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We introduce an alternate route to dynamically polarize the nuclear spin host of nitrogen-vacancy (NV) centers in diamond. Our approach articulates optical, microwave and radio-frequency pulses to recursively transfer spin polarization from…

Quantum Physics · Physics 2014-12-18 Daniela Pagliero , Abdelghani Laraoui , Jacob D. Henshaw , Carlos A. Meriles

Optically polarizable nitrogen-vacancy (NV) center in diamond enables the hyperpolarization of $^{13}$C nuclear spins at low magnetic field and room temperature. However, achieving a high level of polarization comparable to conventional…

Quantum Physics · Physics 2024-10-01 Vladimir V. Kavtanyuk , Changjae Lee , Keunhong Jeong , Jeong Hyun Shim

The nitrogen-vacancy (NV) centre in diamond has emerged as a candidate to non-invasively hyperpolarise nuclear spins in molecular systems to improve the sensitivity of nuclear magnetic resonance (NMR) experiments. Several promising proof of…

Mesoscale and Nanoscale Physics · Physics 2021-05-26 A. J. Healey , L. T. Hall , G. A. L. White , T. Teraji , M. -A. Sani , F. Separovic , J. -P. Tetienne , L. C. L. Hollenberg

The use of nitrogen-vacancy centers in diamond as a non-invasive platform for hyperpolarizing nuclear spins in molecular samples is a promising area of research with the potential to enhance the sensitivity of nuclear magnetic resonance…

Quantum Physics · Physics 2024-08-08 H. Espinós , C. Munuera-Javaloy , I. Panadero , P. Acedo , R. Puebla , J. Casanova , E. Torrontegui

Polarizing nuclear spins is of fundamental importance in biology, chemistry and physics. Methods for hyperpolarizing 13C nuclei from free electrons in bulk, usually demand operation at cryogenic temperatures. Room-temperature approaches…

Nuclear hyperpolarization is a known method to enhance the signal in nuclear magnetic resonance (NMR) by orders of magnitude. The present work addresses the $^{13}$C hyperpolarization in diamond micro- and nanoparticles, using the…

A broad effort is underway to improve the sensitivity of nuclear magnetic resonance through the use of dynamic nuclear polarization. Nitrogen-vacancy (NV) centers in diamond offer an appealing platform because these paramagnetic defects can…

Over the years, an enormous effort has been made to establish nitrogen vacancy (NV) centers in diamond as easily accessible and precise magnetic field sensors. However, most of their sensing protocols rely on the application of bias…

Dynamical nuclear polarisation (DNP) is an important technique that uses polarisation transfer from electron to nuclear spins to achieve nuclear hyperpolarisation. As the electron spin of the nitrogen vacancy (NV) centres in diamond can be…

We report polarization of a dense nuclear-spin ensemble in diamond and its dependence on magnetic field and temperature. The polarization method is based on the transfer of electron spin polarization of negatively charged nitrogen vacancy…

Quantum Physics · Physics 2013-04-01 Ran Fischer , Andrey Jarmola , Pauli Kehayias , Dmitry Budker

The ability to optically initialize the electronic spin of the nitrogen-vacancy (NV) center in diamond has long been considered a valuable resource to enhance the polarization of neighboring nuclei, but efficient polarization transfer to…

Mesoscale and Nanoscale Physics · Physics 2018-08-01 F. Shagieva , S. Zaiser , P. Neumann , D. B. R. Dasari , R. Stöhr , A. Denisenko , R. Reuter , C. A. Meriles , J. Wrachtrup

After initial proof-of-principle demonstrations, optically pumped nitrogen-vacancy (NV) centres in diamond have been proposed as a non-invasive platform to achieve hyperpolarisation of nuclear spins in molecular samples over macroscopic…

Mesoscale and Nanoscale Physics · Physics 2021-01-27 J. -P. Tetienne , L. T. Hall , A. J. Healey , G. A. L. White , M. -A. Sani , F. Separovic , L. C. L. Hollenberg

Nanodiamonds containing nitrogen vacancy (NV-) centers show promise for a number of emerging applications including targeted in vivo imaging and generating nuclear spin hyperpolarization for enhanced NMR spectroscopy and imaging. Here, we…

We present theoretical proposals for two-dimensional nuclear magnetic resonance spectroscopy protocols based on Nitrogen-vacancy (NV) centers in diamond that are strongly coupled to the target nuclei. Continuous microwave and…

Quantum Physics · Physics 2024-10-31 Matthias Kost , Jianming Cai , Martin B. Plenio

Hyper-polarization of nuclear spins is crucial for advancing nuclear magnetic resonance (NMR) and quantum information technologies, as nuclear spins typically exhibit extremely low polarization at room temperature due to their small…

Quantum Physics · Physics 2025-05-20 Haiyang Li , Hao Liao , Ping Wang

We experimentally demonstrate high degree of polarization of 13C nuclear spins weakly interacting with nitrogen-vacancy (NV) centers in diamond. We combine coherent microwave excitation pulses with optical illumination to provide controlled…

Quantum Physics · Physics 2019-10-25 Jiwon Yun , Kiho Kim , Dohun Kim

Enhancing the polarization of nuclear spins surrounding the nitrogen-vacancy (NV) center in diamond has attracted widespread attention recently due to its various applications. Here we present an analytical theory and comprehensive…

Quantum Physics · Physics 2016-07-15 Ping Wang , Bao Liu , Wen Yang

The integration of NMR and high pressure technique brings unique opportunities to study electronic, structural and dynamical properties under extreme conditions. Despite a great degree of success has been achieved using coil-based schemes,…

Quantum Physics · Physics 2022-03-22 Yan-Xing Shang , Fang Hong , Jian-Hong Dai , Ya-Nan Lu , Hui Yu , Yong-Hong Yu , Xiao-Hui Yu , Xin-Yu Pan , Gang-Qin Liu

Dynamic nuclear polarization via contact with electronic spins has emerged as an attractive route to enhance the sensitivity of nuclear magnetic resonance (NMR) beyond the traditional limits imposed by magnetic field strength and…

We determine the polarization of the bulk $^{13}$C nuclear spin system in diamond produced by interaction with optically oriented nitrogen-vacancy (NV-) defect centers. $^{13}$C nuclei are polarized into the higher energy Zeeman state with…

Other Condensed Matter · Physics 2015-05-14 Jonathan P. King , Patrick J. Coles , Jeffrey A. Reimer
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