Related papers: Dynamics on the Double Morse Potential: A Paradigm…
In this paper, we analyse the phase space structure of the roaming dynamics in a two degree of freedom potential energy surface consisting of two identical planar Morse potentials separated by a distance. This potential energy surface was…
We explore a two-body system with superexponential interactions that serves as a fundamental building block for a route to complexity. While being of striking simplicity this highly nonlinear interaction yields a plethora of intriguing…
We study the phase space geometry associated with index 2 saddles of a potential energy surface and its influence on reaction dynamics for $n$ degree-of-freedom (DoF) Hamiltonian systems. For index 1 saddles of potential energy surfaces…
The equilibrium configuration of an engineering structure, able to withstand a certain loading condition, is usually associated with a local minimum of the underlying potential energy. However, in the nonlinear context, there may be other…
In this paper, we study the quantum dynamics of a one degree-of-freedom (DOF) Hamiltonian that is a normal form for a saddle node bifurcation of equilibrium points in phase space. The Hamiltonian has the form of the sum of kinetic energy…
We consider the existence of invariant manifolds in phase space governing reaction dynamics in situations where there are no saddle points on the potential energy surface in the relevant regions of configuration space. We point out that…
We study the effect of changes in the parameters of a two-dimensional potential energy surface on the phase space structures relevant for chemical reaction dynamics. The changes in the potential energy are representative of chemical…
This paper explores the phase space structures characterising transport for a double-well van der Waals potential surface. Trajectories are classified as inter-well, intra-well, and escaping-from-a-well to define different dynamical fates.…
Plenty of saddles on a multidimensional potential energy surface(PES) of two-dimensional microclusters, where atoms are interacting via Morse potential, are numerically located. The reaction paths emanating from the two types of the local…
A model Hamiltonian for the reaction CH$_4^+ \rightarrow$ CH$_3^+$ + H, parametrized to exhibit either early or late inner transition states, is employed to investigate the dynamical characteristics of the roaming mechanism. Tight/loose…
In this paper we explore the phase space structures governing isomerization dynamics on a potential energy surface with four wells and an index-2 saddle. For this model, we analyze the influence that coupling both degrees of freedom of the…
An analytic reversible Hamiltonian system with two degrees of freedom is studied in a neighborhood of its symmetric heteroclinic connection made up of a symmetric saddle-center, a symmetric orientable saddle periodic orbit lying in the same…
In this article we present the influence of a Hamiltonian saddle-node bifurcation on the high-dimensional phase space structures that mediate reaction dynamics. To achieve this goal, we identify the phase space invariant manifolds using…
Active proteins and membrane-bound motors exert force dipole flows along fluid interfaces and lipid bilayers. We develop a Hamiltonian framework for the interactions of pusher and puller dipoles embedded in an incompressible two-dimensional…
A double well loaded with bosonic atoms represents an ideal candidate to simulate some of the most interesting aspects in the phenomenology of thermalisation and equilibration. Here we report an exhaustive analysis of the dynamics and…
Chesnavich's model Hamiltonian for the reaction CH$_4^+ \rightarrow$ CH$_3^+$ is known to exhibit a range of interesting dynamical phenomena including roaming. The model system consists of two parts: a rigid, symmetric top representing the…
We have prepared two ultracold fermionic atoms in an isolated double-well potential and obtained full control over the quantum state of this system. In particular, we can independently control the interaction strength between the particles,…
Escape from a potential well can occur in different physical systems, such as capsize of ships, resonance transitions in celestial mechanics, and dynamic snap-through of arches and shells, as well as molecular reconfigurations in chemical…
In this work we analyze the bifurcation of dividing surfaces that occurs as a result of a pitchfork bifurcation of periodic orbits in a two degrees of freedom Hamiltonian System. The potential energy surface of the system that we consider…
We employ the multi-configuration time-dependent Hartree method for bosons (MCTDHB) in order to investigate the correlated non-equilibrium quantum dynamics of two bosons confined in two colliding and uniformly accelerated Gaussian wells. As…