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Estimating free energy is a fundamental problem in statistical mechanics. Recently, machine-learning-based methods, particularly the variational autoregressive networks (VANs) have been proposed to minimize variational free energy and to…

Statistical Mechanics · Physics 2025-02-12 Jing Liu , Ying Tang , Pan Zhang

We present an effective adaptive procedure for the numerical approximation of the steady-state Gross-Pitaevskii equation. Our approach is solely based on energy minimization, and consists of a combination of gradient flow iterations and…

Numerical Analysis · Mathematics 2020-01-16 Pascal Heid , Benjamin Stamm , Thomas P. Wihler

Gaussian process (GP) emulator has been used as a surrogate model for predicting force field and molecular potential, to overcome the computational bottleneck of molecular dynamics simulation. Integrating both atomic force and energy in…

Chemical Physics · Physics 2022-05-13 Hao Li , Musen Zhou , Jessalyn Sebastian , Jianzhong Wu , Mengyang Gu

The averaged alternating modified reflections (AAMR) method is a projection algorithm for finding the closest point in the intersection of convex sets to any arbitrary point in a Hilbert space. This method can be seen as an adequate…

Optimization and Control · Mathematics 2018-09-27 Francisco J. Aragón Artacho , Rubén Campoy

A powerful and well-established tool for free-energy estimation is Bennett's acceptance ratio method. Central properties of this estimator, which employs samples of work values of a forward and its time reversed process, are known: for…

Statistical Mechanics · Physics 2009-09-16 Aljoscha Maria Hahn , Holger Then

Estimating the free energy in molecular simulation requires, implicitly or explicitly, counting how many times the system is observed in a finite region. If the simulation is biased by an external potential, the weight of the configurations…

Chemical Physics · Physics 2021-12-22 Matteo Carli , Alessandro Laio

In this paper, we study the problem of adaptive estimation of the spectral density of a stationary Gaussian process. For this purpose, we consider a wavelet-based method which combines the ideas of wavelet approximation and estimation by…

Statistics Theory · Mathematics 2011-06-07 Jérémie Bigot , Rolando Biscay Lirio , Jean-Michel Loubes , Lilian Muniz Alvarez

An adapted bubble approach which is a modifiation of the residual-free bubbles (RFB) method, is proposed for the Helmhotz problem in 2D. A new two-level finite element method is introduced for the approximations of the bubble functions.…

Numerical Analysis · Mathematics 2022-11-17 Adem Kaya

Given a finite set of sample points, meta-learning algorithms aim to learn an optimal adaptation strategy for new, unseen tasks. Often, this data can be ambiguous as it might belong to different tasks concurrently. This is particularly the…

Machine Learning · Computer Science 2024-10-24 Alfredo Reichlin , Gustaf Tegnér , Miguel Vasco , Hang Yin , Mårten Björkman , Danica Kragic

This report presents the application of polynomial regression for estimating free energy differences using thermodynamic integration. We employ linear regression to construct a polynomial that optimally fits the thermodynamic integration…

Computational Physics · Physics 2008-10-02 Conrad Shyu , F. Marty Ytreberg

A number of researchers have independently introduced topologies on the set of laws of stochastic processes that extend the usual weak topology. Depending on the respective scientific background this was motivated by applications and…

Probability · Mathematics 2021-05-18 Julio Backhoff , Daniel Bartl , Mathias Beiglböck , Johannes Wiesel

Exact free energy minimization is a convex optimization problem that is usually approximated with stochastic sampling methods. Deterministic approximations have been less successful because many desirable properties have been difficult to…

Computational Physics · Physics 2016-03-17 Jonathan E. Moussa

Recently we proposed a scheme that applies the variational principle to a coherent-pair condensate in the BCS case [Phys. Rev. C 99, 014302 (2019)]. This work extends the scheme to the HFB case by allowing variation of the canonical…

Nuclear Theory · Physics 2020-01-29 L. Y. Jia

This paper introduces a subgradient extragradient algorithm with a conjugate gradient-type direction to solve pseudomonotone variational inequality problems in Hilbert spaces. The algorithm features a self-adaptive strategy that eliminates…

Optimization and Control · Mathematics 2025-05-07 Ibrahim Arzuka , Parin Chaipunya , Poom Kumam

In this paper, we propose a new random forest algorithm that constructs the trees using a novel adaptive split-balancing method. Rather than relying on the widely-used random feature selection, we propose a permutation-based balanced…

Machine Learning · Statistics 2024-09-04 Yuqian Zhang , Weijie Ji , Jelena Bradic

We show how to adapt the approach introduced for viscous damping in [1] to derive the approximate amplitude decay in the case of damping by a force of constant magnitude (sliding friction) and in the case of damping by a force proportional…

Classical Physics · Physics 2025-09-05 Karlo Lelas , Robert Pezer

A modification of Coulomb's law of friction uses a variable coefficient of friction that depends on a power law in the energy of mechanical oscillation. Through the use of three different exponents: 0, 1/2 and 1; all commonly encountered…

Classical Physics · Physics 2007-05-23 Randall D. Peters

An alternative representation of an exact statistical field theory for simple fluids, based on the method of collective variables, is presented. The results obtained are examined from the point of another version of theory that was…

Statistical Mechanics · Physics 2009-11-11 Jean-Michel Caillol , Oksana Patsahan , Ihor Mryglod

Approximating ground and a fixed number of excited state energies, or equivalently low order Hamiltonian eigenvalues, is an important but computationally hard problem. Typically, the cost of classical deterministic algorithms grows…

Quantum Physics · Physics 2015-08-10 Stuart Hadfield , Anargyros Papageorgiou

We introduce a novel adaptive Gaussian Process Regression (GPR) methodology for efficient construction of surrogate models for Bayesian inverse problems with expensive forward model evaluations. An adaptive design strategy focuses on…

Numerical Analysis · Mathematics 2024-05-01 Paolo Villani , Jörg Unger , Martin Weiser
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