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Ce(O,F)Sb(S,Se)2 single crystals were successfully grown using a CsCl/KCl flux method. The obtained crystals have a plate-like shape with the typical size of 1-2 mm and well-developed ab-plane, which enables X-ray single crystal structural…

Single crystal neutron diffraction is combined with synchrotron x-ray scattering to identify the different superlattice phases present in $Cs_{0.8}Fe_{1.6}Se_2$. A combination of single crystal refinements and first principles modelling are…

Ba2ScSbO6 (BSS) has been synthesized in polycrystalline form by solid state reaction. Structural characterization of the compound was done through X-ray diffraction (XRD) followed by Riedvelt analysis of the XRD pattern. The crystal…

Materials Science · Physics 2016-06-22 Rajyavardhan Ray , A K Himanshu , Uday Kumar , Pintu Sen , J. Lahiri , S K Bandyopadhyay , T. P. Sinha

The phase stability of the various crystalline structures of the super-heavy element Copernicium was determined based on the first-principles calculations with different levels of the relativistic effects. We utilized the Darwin term,…

Materials Science · Physics 2018-10-05 Hana Čenčariková , Dominik Legut

We report on the optical properties of CsPbBr3 polycrystalline thin film on a single grain level. A sample comprised of isolated nanocrystals (NCs) mimicking the properties of the polycrystalline thin film grains that can be individually…

Migration of halogen vacancies is one of the primary sources of phase segregation and material degradation in lead-halide perovskites. Here we use first principles density functional theory to compare migration energy barriers and paths of…

Materials Science · Physics 2021-07-07 Raisa-Ioana Biega , Linn Leppert

Using first-principles calculations, we study the dependence of the electronic and vibrational properties of multi-layered PbI 2 crystals on the number of layers and focus on the electronic-band structure and the Raman spectrum.…

Mesoscale and Nanoscale Physics · Physics 2018-09-26 Mehmet Yagmurcukardes , Francois M. Peeters , Hasan Sahin

The structural, electrical, optical, and mechanical characteristics of the lead-free halide double perovskites Cs2NaTlX6 X = F, Cl, Br are calculated by utilizing PBE functional within generalized gradient approximation GGA under the…

Materials Science · Physics 2023-02-07 Mohammed Mehedi Hasan , Nazmul Hasan , Alamgir Kabir

Recently, halide perovskites have gained significant attention from the perspective of efficient spintronics owing to Rashba effect. This effect occurs as a consequence of strong spin-orbit coupling under noncentrosymmetric environment,…

Single crystals of Cs2BiAgBr6 lead-free perovskite were grown by crystallization from supersaturated solution. According to characterization by XRD and EBSD methods the double perovskite single crystal are of the cubic Fm-3m symmetry with…

Zero dimensional perovskite Cs4PbBr6 has attracted considerable attention recently not only because of its highly efficient green photoluminescence (PL), but also its two highly debated opposing mechanisms of the luminescence: embedded…

Inorganic halide perovskites have become attractive for many optoelectronic applications due to their outstanding properties. While chemical synthesis techniques have been successful in producing high-quality perovskite crystals, scaling up…

Sb-substituted CeOBiS2 single crystals with 0.2-1.0 mm size have been successfully grown using CsCl/KCl flux. Sb substitution strongly suppressed the superconductivity in CeOBiS2, and the substitution of more than approximately 4 atomic…

Superconductivity · Physics 2023-12-19 Tatsuya Suzuki , Yuji Hanada , Masanori Nagao , Yuki Maruyama , Satoshi Watauchi , Isao Tanaka

The halide perovskites have truly emerged as efficient optoelectronic materials and show the promise of exhibiting nontrivial topological phases. Since the bandgap is the deterministic factor for these quantum phases, here we present a…

Materials Science · Physics 2021-03-31 Ravi Kashikar , Mayank Gupta , B. R. K. Nanda

Employing density functional theory based calculations, we investigate structural, vibrational and strain-dependent electronic properties of an ultra-thin CdTe crystal structure that can be de- rived from its bulk counterpart. It is found…

Mesoscale and Nanoscale Physics · Physics 2017-11-15 Fadil Iyikanat , Baris Akbali , Jun Kang , R. Tugrul Senger , Yusuf Selamet , Hasan Sahin

Halide perovskites belong to an important family of semiconducting materials with unique electronic properties that enable a myriad of applications, especially in photovoltaics and optoelectronics. Their optical properties, including…

Organic-inorganic halide perovskite solar cells have recently attracted much attention due to their low-cost fabrication, flexibility, and high-power conversion efficiency. The reduction from three- to two-dimension (2D) promises an…

Materials Science · Physics 2018-07-24 Rahul Singh , Prashant Singh , Ganesh Balasubramanian

In the present work, we study the magnetic properties of the NbS2 monolayer by first-principles calculations. The transition metal dichalcogenides (TMDC) are a family of laminar materials presenting exciting properties such as charge…

Mesoscale and Nanoscale Physics · Physics 2016-04-13 F. Güller , V. L. Vildosola , A. M. Llois

We have investigated the electronic structure of meta-stable perovskite Ca1-xSrxIrO3 (x = 0, 0.5, and 1) thin films using transport measurements, optical spectroscopy, and first-principles calculations. We artificially fabricated the…

Strongly Correlated Electrons · Physics 2015-05-14 S. Y. Jang , H. S. Kim , S. J. Moon , W. S. Choi , B. C. Jeon , J. Yu , T. W. Noh

The energetics and the electronic structure of methylammonium lead bromine (CH3NH3PbBr3) perovskite (001) surfaces are studied based on density functional theory. By examining the surface grand potential, we predict that the…

Materials Science · Physics 2016-11-30 Xin Huang , Tula R. Paudel , Peter A. Dowben , Shuai Dong , Evgeny Y. Tsymbal