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I will argue, pace a great many of my contemporaries, that there's something right about Boltzmann's attempt to ground the second law of thermodynamics in a suitably amended deterministic time-reversal invariant classical dynamics, and that…

History and Philosophy of Physics · Physics 2021-06-02 Christopher Gregory Weaver

Due to the second principle of thermodynamics, the time dependence of entropy for all kinds of systems under all kinds of physical circumstances always thrives interest. The logistic map $x_{t+1}=1-a x_t^2 \in [-1,1]\;(a\in [0,2])$ is…

Statistical Mechanics · Physics 2023-05-02 Constantino Tsallis , Ernesto P. Borges

The second law of nonequilibrium thermodynamics within the open system paradigm (a small system coupled to one or multiple baths) is derived. This is done by showing positivity of entropy production for arbitrary Hamiltonian dynamics for a…

Statistical Mechanics · Physics 2020-08-28 Philipp Strasberg

We brief{}ly review the connection between statistical mechanics and thermodynamics. We show that, in order to satisfy thermodynamics and its Legendre transformation mathematical frame, the celebrated Boltzmann-Gibbs~(BG) statistical…

Statistical Mechanics · Physics 2014-11-03 Constantino Tsallis , Leonardo J. L. Cirto

Large entropy fluctuations in a nonequilibrium steady state of classical mechanics were studied in extensive numerical experiments on a simple 2-freedom model with the so-called Gauss time-reversible thermostat. The local fluctuations (on a…

Chaotic Dynamics · Physics 2009-10-31 Boris Chirikov

We review the behaviour of the Gibbs' and conditional entropies in deterministic and stochastic systems and continue to a formulation appropriate for a stochastically perturbed system with delayed dynamics. The underlying question driving…

Mathematical Physics · Physics 2024-06-24 Michael C. Mackey , Marta Tyran-Kaminska

Emergence of one-time-direction macroscopic evolution of a classical system of two mixed gases having different temperatures is derived and explained. The analysis performed at the microscopic level, where the time-symmetric laws of…

Classical Physics · Physics 2016-08-11 Krzysztof Rębilas

Ergodicity, this is to say, dynamics whose time averages coincide with ensemble averages, naturally leads to Boltzmann-Gibbs (BG) statistical mechanics, hence to standard thermodynamics. This formalism has been at the basis of an enormous…

Statistical Mechanics · Physics 2009-11-10 Constantino Tsallis , Celia Anteneodo , Lisa Borland , Roberto Osorio

The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…

Chemical Physics · Physics 2009-12-03 Chi-Ho Cheng

A quantum statistical expression for the entropy of a nonequilibrium system is defined so as to be consistent with Gibbs' relation, and is shown to corresponds to dynamical variable by introducing analogous to the Heisenberg picture in…

Statistical Mechanics · Physics 2013-05-29 Hiroki Majima , Akira Suzuki

Observational entropy -- a quantity that unifies Boltzmann's entropy, Gibbs' entropy, von Neumann's macroscopic entropy, and the diagonal entropy -- has recently been argued to play a key role in a modern formulation of statistical…

Quantum Physics · Physics 2026-03-24 Teruaki Nagasawa , Kohtaro Kato , Eyuri Wakakuwa , Francesco Buscemi

All of the basic microsopic physical laws are time reversible. In contrast, the second law of thermodynamics, which is a macroscopic physical representation of the world, is able to describe irreversible processes in an isolated system…

Chemical Physics · Physics 2015-06-19 Roland Riek

The second law of thermodynamics states that the entropy of an isolated system can only increase over time. This appears to conflict with the reversible evolution of isolated quantum systems under the Schr\"odinger equation, which preserves…

Quantum Physics · Physics 2025-01-16 Florian Meier , Tom Rivlin , Tiago Debarba , Jake Xuereb , Marcus Huber , Maximilian P. E. Lock

The division by N! in the expression of statistical entropy is usually justified to students by the statement that classical particles should be counted as indistinguishable. Sometimes, quantum indistinguishability is invoked to explain it.…

Statistical Mechanics · Physics 2023-05-24 Sergio Di Matteo

Many physicists think that the maximum entropy formalism is a straightforward application of Bayesian statistical ideas to statistical mechanics. Some even say that statistical mechanics is just the general Bayesian logic of inductive…

Statistical Mechanics · Physics 2007-05-23 Cosma Rohilla Shalizi

A question that is currently highly debated is whether the microcanonical entropy should be expressed as the logarithm of the phase volume (volume entropy, also known as the Gibbs entropy) or as the logarithm of the density of states…

Statistical Mechanics · Physics 2015-05-28 Michele Campisi

Applying the theory of self-adjoint extensions of Hermitian operators to Koopman von Neumann classical mechanics, the most general set of probability distributions is found for which entropy is conserved by Hamiltonian evolution. A new…

Statistical Mechanics · Physics 2019-06-24 Gerard McCaul , Alexander Pechen , Denys I. Bondar

The Hamiltonian evolution of an isolated classical system is reversible, yet the second law of thermodynamics states that its entropy can only increase. This has confounded attempts to identify a `Microscopic Dynamical Entropy' (MDE), by…

Statistical Mechanics · Physics 2025-03-17 Mingnan Ding , Michael E. Cates

The population dynamics and stability of ecosystems of interacting species is studied from the perspective of non-equilibrium thermodynamics by assuming that species, through their biotic and abiotic interactions, are units of entropy…

Biological Physics · Physics 2007-05-23 Karo Michaelian

Classical statistical mechanics of macroscopic systems in equilibrium is based on Boltzmann's principle. Tsallis has proposed a generalization of Boltzmann-Gibbs statistics. Its relation to dynamics and nonextensivity of statistical systems…

Classical Physics · Physics 2009-11-10 H. J. Haubold , A. M. Mathai , R. K. Saxena