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Nucleation of a new phase almost always starts at a surface. This surface is almost always assumed not to change with time. However, surfaces can roughen, partially dissolve and change chemically with time. Each of these irreversible…
Porous media, while ubiquitous across many engineering disciplines, is inherently difficult to characterize due to their innate stochasticity and heterogeneity. The key for predicting porous material behavior comes down to the structuring…
Depleted carbonate hydrocarbon reservoirs are promising sites for geological CO2 storage, yet the presence of residual hydrocarbons introduces complex pore-scale interactions that influence the dynamics of solid dissolution. This study…
The detailed nature of spatially heterogeneous dynamics of glycerol-silica nanocomposites is unraveled by combining dielectric spectroscopy with atomistic simulation and statistical mechanical theory. Analysis of the spatial mobility…
Mixing fronts, where fluids of different chemical compositions mix with each other, are typically subjected to velocity gradients, ranging from the pore scale to the catchment scale due to permeability variations and flow line geometries. A…
The flow of fluids within porous rocks is an important process with numerous applications in Earth sciences. Modeling the compaction-driven fluid flow requires the solution of coupled nonlinear partial differential equations that account…
Anaerobic processes (e.g., methanogenesis and fermentation) largely contribute to element cycling and natural contaminant attenuation/mobilization, even in well-oxygenated porous environments, such as shallow aquifers. This paradox is…
Recent X-ray imaging experiments have revealed that multiphase flow through porous media involves transient fluctuations in local occupancy, even under fixed macroscopic steady-state conditions where capillary forces dominate at the pore…
Reactive chemistry of molecular hydrogen at surfaces, notably dissociative sticking and hydrogen evolution, plays a crucial role in energy storage and fuel cells. Theoretical studies can help to decipher underlying mechanisms and reaction…
Morphological measures are introduced to probe the complex procedure of shock wave reaction on porous material. They characterize the geometry and topology of the pixelized map of a state variable like the temperature. Relevance of them to…
There is accumulating evidence for the presence of complex molecules, including carbon-bearing and organic molecules, in the interstellar medium. Much of this evidence comes to us from studies of chemical composition, photo- and…
We derive an upscaled model describing the aggregation and deposition of colloidal particles within a porous medium allowing for the possibility of local clogging of the pores. At the level of the pore scale, we extend an existing model for…
Chemical heterogeneity of solid surfaces disrupts the adsorption of surfactants from the bulk liquid. While its presence can hinder the performance of some formulations, bespoke chemical patterning could potentially facilitate controlled…
In this work we present a model reduction procedure to derive a hybrid-dimensional framework for the mathematical modeling of reactive transport in fractured porous media. Fractures are essential pathways in the underground which allow fast…
Many engineering and environmental surfaces exhibit spatial heterogeneity in the spanwise direction and encompass multiple surface length scales. When the dominant spanwise length scale is on the order of the largest flow scales (e.g., the…
Autocatalytic processes underlie diverse systems in which replication is triggered at interfaces, including heterogeneous catalysis on solid substrates, enzyme activity at membranes, viral infections, biofilm growth, and spatially…
Molecular-scale interactions between solvated macromolecules and solid surfaces govern a large number of processes, from biology to engineering. Yet, despite extensive characterization at the macroscopic level, our molecular understanding…
In particle-laden flows through porous media, porosity and permeability are significantly affected by the deposition and erosion of particles. Experiments show that the permeability evolution of a porous medium with respect to a particle…
We consider a phase-field model for the incompressible flow of two immiscible fluids. This model extends widespread models for two fluid phases by including a third, solid phase, which can evolve due to e.g. precipitation and dissolution.…
Supported metal nanoparticle (NP) catalysts are vital for the sustainable production of chemicals, but their design and implementation are limited by the ability to identify and characterize their structures and atomic sites that are…