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We argue that for generic systems close to a critical point, an extended Fluctuation-Dissipation relation connects the low frequency non-linear (cubic) susceptibility to the four-point correlation function. In glassy systems, the latter…

Statistical Mechanics · Physics 2009-11-11 Jean-Philippe Bouchaud , Giulio Biroli

Advances in high-precision dielectric spectroscopy has enabled access to non-linear susceptibilities of polar molecular liquids. The observed non-monotonic behavior has been claimed to provide strong support for theories of dynamic arrest…

Soft Condensed Matter · Physics 2021-07-07 Thomas Speck

We study theoretically the non-linear response properties of glass formers. We establish several general results which, together with the assumption of Time-Temperature Superposition, lead to a relation between the non-linear response and…

Statistical Mechanics · Physics 2009-12-19 Marco Tarzia , Giulio Biroli , Jean-Philippe Bouchaud , Alexandre Lefèvre

We review 15 years of theoretical and experimental work on the non-linear response of glassy systems. We argue that an anomalous growth of the peak value of non-linear susceptibilities is a signature of growing "amorphous order" in the…

Disordered Systems and Neural Networks · Physics 2021-01-12 Giulio Biroli , Jean-Philippe Bouchaud , Francois Ladieu

In this paper, we discuss theoretically the behavior of the four point nonlinear susceptibility and its associated correlation length for supercooled liquids close to the Mode Coupling instability temperature $T_c$. We work in the…

Disordered Systems and Neural Networks · Physics 2009-10-31 Silvio Franz , Giorgio Parisi

Glasses are ubiquitous in daily life and technology. However the microscopic mechanisms generating this state of matter remain subject to debate: Glasses are considered either as merely hyper-viscous liquids or as resulting from a genuine…

Disordered Systems and Neural Networks · Physics 2016-06-14 S. Albert , Th. Bauer , M. Michl , G. Biroli , J. -P. Bouchaud , A. Loidl , P. Lunkenheimer , R. Tourbot , C. Wiertel-Gasquet , F. Ladieu

Experimental measurements of nonlinear dielectric response in glassformers like supercooled glycerol or propylene carbonate have been interpreted as providing evidence for a growing thermodynamic length scale when lowering temperature. A…

Disordered Systems and Neural Networks · Physics 2026-01-08 Eric Bertin , François Ladieu

Within the framework of the effective potential theory of the structural glass transition, we calculate for the p-spin model a static nonlinear susceptibility related to a four-point density correlation function, and show that it grows and…

Disordered Systems and Neural Networks · Physics 2009-10-13 Claudio Donati , Silvio Franz , Giorgio Parisi , Sharon C. Glotzer

The ac nonlinear dielectric response $\chi_3(\omega,T)$ of glycerol was measured close to its glass transition temperature $T_g$ to investigate the prediction that supercooled liquids respond in an increasingly non-linear way as the…

Soft Condensed Matter · Physics 2015-05-18 C. Crauste-Thibierge , C. Brun , F. Ladieu , D. L'Hote , G. Biroli , J-P. Bouchaud

We use recently introduced three-point dynamic susceptibilities to obtain an experimental determination of the temperature evolution of the number of molecules, N_corr, that are dynamically correlated during the structural relaxation of…

We compare the slow dynamics of irreversible gels, colloidal gels, glasses and spin glasses by analyzing the behavior of the so called non-linear dynamical susceptibility, a quantity usually introduced to quantitatively characterize the…

Soft Condensed Matter · Physics 2015-06-25 A. Coniglio , T. Abete , A. de Candia , E. Del Gado , A. Fierro

Recent work has demonstrated the strong qualitative differences between the dynamics near a glass transition driven by short-ranged repulsion and one governed by short-ranged attraction. Here, we study in detail the behavior of non-linear,…

Statistical Mechanics · Physics 2010-04-16 P. Charbonneau , D. R. Reichman

The recently developed pragmatical model of asymmetric double-well potentials with a finite lifetime is applied to nonlinear dielectric data in polar undercooled liquids. The viscous effects from the finite lifetime provide a crossover from…

Disordered Systems and Neural Networks · Physics 2017-05-23 U. Buchenau

We have measured the linear dielectric susceptibility of two molecular glass formers close to Tg in order to estimate the size of the dynamically correlated clusters of molecules which are expected to govern the physics of glass formation.…

Statistical Mechanics · Physics 2009-11-13 François Ladieu , Caroline Thibierge , Denis L'Hôte

Existence and growth of amorphous order in supercooled liquids approaching glass transition is a subject of intense research. Even after decades of work, there is still no clear consensus on the molecular mechanisms that lead to a rapid…

Statistical Mechanics · Physics 2023-03-14 Rajsekhar Das , Saurish Chakrabarty , Smarajit Karmakar

We summarize current developments in the investigation of glassy matter using nonlinear dielectric spectroscopy. This work also provides a brief introduction into the phenomenology of the linear dielectric response of glass-forming…

Disordered Systems and Neural Networks · Physics 2017-08-30 P. Lunkenheimer , M. Michl , Th. Bauer , A. Loidl

The glass is a disordered solid that processes distinct dynamical and elastic properties compared with crystal. How heterogeneous glassy materials can be and to what extent dynamics is encoded with structure and elasticity are long-standing…

Soft Condensed Matter · Physics 2019-04-02 Bo Li , Kai Lou , Walter Kob , Steve Granick

When a liquid is cooled below its melting temperature, if crystallization is avoided, it forms a glass. This phenomenon, called glass transition, is characterized by a marked increase of viscosity, about 14 orders of magnitude, in a narrow…

Disordered Systems and Neural Networks · Physics 2008-08-23 Simone Capaccioli , Giancarlo Ruocco , Francesco Zamponi

The static and dynamic susceptibilities for a general class of mean field random orthogonal spherical spin glass models are studied. We show how the static and dynamical properties of the linear and nonlinear susceptibilities depend on the…

Disordered Systems and Neural Networks · Physics 2009-11-11 Leticia F. Cugliandolo , David S. Dean , Hajime Yoshino

Dynamic nonlinear (cubic) susceptibility in quantum d-dimensional Ising spin glass with short-range interactions is investigated on the basis of quantum droplet model and quantum-mechanical nonlinear response theory. Nonlinear response…

Disordered Systems and Neural Networks · Physics 2009-11-07 G. Busiello , R. V. Saburova , V. G. Sushkova
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