayuki Goto , Atsushi Koma