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Gas-liquid criticality in ionic fluids is studied in exactly soluble spherical models that use interlaced sublattices to represent hard-core \textit{multi}component systems. Short range attractions in the uncharged fluid drive criticality…

Statistical Mechanics · Physics 2009-11-10 Jean-Noel Aqua , Michael E. Fisher

In this article, we study the transport properties of superconcentrated electrolytes using Molecular Dynamics simulations, which have been shown experimentally to retard elemental dissolution in vanadium containing cathode materials. Five…

Materials Science · Physics 2021-11-30 Arijit Mitra , Saptarshi Das , Debasish Das , Subhasish B. Majumder , Siddhartha Das

The exceptional physicochemical properties and versatile biological activities of ionic liquids (ILs) have propelled their potential applications in various industries, including pharmaceuticals and green chemistry. However, their…

Soft Condensed Matter · Physics 2024-07-29 J. Gupta , V. K. Sharma , P. Hitaishi , H. Srinivasan , S. Kumar , S. K. Ghosh , S. Mitra

In this tutorial we discuss the chemical potential of ions in water (i.e., in a salt solution, in an electrolyte phase) and inside (charged) nanoporous materials such as porous membranes. In water treatment, such membranes are often used to…

Chemical Physics · Physics 2025-06-25 P. M. Biesheuvel

Two-dimensional moir\'e superlattices have been extensively studied, and a variety of correlated phenomena have been observed. However, their lower-dimensional counterpart, one-dimensional (1D) moir\'e superlattices, remain largely…

Colossal Ion Conductivity (CIC) is the phenomenon in which large changes in oxygen conductivity are observed when a solid state oxygen electrolyte is placed in a heterolayer super lattice. Several hypotheses have been posed concerning both…

Materials Science · Physics 2019-01-04 M. F. Francis

Mechanosensitive ion nanochannels regulate transport by undergoing conformational changes within nanopores. However, achieving precise control over these conformational states remains a major challenge for both artificial soft or solid…

Chemical Physics · Physics 2026-01-06 Ke Zhou

Future lithium-based batteries are expected to use solid electrolytes to achieve higher energy density and fast charge capabilities. The majority of solid electrolytes are thermodynamically unstable against layered oxide cathodes. Here, the…

Ionic Seebeck effect of electrolytes has shown promising applications in harvesting energy from low-grade waste-heat sources with small temperature difference from the environment, which can power sensors and Internet-of-Things devices.…

Soft Condensed Matter · Physics 2022-02-03 Xin Qian , Te-Huan Liu , Ronggui Yang

Ion transport through nanopores permeates through many areas of science and technology, from cell behavior to sensing and separation to catalysis and batteries. Two-dimensional materials, such as graphene, molybdenum disulfide (MoS$_2$),…

Mesoscale and Nanoscale Physics · Physics 2019-07-19 Subin Sahu , Michael Zwolak

Functoinal polymers can be used as electrolyte and binder materials in solid-state batteries. This often requires performance targets in terms of both transport and mechanical properties. In this work, a model ionic conductive polymer…

Soft Condensed Matter · Physics 2023-11-15 Harish Gudla , Kristina Edström , Chao Zhang

We demonstrate in this paper that the recently discovered infinite-layer (IL) nickelates have much in common with a class of materials known as electrides. Oxide based electrides are compounds in which topotactic removal of loosely bound…

Superconductivity · Physics 2023-11-30 Kateryna Foyevtsova , Ilya Elfimov , George A. Sawatzky

Lubricant-infused surfaces (LISs) can promote stable dropwise condensation and improve heat transfer rates due to a low nucleation free-energy barrier and high droplet mobility. Topographical differences in the oil surface cause water…

Fluid Dynamics · Physics 2021-11-02 Jianxing Sun , Xinyu Jiang , Patricia B. Weisensee

The addition of filler particles to polymer electrolytes is known to increment their ionic conductivity (IC). A detailed understanding of how the interactions between the constituent materials are responsible for the enhancement, remains to…

Materials Science · Physics 2021-03-19 Andres Villa , Juan Carlos Verduzco , Joseph A. Libera , Ernesto E. Marinero

New ionic liquids (ILs) are continuously introduced involving an increasing number of organic and inorganic ions. Amino acid based ILs (AAILs) represent a specific interest due to their natural origin and, allegedly, low cost. We apply our…

Materials Science · Physics 2014-12-09 Vitaly V. Chaban , Eudes Eterno Fileti

Understanding the bulk and interfacial properties of super-concentrated electrolytes, such as ionic liquids (ILs), has attracted significant attention lately for their promising applications in supercapacitors and batteries. Recently,…

Ion transport in extremely narrow nanochannels has gained increasing interest in recent years due to its unique physical properties, and the technological advances that allow us to study them. It is tempting to approach this regime with the…

Soft Condensed Matter · Physics 2020-02-11 Amir Levy , J. Pedro de Souza , Martin Z Bazant

We report a comprehensive study on the electrochemical performance of four different Transition Metal Oxides encapsulated inside carbon nanotubes (CNT). Irrespective of the type of oxide-encapsulate, all these samples exhibit superior…

We report the first observation of intermolecular Coulombic decay (ICD) in liquid water following inner-valence ionization. By combining a monochromatized table-top high-harmonic source with a liquid micro-jet, we recorded electron-electron…

Atomic and Molecular Clusters · Physics 2022-04-05 Pengju Zhang , Conaill Perry , Tran Trung Luu , Danylo Matselyukh , Hans Jakob Wörner

Ionic liquids have generated interest in applications as lubricants and as additives to conventional lubricants due to their unique physical properties. In these applications, the liquid thin film can be subjected simultaneously to…

Soft Condensed Matter · Physics 2023-04-17 Kalil Bernardino , Mauro C. C. Ribeiro