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Mesoporous silica particles of MCM-41 type were synthesized by sol-gel method from tetraethyl orthosilicate (TEOS) in 2-methoxyethanol and deionized water mixture in base conditions at room temperature. Ammonia or sodium hydroxides were…

Mesoporous silica matrices have been prepared via classic acid catalyzed and sono-catalyzed sol-gel routes. Tetramethoxysilan (TMOS) and methyl-trimethoxysilane (MTMS) were used as silica precursors, and N-butyl-3-methylpyridinium…

Materials Science · Physics 2017-02-02 Ana-Maria Putz , Adél Len , Catalin Ianăşi , Cecilia Savii , László Almásy

We present an innovative template-free water-based sol-gel method to produce uniform mesoporous silica beads of millimeter size, which have tunable size, stiffness and porosity, and could be used for adsorption applications. Our protocol…

Soft Condensed Matter · Physics 2025-02-03 M. Milani , K. Ahmad , E. Cavalletti , C. Ligoure , L. Cipelletti , M. Kongkaew , P. Trens , L. Ramos

Mesoporous systems are ubiquitous in membrane science and applications due to their high internal surface area and tunable pore size. A new synthesis pathway of hydrolytic ionosilica films with mesopores formed by ionic liquid (IL)…

Aminopropyl modified mesoporous SiO2 nanoparticles, MCM-41 type, have been synthesized by the co-condensation method from tetraethylorthosilicate (TEOS) and aminopropyltriethoxysilane (APTES). By means of modifying TEOS/APTES ratio we have…

Tissues and Organs · Quantitative Biology 2021-03-24 M. V. Cabanas , D. Lozano , A. Torres-Pardo , C. Sobrino , J. Gonzalez-Calbet , D. Arcos , M. Vallet-Regi

In the past decade, the discovery of active pharmaceutical substances with high therapeutic value but poor aqueous solubility has increased, thus making it challenging to formulate these compounds as oral dosage forms. The bioavailability…

Biological Physics · Physics 2017-07-04 Smruti P. Chaudhari , Anshul Gupte

One pot synthetic technique was used to synthesize mesoporous fullerene using highly ordered mesoporous template such as KIT6-150 and SBA-15-150. Highly ordered porous fullerene with cross linkage between the fullerene molecules was…

Materials Science · Physics 2015-03-12 Sujit K. Mondal

We present several recently synthesized nanocomposites consisting of liquid crystals as well as an organic molecular crystal embedded into the nanochannels of mesoporous alumina and silica. As liquid-crystalline mesogens achiral, nematogen…

In this work the synthesis of ZrO$_{2}$-CeO$_{2}$ and ZrO$_{2}$-CeO$_{2}$/SiO$_{2}$ were developed, based on the process to form ordered mesoporous materials such as SBA-15 silica. The triblock copolymer Pluronic P-123 was used as template,…

Materials Science · Physics 2016-02-05 R. Bacani , T. S. Martins , D. G. Lamas , M. C. A. Fantini

Adsorption in nanoporous materials is one strategy that can be used to store hydrogen at conditions of temperature and pressure that are economically viable. Adsorption capacity of nanoporous materials depends on surface area which can be…

Materials Science · Physics 2024-05-28 Siddharth Gautam , David R. Cole , Zoltán Imre Dudás , Indu Dhiman

It is shown that porous spherical particles can be obtained via the freezing of silica nanoparticle aqueous suspensions emulsified in a continuous oil phase. After two freeze-thaw cycles, nanoparticles turn aggregated into flocculated…

Soft Condensed Matter · Physics 2020-05-26 Mathieu Nespoulous , Mickaël Antoni , Carine Chassigneux , Renaud Denoyel

Mesoporous silica particles are promising candidates for drug delivery applications. In this paper, we first synthesize mesoporous silica MCM-41 and its derivative MCM-41GA with anchored glutaraldehyde bridges, and characterize them using a…

Dense and mesoporous 4% mol Yttria-stabilized zirconia thin films were deposited on amorphous silica substrates. The effects of the temperature on the mesostructure were analyzed, by applying different thermal treatments to the samples…

Development of the new nanomaterial - the mesoporous Ge - by bipolar electrochemical etching (BEE) and analysis of its physico-chemical properties is the subject of this thesis. Formation of mesoporous Ge by electrochemical etching was…

Materials Science · Physics 2014-02-12 Sergii Tutashkonko

We combine for the first time the properties of ordered mesoporous thin films and complex oxide nanoparticles in the design of new heterostructures, taking advantage of the accessible tridimensional pores network. In this work, we…

Mesoscale and Nanoscale Physics · Physics 2026-01-01 S. Passanante , M. Quintero , A. Zelcer , M. S. Moreno , D. Lionello , D. Vega , L. P. Granja

Silicon nanowires are prepared by the method of the two-step metal-assisted wet chemical etching. We have analyzed the structure of solid, rough and porous nanowire surfaces of boron-doped silicon substrates with resistivities of \rho >…

Microporous organosilicas assembled from polysilsesquioxane (POSS) building blocks are promising materials that are yet to be explored in-depth. Here, we investigate the processing and molecular structure of bispropylurea bridged POSS…

Microemulsion (water-in-oil) methods enable the encapsulation of individual nanoparticles into SiO2 spheres. The major drawbacks of this method, when applied for silica encapsulation of anisotropic nanorods (NRs), are a spatially unequal…

Chemical Physics · Physics 2017-10-18 Xiao Tang , Elvira Kröger , Andreas Nielsen , Christian Strelow , Alf Mews , Tobias Kipp

We present a capacitance method to measure the adsorption of rod-like nematogens (4-cyano-4'-pentylbiphenyl, 5CB) from a binary liquid 5CB/methanol solution into a monolithic mesoporous silica membrane traversed by tubular pores with radii…

Soft Condensed Matter · Physics 2021-10-04 Andriy V. Kityk , Gennady Y. Gor , Patrick Huber

Tuberculosis remains today a major public health issue with a total of 9 million new cases and 2 million deaths annually. The lack of an effective vaccine and the increasing emergence of new strains of Mycobacterium tuberculosis (Mtb)…

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