Related papers: Bi-layer-dimerized chiral liquid crystals
Under an electric field, chiral smectic liquid crystals transit usually to the unwound SmC* phase where the helical structure is completely unrolled. Sometimes the sample transits initially towards an intermediate polar state before the…
The biaxial smectic-A* (Sm-A_B*) phase, appearing in the phase sequence Sm-A*--Sm-A*_B--Sm-C*, is analyzed using Landau theory. It is found to possess a helical superstructure with a pitch that is significantly shorter than the pitch of the…
Recently Wang et al. [Phys. Rev. Lett. 104, 027801 (2010)] discovered a new polar smectic phase with six-layer period (SmC*d6). In this manuscript, we demonstrate that the theory [Phys. Rev. E 67, 041716 (2003)] based on the free energy…
Recently we have formulated theory of bi-layer-dimerized chiral liquid antiferroelectric crystals. The spontaneous polarization has been increased owing to the strong interaction of the aromatic cores of the rod like liquid crystal…
In many biological materials with a hierarchical structure there is an intriguing and unique mechanism responsible for the 'propagation' of order from the molecular to the nano- or micro-scale level. Here we present a much simpler molecular…
Chiral smectic liquid crystals exhibit a series of phases, including ferroelectric, antiferroelectric and ferrielectric commensurate structures as well as an incommensurate SmCalpha phase. We carried out an extension of the phenomenological…
Recent experiments have found a bent-core liquid crystal in which the layer chirality alternates from layer to layer, giving a racemic or "antichiral" material, even though the molecules are uniformly chiral. To explain this effect, we map…
Phenomenological model of chiral polar smectics is introduced with interactions up to the fourth neighboring layers. The minimization of the free energy gives three stable structures: the ferroelectric Sm C$^*$ phase, the antiferroelectric…
We introduce novel higher-order topological phases of matter in chiral-symmetric systems (class AIII of the tenfold classification), most of which would be misidentified as trivial by current theories. These phases are protected by…
We demonstrate that the sequence of distorted commensurate phases observed in tilted chiral smectics is explained by the gain in electrostatic energy due to the lock-in of the unit cell to a number of layers which is the integer closest to…
Smectic liquid crystals are charcterized by layers that have a preferred uniform spacing and vanishing curvature in their ground state. Dislocations in the smectics play an important role in phase nucleation, layer reorientation, and…
Recently, a new class of smectic liquid crystal phases (SmCP phases) characterized by the spontaneous formation of macroscopic chiral domains from achiral bent-core molecules has been discovered. We have carried out Monte Carlo simulations…
It is demonstrated by analyzing real examples that phase transitions in layered crystals occur like all other solid-state phase transitions by nucleation and crystal growth, but have a specific morphology. There the nucleation is epitaxial,…
The order parameter of the smectic liquid crystal phase is the same as that of a superfluid or superconductor, namely a complex scalar field. We show that the essential difference in boundary conditions between these systems leads to a…
We propose a continuum tensorial model for chiral smectic C (SmC$^*$) liquid crystals using a tensor-valued order parameter $\mathbf{Q}$ to describe orientational order and a real-valued order parameter $\delta\rho$ to capture layer…
We propose an experimental scheme to effectively assemble chains of dipolar gases with an uniform length in a multi-layer system. The obtained dipolar chains can form a chain crystal with the system temperature easily controlled by the…
A material showing a sequence of three ferroelectric liquid crystalline phases below the paraelectric nematic phase has been synthesized and studied. The polar order of molecules appearing due to the dipole-dipole interactions in the NF…
We explore the possibility that the large electroclinic effect observed in ferroelectric liquid crystals arises from the presence of an ordered array of disclination lines and walls. If the spacing of these defects is in the subvisible…
The smectic C (smC) phase represents a unique class of liquid crystal phases characterised by the layered arrangement of molecules with tilted orientations with respect to layer normals. Building upon the real-valued tensorial smectic A…
We have structurally characterized the liquid crystal phase that appears as an intermediate state when a dielectric nematic, having polar disorder of its molecular dipoles, transitions to the almost perfectly polar-ordered ferroelectric…