Related papers: Effective Polarisability Models
The Polarizable Continuum Model (PCM) can be used in conjunction with Density Functional Theory (DFT) and its time-dependent extension (TDDFT) to simulate the electronic and optical properties of molecules and nanoparticles immersed in a…
The van der Waals potential of two atoms in the presence of an arbitrary arrangement of dispersing and absorbing magnetodielectric bodies is studied. Starting from a polarizable atom placed within a given geometry, its interaction with a…
We introduce a numerical method that enables efficient modelling of light scattering by large, disordered ensembles of non-spherical particles incorporated in stratified media, including when the particles are in close vicinity to each…
Multiple scattering of polarised electromagnetic waves in diffusive media is investigated by means of radiative transfer theory. The method becomes exact in several situations of interest, such as a thick-slab experiment (slab thickness L…
We study the electromagnetic behaviour of dense, spherical clusters made of hundreds of plasmonic nanoparticules under illumination by a plane wave. Using high-precision T-matrix numerical calculations, we compute the multipolar response of…
The dielectric properties of molecules or nanostructures are usually modified in a complex manner, when assembled into a condensed phase. We propose a first-principles method to compute polarizabilities of sub-entities of solids and…
We model the conservation of energy in the framework of the thin layer approximation for two types of interstellar medium (ISM). In particular, we analyse an ISM in the presence of self-gravity and a Gaussian ISM which produces an asymmetry…
The effective interaction between two planar walls immersed in a fluid is investigated by use of Density Functional Theory in the super-critical region of the phase diagram. A hard core Yukawa model of fluid is studied with special…
We introduce an effective modes formalism to describe how the quasi-continuum of photonic modes in an optical cavity effectively behaves in the strong light-matter coupling regime of cavity quantum electrodynamics. By expressing these…
We consider binary mixtures of soft repulsive spherical particles and calculate the depletion interaction between two big spheres mediated by the fluid of small spheres, using different theoretical and simulation methods. The validity of…
Hard spheres are a central and important model reference system for both homogeneous and inhomogeneous fluid systems. In this paper we present new high-precision molecular-dynamics computer simulations for a hard sphere fluid at a planar…
The screening of an individual low-dimensional object can be strongly influenced by the objects nearby. We propose that such environment's influence can be absorbed into an effective polarizability, instead of its intrinsic polarizability.…
We estimate polarizabilities of atoms in molecules without electron density, using a Voronoi tesselation approach instead of conventional density partitioning schemes. The resulting atomic dispersion coefficients are calculated, as well as…
It is found that there exist composite media that exhibit strong spatial dispersion even in the very large wavelength limit. This follows from the study of lattices of ideally conducting parallel thin wires (wire media). In fact, our…
We report a Monte Carlo simulation study of the properties of highly asymmetric binary hard sphere mixtures. This system is treated within an effective fluid approximation in which the large particles interact through a depletion potential…
The present paper - a continuation of our recent series of papers on Casimir friction for a pair of particles at low relative particle velocity - extends the analysis so as to include dense media. The situation becomes in this case more…
We consider the Asakura-Oosawa model of hard sphere colloids and ideal polymers in contact with a porous matrix modeled by immobilized configurations of hard spheres. For this ternary mixture a fundamental measure density functional theory…
Free-space optical (FSO) communication can be subject to various types of distortion and loss as the signal propagates through non-uniform media. In experiment and simulation, we demonstrate that the state of polarization and degree of…
We apply near-field matter-wave interferometry to determine the absolute scalar polarizability of the fullerenes C$_{60}$ and C$_{70}$. A key feature of our experiment is the combination of good transmission and high spatial resolution,…
A multilayered effective medium model is proposed to calculate the contribution of surface roughness to the Casimir force. In this model the rough layer has its optical properties derived from an effective medium approximation, with the…