Related papers: Topological Methods for Polymeric Materials: Chara…
The linear viscoelastic response of single semiflexible polymer chains in the infinite-dilution limit is studied using Brownian dynamics simulations of coarse-grained bead-spring chains. The springs obey the FENE-Fraenkel force law, a…
We examine in details the connections between topological and entanglement properties of short-range resonating valence bond (RVB) wave functions using Projected Entangled Pair States (PEPS) on kagome and square lattices on (quasi-)infinite…
A brief report is presented on the effect of viscoelastic losses in a high density contrast sonic band-gap material of close-packed rubber spheres in air. The scattering properties of such a material are computed with an on-shell multiple…
We study the viscoelastic properties of highly entangled, flexible, self-propelled polymers using Brownian dynamics simulations. Our results show that the active motion of the polymer increases the height of the stress plateau by orders of…
The rheological behavior of polymer melts is strongly influenced by parameters such as chain length, chain stiffness, and architecture. In particular, shear thinning, characterized by a power-law decrease in shear viscosity with increasing…
Macroscale chains have been proposed to give insight into the physics of molecular polymer systems. Nevertheless, understanding the rheological response of systems of quasi-one-dimensional semiflexible materials, such as bead-chain…
In this paper, we consider a contact problem with adhesion between a viscoelastic body and a rigid support, taking thermal effects into account. The PDE system we deal with is derived within the modelling approach proposed by M. Fremond…
Here we investigate the connection between topological order and the geometric entanglement, as measured by the logarithm of the overlap between a given state and its closest product state of blocks. We do this for a variety of…
Entangled networks are ubiquitous in tissues, polymers, and fabrics. However, their mechanics remain insufficiently understood due to the complexity of the topological constraints at the network level. Here, we develop a mathematical…
Quantum entanglement and classical topology are two distinct phenomena that are difficult to be connected together. Here we discover that an open bosonic quadratic chain exhibits topology-induced entanglement effect. When the system is in…
Polymer rings in solution are either permanently entangled or not. Permanent topological restrictions give rise to additional entropic interactions apart from the ones arising due to mere chain flexibility or excluded volume. Conversely,…
We consider a continuum model of active viscoelastic matter, whereby an active nematic liquid-crystal is coupled to a minimal model of polymer dynamics with a viscoelastic relaxation time $\tau_C$. To explore the resulting interplay between…
Entangled granular systems exhibit mechanical rigidity and resistance to deformation, reminiscent of cohesive materials, due to their reduced degrees of freedom and contact friction. A quantitative understanding of how classical granular…
Constitutive equations are derived for the time-dependent behavior of particle-reinforced elastomers at isothermal loading with finite strains. A rubbery polymer is modelled as a network of macromolecules bridged by junctions which can slip…
Conformational transitions are ubiquitous in biomolecular systems, have significant functional roles and are subject to evolutionary pressures. Here we provide a first theoretical framework for topological transition, i.e. conformational…
Wetting and drying phenomena are studied for flexible and semiflexible polymer solutions via coarse-grained molecular dynamics simulations and density functional theory calculations. The study is based on the use of Young's equation for the…
In this work we study the nature of correlations among mixed states in the setup of two symmetric strips. We use various tools to determine how the bulk geometry could be reconstructed from the boundary mixed information. These tools would…
A phenomenological model on the relationship between viscoelasticity and flexoelectricity is proposed to address the electromechanical coupling under rheological processes in viscoelastic materials. Our theoretical studies show that some…
Primitive path analyses of entanglements are performed over a wide range of chain lengths for both bead spring and atomistic polyethylene polymer melts. Estimators for the entanglement length N_e which operate on results for a single chain…
We consider concentration dependence of rheological properties of associative telechelic polymer solutions. Experimental results for model telechelic polymer solutions show rather strong concentration dependence of rheological properties.…