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The spin-ladder compounds of the BaFe2X3 (X = chalcogen) family may be viewed as dimensional reductions (along stripe-like motifs) of the two-dimensional iron-based pnictide planes extensively studied since 2006. Remarkably, despite their…

The superconducting pyrochlore oxide Cd2Re2O7 (Tc = 1 K), which is now considered as a candidate of the spin-orbit-coupled metal, shows an inversion-symmetry-breaking structural transition at Ts1 = 200 K. Ts1 decreases with increasing…

Strongly Correlated Electrons · Physics 2018-04-30 Yasuhito Matsubayashi , Takumi Hasegawa , Norio Ogita , Jun-ichi Yamaura , Zenji Hiroi

Indium selenide compounds are promising materials for energy conversion, spintronic applications, and chemical sensing. However, it is difficult to grow stoichiometric indium selenide crystals due to the high equilibrium selenium vapor…

Materials Science · Physics 2021-10-22 Chao Tang , Yohei Sato , Katsuya Watanabe , Tadao Tanabe , Yutaka Oyama

The superconductor Sn_{1-x}In_{x}Te is a doped topological crystalline insulator and has become important as a candidate topological superconductor, but its superconducting phase diagram is poorly understood. By measuring about 50 samples…

Superconductivity · Physics 2015-06-17 Mario Novak , Satoshi Sasaki , Markus Kriener , Kouji Segawa , Yoichi Ando

The transition metal selenides (MxSey) have gained attention for their unique physical and chemical properties, especially those associated with the transition metal (M). Despite advancements in synthesis, fabricating these selenides is…

Materials Science · Physics 2025-01-28 Monika Ghalawat , Inderjeet Chauhan , Dinesh Singh , Chinnakonda S. Gopinath , Pankaj Poddar

Two single crystalline samples with the same nominal composition of Rb0.8Fe2Se2 prepared via slightly different precursor routes under the same thermal processing conditions were investigated at ambient and high pressures. One sample was…

Superconductivity · Physics 2012-07-18 M. Gooch , B. Lv , L. Z. Deng , T. Muramatsu , J. Meen , Y. Y. Xue , B. Lorenz , C. W. Chu

Ferroelectric phase transition in the semiconductor Sn2P2S6 single crystal has been studied by means of neutron scattering in the pressure-temperature range adjacent to the anticipated tricritical Lifshitz point (p=0.18GPa, T=296K). The…

[(SnSe)$_{1+\delta}$]$_m$(NbSe$_2$) ($m$ = 1-6, 8, and 12) highly orientated crystals 1-2 mm in size and well-defined c-planes were successfully grown using CsCl/KCl flux, including the first growth of crystals with $m = 12$. The stacked…

The structural, superconducting, and electronic phase diagram of [Tl4]Tl1-xSnxTe3 is reported. Magnetization and specific heat measurements show bulk superconductivity exists for 0 < x < 0.4. Resistivity measurements indicate a crossover…

Strongly Correlated Electrons · Physics 2015-02-26 K. E. Arpino , B. D. Wasser , T. M. McQueen

This joint experimental and theoretical study of the structural, vibrational and electrical properties of rhombohedral SnSb2Te4 at high pressure unveils the internal mechanisms of its compression. The equation of state and the internal…

Slack's phonon-glass and electron-crystal concept has been the guiding paradigm for designing new thermoelectric materials. Zintl phases, in principle, have been shown as great contenders of the concept and thereby good thermoelectric…

Materials Science · Physics 2025-11-11 Vivek Gusain , Mohd Zeeshan , B. K. Mani

We have investigated the pressure-induced phase transition and superconducting properties of niobium disulfide (NbS$_2$) based on the density functional theory. The structures of NbS$_2$ at pressures from 0 to 200 GPa were predicted using…

Superconductivity · Physics 2014-10-31 Zhong-Li Liu , Ling-Cang Cai , Xiu-Lu Zhang

The high pressure structural properties of bismuth oxide Bi2SiO5 have been investigated up to 28 GPa using in situ powder synchrotron X-ray diffraction and up to 50 GPa with DFT calculations. The monoclinic structure is found to persist up…

Using first-principles variable-composition evolutionary methodology, we explored the high-pressure structures of beryllium hydrides between 0 and 400 GPa. We found that BeH$_2$ remains the only stable compound in this pressure range. The…

Materials Science · Physics 2014-07-15 Shuyin Yu , Qingfeng Zeng , Artem R. Oganov , Chaohao Hu , Gilles Frapper , Litong Zhang

Despite their electronic dominance, cubic diamond structured Si and Ge, are optoelectronically deficient. Recent work indicates, however, that a volume-expanded hexagonal Ge modification can exhibit intensely sought, superior optoelectronic…

Here, we have grown single crystals of LaTe2-xSbx (x=0 and 0.4) with continuously adjustable CDW. High-pressure x-ray diffraction show LaTe2 does not undergo phase transition and keep robust below 40 GPa. In-situ high-pressure electrical…

In situ high-pressure energy dispersive x-ray diffraction experiments on polycrystalline powder TiN with NaCl-type structure have been conducted with the pressure up to 30.1 GPa by using the diamond anvil cell instrument with synchrotron…

Materials Science · Physics 2009-11-11 J. G. Zhao , L. X. Yang , Y. Yu , S. J. You , R. C. Yu , L. C. Chen , F. Y. Li , C. Q. Jin , X. D. Li , Y. C. Li , J. Liu

We report an unusual evolution of superconductivity (SC) in the three-dimensional Dirac semimetal PdTe with increasing pressure up to $\sim$50 GPa. The compressed PdTe exhibits a sudden reversal in the superconducting transition temperature…

Recently, A2B3 type strong spin orbital coupling compounds such as Bi2Te3, Bi2Se3 and Sb2Te3 were theoretically predicated to be topological insulators and demonstrated through experimental efforts. The counterpart compound Sb2Se3 on the…

Both tin monosulfide (SnS) and tin disulfide (SnS2) are thermodynamically stable layered materials with potential for spin-valleytronic devices and photodetectors. Notably, monolayer SnS, owing to its low symmetry, exhibits interesting…