Related papers: Isotopic fractionation in interstellar molecules
It is a fact that interstellar formation processes are thermodynamically affected. Based on this, the seven heterocycles; imidazole, pyridine, pyrimidine, pyrrole, quinoline, isoquinoline and furan that have been searched for from different…
We present the results of a single-pointing survey of 207 dense cores embedded in Planck Galactic Cold Clumps distributed in five different environments ($\lambda$ Orionis, Orion A, B, Galactic plane, and high latitudes) to identify dense…
High deuterium fractionation is observed in various types of environment such as prestellar cores, hot cores and hot corinos. It has proven to be an efficient probe to study the physical and chemical conditions of these environments. The…
Deuteration is a crucial tool to understand the complexity of interstellar chemical processes, especially when they involve the interplay of gas-phase and grain-surface chemistry. In the case of multiple deuteration, comparing observation…
Interstellar objects provide a unique opportunity to further our understanding of the planetary formation process by studying in detail material formed around another star. Their ices contain precious clues about the environment and…
While the abundance of elemental deuterium is relatively low (D/H ~ a few 1E-5), orders of magnitude higher D/H abundance ratios have been found for many interstellar molecules, enhanced by deuterium fractionation. In cold molecular clouds…
Carbon containing molecules in cold molecular clouds show various levels of isotopic fractionation through multiple observations. To understand such effects, we have developed a new gas-grain chemical model with updated 13C fractionation…
We present N2D+ 3-2 (IRAM) and H2D+ 1_11 - 1_10 and N2H+ 4-3 (JCMT) maps of the small cluster-forming Ophiuchus B2 core in the nearby Ophiuchus molecular cloud. In conjunction with previously published N2H+ 1-0 observations, the N2D+ data…
Extremely high deuteration of several molecules have been observed around low mass protostars since a decade. Among them, formaldehyde and methanol present particularly high deuteration, with observations of abundant doubly and triply…
We investigated the chemistry of nitrogen--containing species, principally isotopomers of CN, HCN, and HNC, in a sample of pre-protostellar cores. We used the IRAM 30 m telescope to measure the emission in rotational and hyperfine…
A broad array of interstellar absorption features that appear in the ultraviolet spectra of bright sources allows us to measure the abundances and ionization states of many important heavy elements that exist as free atoms in the…
High levels of deuterium fraction in N$_2$H$^+$ are observed in some pre-stellar cores. Single-zone chemical models find that the timescale required to reach observed values ($D_{\rm frac}^{{\rm N}_2{\rm H}^+} \equiv {\rm N}_2{\rm D}^+/{\rm…
Excess levels of 15N isotopes which have been detected in primitive solar system materials are explained as a remnant of interstellar chemistry which took place in regions of the protosolar nebula. Chemical models of nitrogen fractionation…
Nucleosynthesis, on the surface of accreting neutron stars, produces a range of chemical elements. We perform molecular dynamics simulations of crystallization to see how this complex composition forms new neutron star crust. We find…
Infrared Dark Clouds (IRDCs) are cold, dense regions that are usually found within Giant Molecular Clouds (GMCs). Ongoing star formation within IRDCs is typically still deeply embedded within the surrounding molecular gas. Characterising…
Although deuterium enrichment of water may provide an essential piece of information in the understanding of the formation of comets and protoplanetary systems, only a few studies up to now have aimed at deriving the HDO/H2O ratio in…
We aim to determine the $^{14}$N/$^{15}$N and $^{12}$C/$^{13}$C ratios for HCN in six starless and prestellar cores and compare the results between the direct method using radiative transfer modeling and the indirect double isotope method…
We simulate atmospheric fractionation in escaping planetary atmospheres using IsoFATE, a new open-source numerical model. We expand the parameter space studied previously to planets with tenuous atmospheres that exhibit the greatest helium…
We investigate mixed (50/50) clusters of parahydrogen and orthodeuterium at low temperature, by means of Quantum Monte Carlo simulations. Our results provide evidence of liquid-like behavior and partial isotopic separation in a cluster of…
Molecular deuteration is commonly seen in starless cores and is expected to occur on a timescale comparable to that of the core contraction. Thus, the deuteration serves as a chemical clock, allowing us to investigate dynamical theories of…