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We have assigned the chirality of the internal tubes of double walled carbon nanotubes grown by catalytic chemical vapor deposition using the high sensitivity of the radial breathing mode (RB) in inelastic light scattering experiments. The…

Materials Science · Physics 2009-11-07 R. R. Bacsa , A. Peigney , Ch. Laurent , P. Puech , W. S. Bacsa

From resonant Raman scattering on isolated nanotubes we obtained the optical transition energies, the radial breathing mode frequency and Raman intensity of both metallic and semiconducting tubes. We unambiguously assigned the chiral index…

Materials Science · Physics 2009-11-10 H. Telg , J. Maultzsch , S. Reich , F. Hennrich , C. Thomsen

Monoatomic chains of molybdenum encapsulated in single walled carbon nanotubes of different chiralities are investigated using density functional theory. We determine the optimal size of the carbon nanotube for encapsulating a single atomic…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 A. García-Fuente , V. M. García-Suárez , J. Ferrer , A. Vega

We show by ab initio calculations that the electron-phonon coupling matrix element M of the radial breathing mode in single-walled carbon nanotubes depends strongly on tube chirality. For nanotubes of the same diameter the coupling strength…

Materials Science · Physics 2009-11-10 M. Machon , S. Reich , H. Telg , J. Maultzsch , P. Ordejon , C. Thomsen

The analysis of the Raman scattering cross section of the radial breathing modes of double-wall carbon nanotubes allowed to determine the optical transitions of the inner tubes. The Raman lines are found to cluster into species with similar…

Soft Condensed Matter · Physics 2007-05-23 R. Pfeiffer , F. Simon , H. Kuzmany , V. N. Popov

Long linear carbon-chains have been attracting intense interest arising from the remarkable properties predicted and their potential applications in future nanotechnology. Here we comprehensively interrogate the excitonic transitions and…

We report the existence of broad and weakly asymmetric features in the high-energy (G) Raman modes of freely suspended metallic carbon nanotubes of defined chiral index. A significant variation in peak width (from 12 cm-1 to 110 cm-1) is…

Growing graphene nanoribbons from small organic molecules encapsulated in carbon nanotubes can result in products with uniform width and chirality. We propose a method based on encapsulation of 1,2,4-trichlorobenzene from the liquid phase…

Two paramount challenges in carbon nanotube research are achieving chirality-controlled synthesis and understanding chirality-dependent device physics. High-throughput and in-situ chirality and electronic structural characterization of…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 Kaihui Liu , Xiaoping Hong , Qin Zhou , Chenhao Jin , Jinghua Li , Weiwei Zhou , Jie Liu , Enge Wang , Alex Zettl , Feng Wang

We present a comprehensive characterization of an individual multiwalled carbon nanotube transport device combining electron microscopy and Raman spectroscopy with electrical measurements. Each method gives complementary information that…

Mesoscale and Nanoscale Physics · Physics 2011-08-01 Robert Frielinghaus , Karin Goß , Stefan Trellenkamp , Lothar Houben , Claus M. Schneider , Carola Meyer

We consider chirality related effects in optical, photogalvanic and electron-transport properties of carbon nanotubes. We show that these properties of chiral nanotubes are determined by terms in the electron effective Hamiltonian…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 E. L. Ivchenko , B. Spivak

Graphene nanoribbons are prepared inside boron nitride nanotubes by liquid phase encapsulation and subsequent annealing of 1,2,4-trichlorobenzene. The product is imaged with high resolution transmission electron microscopy, and…

Materials Science · Physics 2023-01-18 Ana Cadena , Áron Pekker , Bea Botka , Erzsébet Dodony , Zsolt Fogarassy , Béla Pécz , Katalin Kamarás

Structure of the spin-orbit coupling varies from material to material and thus finding the correct spin-orbit coupling structure is an important step towards advanced spintronic applications. We show theoretically that the curvature in a…

Mesoscale and Nanoscale Physics · Physics 2011-09-14 Jae-Seung Jeong , Hyun-Woo Lee

We present a comprehensive study of the chiral-index assignment of carbon nanotubes in aqueous suspensions by resonant Raman scattering of the radial breathing mode. We determine the energies of the first optical transition in metallic…

Materials Science · Physics 2007-05-23 J. Maultzsch , H. Telg , S. Reich , C. Thomsen

Single-walled carbon nanotubes are hollow cylinders, that can grow centimeters long by carbon incorporation at the interface with a catalyst. They display semi-conducting or metallic characteristics, depending on their helicity, that is…

Materials Science · Physics 2018-11-14 Yann Magnin , Hakim Amara , François Ducastelle , Annick Loiseau , Christophe Bichara

We study large-amplitude oscillations of carbon nanotubes with chiralities $(m,0)$ and $(m,m)$ and predict the existence of localized nonlinear modes in the form of {\em discrete breathers}. In nanotubes with the index $(m,0)$ {\em three…

Pattern Formation and Solitons · Physics 2007-06-01 Alexander V. Savin , Yuri S. Kivshar

The lineshapes of the Raman excitation profiles for radial breathing modes in carbon nanotubes are shown to be strongly affected by interference effects that arise whenever strong optical transitions are separated by a small energy. This is…

Materials Science · Physics 2009-11-10 G. Bussi , J. Menendez , J. Ren , M. Canonico , E. Molinari

We calculate the van der Waals energy of a C60 molecule when it is encapsulated in a single-walled carbon nanotube with discrete atomistic structure. orientational degrees of freedom and longitudinal displacements of the molecule are taken…

Materials Science · Physics 2012-08-17 B. Verberck , K. H. Michel

By employing the first-principles calculations, we investigate electronic properties of a novel carbon nanostructure called a carbon nanobud, in which a $C_{60}$ molecule covalently attaches or embeds in an armchair carbon nanotube. We find…

Mesoscale and Nanoscale Physics · Physics 2009-12-19 H. Y. He , B. C. Pan

Carbon nanotubes are the focus of considerable research efforts due to their fascinating physical properties. They provide an excellent model system for the study of one dimensional materials and molecular electronics. The chirality of…

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