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We develop a framework to describe collective buckling in metal-organic frameworks (MOFs). Starting from the microscopic structure of a single organic linker, we define a buckling coordinate governed by an effective double-well potential.…

Statistical Mechanics · Physics 2026-03-27 Nico Hahn , Lars Öhrström , R. Matthias Geilhufe

Based on recently synthesized Ni3C12S12 class 2D metal-organic frameworks, we predict electronic properties of M3C12S12 and M3C12O12, where M is Zn, Cd, Hg, Be, or Mg with no M orbital contributions to bands near Fermi level. For M3C12S12,…

Materials Science · Physics 2016-12-22 Menghao Wu , Zhijun Wang , Junwei Liu , Huahua Fu , Lei Sun , Xin Liu , Minghu Pan , Hongming Weng , Mircea Dinca , Liang Fu , Ju Li

Luminescent multifunctional nanomaterials are important because of their potential impact on the development of key technologies such as smart luminescent sensors and solid-state lightings. To be technologically viable, the luminescent…

We present a comprehensive study of the band alignments of two-dimensional (2D) semiconducting materials and highlight the possibilities of forming momentum-matched type I, II and III heterojunctions; an enticing possibility being atomic…

Materials Science · Physics 2016-07-13 V. Ongun Özçelik , Javad G. Azadani , Ce Yang , Steven J. Koester , Tony Low

Mo2P as a new member of the advancing two-dimensional (2D) materials family has been theoretically identified in this study. We conducted extensive density functional theory calculations to explore the crystal structure, dynamical…

Materials Science · Physics 2017-09-18 Bohayra Mortazavi , Masoud Shahrokhi , Meysam Makaremi , Timon Rabczuk

The last several decades have seen significant advances in the theoretical modeling of materials within the fields of solid-state physics and materials science, but many methods commonly applied to this problem struggle to capture strong…

Strongly Correlated Electrons · Physics 2025-04-07 Anna O. Schouten , Simon Ewing , David A. Mazziotti

Two-dimensional (2D) black phosphorus (i.e., phosphorene) has become a rising star in electronics. Recently, 2D phosphorus oxides with higher stability have been synthesized. In this work, we systematically explore the structures and…

Materials Science · Physics 2016-05-11 Wei Luo , Hongjun Xiang

Building on discoveries in graphene and two-dimensional (2D) transition metal dichalcogenides, van der Waals (VdW) layered heterostructures - stacks of such 2D materials - are being extensively explored with resulting new discoveries of…

Materials Science · Physics 2022-10-20 Nicholas Ng , Tyrel M. McQueen

Recently synthesized two-dimensional (2D) boron, borophene, exhibits a novel metallic behavior rooted in the s-p orbital hybridization, distinctively different from other 2D materials such as sulfides/selenides and semi-metallic graphene.…

Solid materials are commonly classified as crystalline or amorphous based on the presence or absence of long-range order.Metal-organic frameworks (MOFs), like other solids,also display markedly different properties and functions in these…

2D materials find promising applications in next-generation devices, however, large-scale, low-defect, and reproducible synthesis of 2D materials remains a challenging task. To assist in the selection of suitable substrates for the…

Materials Science · Physics 2021-12-08 Tara M. Boland , Arunima K. Singh

The ability to control the size of the electronic bandgap is an integral part of solid-state technology. Atomically-thin two-dimensional crystals offer a new approach for tuning the energies of the electronic states based on the interplay…

Two-dimensional (2D) materials exhibit a wide range of electronic properties that make them promising candidates for next-generation nanoelectronic devices. Accurate prediction of their quantum transport behavior is therefore of both…

Materials Science · Physics 2025-12-22 Jijie Zou , Zhanghao Zhouyin , Qiangqiang Gu , Shishir Kumar Pandey

Discovery of intrinsic two-dimensional (2D) magnetic materials is crucial for understanding the fundamentals of 2D magnetism and realizing next-generation magnetoelectronic and magneto-optical devices. Although significant efforts have been…

Two-dimensional (2D) carbon-based materials have attracted considerable interest due to their diverse structural and electronic properties, making them ideal for next-generation flat electronics. Among these materials, metallic-like porous…

The presence of a direct band gap and an ultrathin form factor has caused a considerable interest in two-dimensional (2D) semiconductors from the transition metal dichalcogenides (TMD) family with molybdenum disulphide (MoS2) being the most…

Mesoscale and Nanoscale Physics · Physics 2014-09-24 Daria Krasnozhon , Dominik Lembke , Clemens Nyffeler , Yusuf Leblebici , Andras Kis

Two-dimensional (2D) materials and Transition Metal Dichalcogenides (TMD) in particular are at the forefront of nanotechnology. To tailor properties for engineering applications, alloying strategies used for bulk metals in the last century…

Materials Science · Physics 2022-12-14 Andrea Silva , Jiangming Cao , Tomas Polcar , Denis Kramer

The potential to utilize metal-organic frameworks as a replacement for rare earth materials as well as in technological applications has prompted increased interested in this material class. The simulation of organic materials, including…

Materials Science · Physics 2026-05-01 Alexander C. Tyner , Avinash Pathapati , Alexander V. Balatsky

Kagome lattices facilitate various quantum phases, yet in bulk materials, their kagome flat-bands often interact with bulk bands, suppressing kagome electronic characteristics for hosting these phases. Here, we use density-functional-theory…

Materials Science · Physics 2024-08-29 Jiaqi Dai , Zhongqin Zhang , Zemin Pan , Cong Wang , Chendong Zhang , Zhihai Cheng , Wei Ji

Layered two-dimensional (2D) semiconducting transition metal dichalcogenides (TMD) have been widely isolated, synthesized, and characterized recently. Numerous 2D materials are identified as the potential candidates as channel materials for…

Materials Science · Physics 2014-10-31 Yuchen Du , Lingming Yang , Han Liu , Peide D. Ye