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Time-dependent density-functional theory simulations are performed to examine the effects of varying incident points and kinetic energies of hydrogen atom projectiles on a graphene-like structure. The simulations reveal that the incident…

Materials Science · Physics 2024-12-11 Samuel S. Taylor , Nicholas Skoufis , Hongbo Du , Cody Covington , Kalman Varga

We present a first-principles study of the atomic hydrogen adsorption onto the Be(10\={1}0) thin film. There are two types of Be(10\={1}0) surfaces according to the interlayer spacing between the surface and its nearest-neighbor layer. We…

Materials Science · Physics 2007-05-23 Ping Zhang , Hong-Zhou Song

We have studied the adsorption of Li atoms at the hollow sites of graphene nanoribbons (zigzag and armchair), graphene, and fullerenes by means of density functional theory calculations including local and semilocal functionals. The binding…

Materials Science · Physics 2015-05-14 Chananate Uthaisar , Veronica Barone , Juan E. Peralta

We investigated a suspended bilayer graphene where the bottom (top) layer is doped by boron (nitrogen) substitutional atoms by using Density Functional Theory (DFT) calculations. We found that at high dopant concentration (one B-N pair…

Materials Science · Physics 2016-05-25 Daniele Giofré , Davide Ceresoli , Mario I. Trioni

Adsorption of benzoic acid on the (110) surface of rutile, both unreconstructed and (1x2)- reconstructed ones, at saturation coverage of one benzoate per two adjacent five-coordinated Ti5c sites has been studied using DFT simulations, as…

Materials Science · Physics 2014-07-08 Xiang Zhao , David R. Bowler

Based on the first-principles plane wave calculations, we showed that Ca adsorbed on graphene can serve as a high-capacity hydrogen storage medium, which can be recycled by operations at room temperature. Ca is chemisorbed by donating part…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 C. Ataca , E. Akturk , S. Ciraci

It is shown that adsorption energy at semiconductor surfaces critically depends on the charge transfer to or from the adsorbed species. For the processes without the charge transfer, such as molecular adsorption of closed shell systems, the…

Materials Science · Physics 2013-08-23 Paweł Kempisty , Paweł Strak , Konrad Sakowski , Stanisław Krukowski

The anchoring of benzene molecules on lithium adsorption sites at the surface of graphene and nanoribbons thereof are investigated. The effects of adsorbate densities, specific adsorption locations, and spin states on the structural…

Materials Science · Physics 2013-10-01 Dana Krepel , Oded Hod

We investigated the adsorption of a single atom, hydrogen and aluminum, on single wall carbon nanotubes from first-principles. The adsorption is exothermic, and the associated binding energy varies inversely as the radius of the zigzag…

Materials Science · Physics 2009-11-07 O. Gulseren , T. Yildirim , S. Ciraci

First-principles calculations reveal that the adsorption of representative first-row atoms with different electronegativity, such as lithium (Li), carbon (C) and fluorine (F), on zigzag single-walled boron nitride nanotubes (BNNTs) exhibits…

Materials Science · Physics 2007-05-23 Jia Li , Gang Zhou , Haitao Liu , Wenhui Duan

We show, with both experiment and theory, that adsorption of $CO_2$ is sensitive to charge on a capturing model carbonaceous surface. In the experiment we dope superfluid helium droplets with $C_{60}$ and $CO_2$ and expose them to ionising…

Atomic and Molecular Clusters · Physics 2016-09-06 Stefan Ralser , Alexander Kaiser , Michael Probst , Johannes Postler , Michael Renzler , Diethard K. Bohme , Paul Scheier

Motivated by the recent realization of graphene sensors to detect individual gas molecules, we investigate the adsorption of H2O, NH3, CO, NO2, and NO on a graphene substrate using first-principles calculations. The optimal adsorption…

Materials Science · Physics 2009-11-13 O. Leenaerts , B. Partoens , F. M. Peeters

In order to identify potential hydrogen storage materials, worldwide attention has been focused on hydrides with high gravimetric and volumetric capacity. Hydrogen is a unique element that possess positive, negative or neutral oxidation…

Materials Science · Physics 2019-02-14 S Kiruthika , H. Fjellvag , P Ravindran

The chapter generalizes results on influence of uniaxial strain and adsorption on the electron states and charge transport or localization in graphene with different configurations of imperfections (point defects): resonant (neutral)…

We evaluate the rate of the absorption of an optical nanofiber mode by a Cs atom in an electric quadrupole transition. With the Cs atom localized near the outer surface of the optical nano-fiber, an interaction occurs between the atomic…

Optics · Physics 2023-10-20 Smail Bougouffa , Mohamed Babiker

We employ dispersion-corrected density-functional theory to study the adsorption of tetrapyrrole 2H-porphine (2H-P) at Cu(111) and Ag(111). Various contributions to adsorbate-substrate and adsorbate-adsorbate interactions are systematically…

Chemical Physics · Physics 2016-09-05 Moritz Müller , Katharina Diller , Reinhard J. Maurer , Karsten Reuter

Heterostructures made of stacked 2D materials with different electronic properties are studied for their potential in creating multifunctional devices. Graphene (G) and hexagonal boron nitride (h-BN) van der Waals (vdW) systems have been…

Materials Science · Physics 2023-03-16 D. P. de Andrade Deus , J. M. J. Lopes , Roberto H. Miwa

Ab initio self-consistent total energy calculations using second order Moller-Plesset perturbation theory and Hay-Wadt effective core potentials for gallium and arsenic have been used to investigate the chemisorption of atomic oxygen on the…

Condensed Matter · Physics 2007-05-23 Michael L. Mayo , Asok K. Ray

We present a theory to study gas molecules adsorption on armchair graphene nanoribbons (AGNRs) by applying the results of \emph{ab} \emph{initio} calculations to the single-band tight-binding approximation. In addition, the effect of edge…

Mesoscale and Nanoscale Physics · Physics 2010-06-04 Alireza Saffarzadeh

We compare the density functional theory (DFT) results on the adsorption of small aromatic molecules (benzene, pyridine and thiophene) on gold surfaces obtained by using three types of van der Waals exchange-correlation functionals and…

Chemical Physics · Physics 2014-02-05 Luiza Buimaga-Iarinca , Cristian Morari