Related papers: Volume Expansion of Branched Polymers
Nonequilibrium molecular dynamics simulations are used to study the deformation behavior of disperse polymer melts by tracking test chains of length N = Mw, the weight average molecular weight, in melts of varying dispersity. At high strain…
We explore semi-dilute and concentrated oligomers and polymers in a broad range of polymerization indices N ranging from 1 to a 100 and in a range of monomer number densities $\phi$ from 0.1 to 0.8 via molecular dynamics simulations and…
We study the passage (translocation) of a self-avoiding polymer through a membrane pore in two dimensions. In particular, we numerically measure the probability distribution Q(T) of the translocation time T, and the distribution P(s,t) of…
The study of the noise induced effects on the dynamics of a chain molecule crossing a potential barrier, in the presence of a metastable state, is presented. A two-dimensional stochastic version of the Rouse model for a flexible polymer has…
We determine the distribution of free ends and the monomer insertion potential in the strongly-stretched limit for regularly and statistically branched polymer brushes. We find that the end density flattens in the limit of very strong…
Using the recently discovered strong negative dependence properties of the symmetric exclusion process, we derive general conditions for when the normalized current of particles between regions converges to the Gaussian distribution. The…
In [math-ph/0107005] we have proven that the generating function for self-avoiding branched polymers in D+2 continuum dimensions is proportional to the pressure of the hard-core continuum gas at negative activity in D dimensions. This…
The mathematical derivation of the mean square radius of gyration, <s2x>, of branched polymers is reinvestigated from a kinetic-equation-point of view. In particular we derive the corresponding quantity of the A-R-Bf-1 model; the result…
We consider the motion of overdamped particles on random potentials subjected to a Gaussian white noise and a time-dependent periodic external forcing. The random potential is modeled as the potential resulting from the interaction of a…
We consider an inextensible, semiflexible polymer or worm-like chain which is confined in the transverse direction by a parabolic potential and subject to a longitudinal force at the ends, so that the polymer is stretched out and…
We use the mapping between Burgers' equation and the problem of a directed polymer in a random medium in order to study the fully developped turbulence in the $N$ dimensional forced Burgers' equation. The stirring force corresponds to a…
A representation of polymer self-consistent field theory equivalent to quantum density functional theory is given in terms of non-orthogonal basis sets. Molecular integrals and self-consistent equations for spherically symmetric systems…
We study the mechanical properties of semiflexible polymers when the contour length of the polymer is comparable to its persistence length. We compute the exact average end-to-end distance and shape of the polymer for different boundary…
In this paper, we generalize the result on the average volume of random polytopes with vertices following beta distributionsto the case of non-identically distributed vectors. Specifically,we consider the convex hull of independent random…
In the Onsager model of one-component hard-particle systems, the entire phase behaviour is dictated by a function of relative orientation, which represents the amount of space excluded to one particle by another at this relative…
Understanding the dynamics of soft colloids, such as star polymers, dendrimers, and microgels, is of scientific and practical importance. It is known that the excluded volume effect plays a key role in colloidal dynamics. Here, we propose a…
Let $A$ be a compact $d$-dimensional $C^2$ Riemannian manifold with boundary, embedded in ${\bf R}^m$ where $m \geq d \geq 2$, and let $B$ be a nice subset of $A$ (possibly $B=A$). Let $X_1,X_2, \ldots $ be independent random uniform points…
Spatial configurations of randomly charged polymers, known as polyampholytes (PAs), are very sensitive to the overall excess charge Q. Analytical arguments, supported by Monte Carlo simulations and exact enumeration studies, lead to the…
In this work we study the properties of the mass density field in the non-Gaussian world models simulated by Grossi et al. 2007. In particular we focus on the one-point density probability distribution function of the mass density field in…
A collection of rigorous results for a class of mean-field monomer-dimer models is presented. It includes a Gaussian representation for the partition function that is shown to considerably simplify the proofs. The solutions of the quenched…