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This paper presents a thermodynamically consistent model for multicomponent electrolyte solutions. The first part of this paper derives the general governing equations for nonequilibrium systems within the theory of nonequilibrium…

Analysis of PDEs · Mathematics 2016-05-25 Matthias Herz , Peter Knabner

The search for thermodynamic admissibility moreover reveals a fundamental difference between liquids and gases in relativistic fluid dynamics, as the reversible convection mechanism is much simpler for liquids than for gases. In…

General Relativity and Quantum Cosmology · Physics 2019-01-16 Laura Stricker , Hans Christian Öttinger

This paper investigates the asymptotic behavior of a hyperbolic relaxation system designed for homogeneous two-phase flows in the limit of vanishing relaxation time. The governing equations comprise conservation laws for mixture mass and…

Analysis of PDEs · Mathematics 2026-03-19 Huimin Yu

In continuum thermodynamics, models of two-phase mixtures typically obey the condition of pressure equilibrium across interfaces between the phases. We propose a new non-equilibrium model beyond that condition, allowing for microinertia of…

Fluid Dynamics · Physics 2023-12-18 Ilya Peshkov , Evgeniy Romenski , Michal Pavelka

A general diffuse interface model with a realistic equation of state (e.g. Peng-Robinson equation of state) is proposed to describe the multi-component two-phase fluid flow based on the principles of the NVT-based framework which is a…

Numerical Analysis · Mathematics 2016-11-29 Jisheng Kou , Shuyu Sun

This work expands on our recently introduced low Mach enthalpy method [1] for simulating the melting and solidification of a phase change material (PCM) alongside (or without) an ambient gas phase. The method captures PCM's volume change…

Fluid Dynamics · Physics 2025-03-11 Ramakrishnan Thirumalaisamy , Amneet Pal Singh Bhalla

We present general calculations allowing to express the thermodynamical coefficients and thermophysical properties (compressibility, thermal coefficients and heat capacities) of a material composed of a mixture of two constituents or…

Classical Physics · Physics 2021-08-24 S Benjelloun , R. Boukharfane

In this paper, we consider mathematical modeling and numerical simulation of non-isothermal compressible multi-component diffuse-interface two-phase flows with realistic equations of state. A general model with general reference velocity is…

Numerical Analysis · Mathematics 2018-08-15 Jisheng Kou , Shuyu Sun

This study uses continuum thermodynamics of pure thermoelastic fluids to examine their phase transformation. To examine phase transformation kinetics, a special emphasis is placed on the jump condition for the axiom of entropy inequality,…

Statistical Mechanics · Physics 2022-07-29 Gerard A. Ateshian , Jay J. Shim

We present a novel approach to kinetic theory modeling enabling the simulation of a generic, real gas presented by its corresponding equation of state. The model is based on mass, momentum and energy conservation, and unlike the lattice…

Fluid Dynamics · Physics 2020-02-25 Ehsan Reyhanian , Benedikt Dorschner , Ilya Karlin

The paper concerns the construction of a compressible liquid-vapor relaxation model which is able to capture the metastable states of the non isothermal van der Waals model as well as saturation states. Starting from the Gibbs formalism, we…

Analysis of PDEs · Mathematics 2019-11-01 Hala Ghazi , Francois James , Hélène Mathis

In this paper, we present a numerical scheme for the diffuse-interface model in [Abels, Garcke, Gr\"un, M3AS 22(3), 2012] for two-phase flow of immiscible, incompressible fluids. As that model is in particular consistent with…

Numerical Analysis · Mathematics 2012-10-19 Günther Grün , Fabian Klingbeil

The liquid-gas phase transition in finite nuclei is studied in a heated liquid-drop model where the drop is assumed to be in thermodynamic equilibrium with the vapour emanated from it. Changing pressure along the liquid-gas coexistence line…

Nuclear Theory · Physics 2007-05-23 Tapas Sil , S. K. Samaddar , J. N. De , S. Shlomo

Fluid polyamorphism, the existence of multiple amorphous fluid states in a single-component system, has been observed or predicted in a variety of substances. A remarkable example of this phenomenon is the fluid-fluid phase transition in…

Soft Condensed Matter · Physics 2022-09-21 Nathaniel R. Fried , Thomas J. Longo , Mikhail A. Anisimov

The diffuse medium in and around galaxies can exist in a multi-phase state: small, cold gas clouds contributing significantly to the total mass embedded in pressure equilibrium with a hotter, more diffuse volume-filling component. Modeling…

Astrophysics of Galaxies · Physics 2022-12-28 Rainer Weinberger , Lars Hernquist

Evaporation of liquid into a vapor-gas mixture is interesting and important process as for fundamental research and for different applications. In general, the rate at which a liquid evaporates is dependent on the transport of mass and…

Fluid Dynamics · Physics 2013-07-11 A. A. Gorbunov , A. P. Kryukov , V. Yu Levashov

A general thermodynamic treatment of dissipative relativistic fluids is introduced, where the temperature four vector is not parallel to the velocity field of the fluid. Generic stability and kinetic equilibrium points out a particular…

General Relativity and Quantum Cosmology · Physics 2014-05-27 P. Ván , T. S. Biró

The thermodynamic approach to non-equilibrium dynamics describes the state of macroscopic systems by means of a collection of intensities or intensive variables. The latter are by definition the differentials of the entropy with respect to…

chao-dyn · Physics 2008-02-03 Z. Hens , X. de Hemptinne

Atmospheric systems incorporating thermal dynamics must be stable with respect to both energy and entropy. While energy conservation can be enforced via the preservation of the skew-symmetric structure of the Hamiltonian form of the…

Numerical Analysis · Mathematics 2023-10-31 Kieran Ricardo , David Lee , Kenneth Duru

Quantum thermodynamics with open systems is often based on the quantum optical weak-coupling master equation or on operational repeated interaction models, whereas early works on thermalisation and on decoherence theory were mostly…

Quantum Physics · Physics 2025-06-27 Michael Gaida , Giulio Gasbarri , Stefan Nimmrichter
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