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It has recently been shown that configuration state functions (CSF) with local orbitals can provide a compact reference state for low-spin open-shell electronic structures, such as antiferromagnetic states. However, optimizing a low-spin…

Chemical Physics · Physics 2025-08-05 Hugh G. A. Burton

Ground state energies are obtained using the unrestricted Hartree Fock method for up to four interacting electrons parabolically confined in a quantum dot subject to a magnetic field. Restoring spin and rotational symmetries we recover Hund…

Mesoscale and Nanoscale Physics · Physics 2011-10-10 U. De Giovannini , F. Cavaliere , R. Cenni , M. Sassetti , B. Kramer

In this article, we set up a functional setting for mean-field electronic structure models of Hartree-Fock or Kohn-Sham types for disordered crystals. The electrons are quantum particles and the nuclei are classical point-like articles…

Mathematical Physics · Physics 2013-12-11 Eric Cancès , Salma Lahbabi , Mathieu Lewin

We calculate the ground state phase diagram of the homogeneous electron gas in three dimensions within the Hartree-Fock approximation and show that broken symmetry states are energetically favored at any density against the homogeneous…

Strongly Correlated Electrons · Physics 2014-03-04 Lucas Baguet , François Delyon , Bernard Bernu , Markus Holzmann

The coordinate-space representation of the Hartree-Fock-Bogoliubov theory is the method of choice to study weakly bound nuclei whose properties are affected by the quasiparticle continuum space. To describe such systems, we developed a…

Nuclear Theory · Physics 2022-03-28 Mengzhi Chen , Tong Li , Bastian Schuetrumpf , Paul-Gerhard Reinhard , Witold Nazarewicz

We investigate complex versions of the Korteweg-deVries equations and an Ito type nonlinear system with two coupled nonlinear fields. We systematically construct rational, trigonometric/hyperbolic, elliptic and soliton solutions for these…

Mathematical Physics · Physics 2015-03-19 Andrea Cavaglia , Andreas Fring , Bijan Bagchi

We present a density matrix approach for computing global solutions of Hartree-Fock theory, based on semidefinite programming (SDP), that gives upper and lower bounds on the Hartree-Fock energy of quantum systems. Equality of the upper- and…

Chemical Physics · Physics 2014-02-11 Srikant Veeraraghavan , David A. Mazziotti

The two-basis method to solve the HFB for deformed nuclei in coordinate space is examined concerning the precision of the density tail. Small cutoff energies are shown to give rise to ripples in the tail, whose wave length corresponds to…

Nuclear Theory · Physics 2007-05-23 Naoki Tajima

The stable and unstable manifolds of an invariant set of a piecewise-smooth map are themselves piecewise-smooth. Consequently, as parameters of a piecewise-smooth map are varied, an invariant set can develop a homoclinic connection when its…

Dynamical Systems · Mathematics 2016-08-03 David J. W. Simpson

In this manuscript we provide an outline of the numerical methods used in implementing the density constrained time-dependent Hartree-Fock (DC-TDHF) method and provide a few examples of its application to nuclear fusion. In this approach,…

Nuclear Theory · Physics 2015-02-16 V. E. Oberacker , A. S. Umar

We report Hartree-Fock (HF) based pseudopotentials suitable for plane-wave calculations. Unlike typical effective core potentials, the present pseudopotentials are finite at the origin and exhibit rapid convergence in a plane-wave basis;…

Materials Science · Physics 2008-02-28 W. A. Al-Saidi , E. J. Walter , A. M. Rappe

Microscopic methods and tools to describe nuclear dynamics have considerably been improved in the past few years. They are based on the time-dependent Hartree-Fock (TDHF) theory and its extensions to include pairing correlations and quantum…

Nuclear Theory · Physics 2018-09-13 C. Simenel , A. S. Umar

Projected Hartree-Fock theory (PHF) has a long history in quantum chemistry. PHF is here understood as the variational determination of an N-electron broken symmetry Slater determinant that minimizes the energy of a projected state with the…

Strongly Correlated Electrons · Physics 2013-06-28 Carlos A. Jimenez-Hoyos , Thomas M. Henderson , Takashi Tsuchimochi , Gustavo E. Scuseria

Classes of spontaneous symmetry breaking at zero and low magnetic fields in single quantum dots (QD's) and quantum dot molecules (QDM's) are discussed in relation to the ratio R_W between the interelectron Coulomb repulsion and the harmonic…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Constantine Yannouleas , Uzi Landman

Spin-singlet orders are studied for the antiferromagnetic Heisenberg model with spin $S$>1/2 on a breathing pyrochlore lattice, where tetrahedron units are weakly coupled and exchange constants have two values $0<J' \ll J$. The ground state…

Strongly Correlated Electrons · Physics 2017-02-16 Hirokazu Tsunetsugu

We discuss some recent results on the statistics of the Coulomb Blockade in disordered quantum dots containing spinless interacting fermions using the self-consistent Hartree-Fock approximation. We concentrate on the regime r_s >~1, with…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 Paul N. Walker , Gilles Montambaux , Yuval Gefen

The variational principle is used to build a model which describes open shell nuclei with ground state deformations. Hartree-Fock equations are solved by using single particle wave functions whose radial parts depend on the projection of…

Nuclear Theory · Physics 2021-07-22 G. Co , M. Anguiano , A. M. Lallena

We compute the electronic structure of acceptor clusters in silicon by using three methods to include electron correlations: the full configuration interaction, the Heitler-London approximation, and the unrestricted Hartree-Fock method. We…

Mesoscale and Nanoscale Physics · Physics 2021-09-15 Jianhua Zhu , Wei Wu , Andrew J. Fisher

The spherical Hartree-Fock approximation is applied to the $abinitio$ no-core shell model, with a realistic effective nucleon-nucleon interaction in order to investigate the range of its utility. Hartree-Fock results for binding energies,…

Nuclear Theory · Physics 2009-11-10 M. A. Hasan , J. P. Vary , P. Navratil

Self-consistent-field (SCF) approximations formulated using Hartree-Fock (HF) or Kohn-Sham Density Functional Theory (KS-DFT) both have the potential to yield multiple solutions. However, the formal relationship between multiple solutions…

Chemical Physics · Physics 2021-01-06 Rhiannon A. Zarotiadis , Hugh G. A. Burton , Alex J. W. Thom