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Controlling molecular binding at the level of single atoms is one of the holy grails of quantum chemistry. Rydberg macrodimers -- bound states between highly excited Rydberg atoms -- provide a novel perspective in this direction. Resulting…

Atomic Physics · Physics 2023-06-14 Simon Hollerith , Johannes Zeiher

We consider bosonic dipolar molecules in an optical lattice prepared in a mixture of different rotational states. The 1/r^3 interaction between molecules for this system is produced by exchanging a quantum of angular momentum between two…

Strongly Correlated Electrons · Physics 2009-11-11 Ryan Barnett , Dmitry Petrov , Mikhail Lukin , Eugene Demler

The properties of the electronic ground state of the polar and paramagnetic europium-$S$-state-atom molecules have been investigated. Ab initio techniques have been applied to compute the potential energy curves for the…

Atomic Physics · Physics 2014-09-04 Michał Tomza

We study the two-photon scattering processes in a one-dimensional waveguide coupled to a two- or three-level giant atom, respectively. The accumulated phase shift between the two coupling points can be utilized to alter the scattering…

Quantum Physics · Physics 2023-11-30 Wenju Gu , He Huang , Zhen Yi , Lei Chen , Lihui Sun , Huatang Tan

In this paper we show how to generate efficiently entanglement between two artificial giant atoms with photon-mediated interactions in a waveguide. Taking advantage of the adjustable decay processes of giant atoms into the waveguide, and of…

Quantum Physics · Physics 2023-02-06 Alan C. Santos , R. Bachelard

We derive general conditions for the emergence of singlet Feshbach molecules in the presence of artificial Zeeman fields for arbritary mixtures of Rashba and Dresselhaus spin-orbit orbit coupling in two or three dimensions. We focus on the…

Quantum Gases · Physics 2016-02-10 Doga Murat Kurkcuoglu , C. A. R. Sa de Melo

Cs$_2$ Rydberg-ground molecules consisting of a Rydberg, $nD_{J}$ (33 $\leq$ $n$ $\leq$ 39), and a ground state atom, 6$S_{1/2} (F=$3 or 4$)$, are investigated by photo-association spectroscopy in a cold atomic gas. We observe vibrational…

Atomic and Molecular Clusters · Physics 2020-10-07 Suying Bai , Xiaoxuan Han , Jingxu Bai , Yuechun Jiao , Jianming Zhao , Suotang Jia , Georg Raithel

We demonstrate that ultracold symmetric top molecules loaded into an optical lattice can realize highly tunable and unconventional models of quantum magnetism, such as an XYZ Heisenberg spin model. We show that anisotropic dipole-dipole…

Quantum Gases · Physics 2015-03-20 M. L. Wall , K. Maeda , L. D. Carr

We study the coupling of internal electronic excitations to vibrational modes of the external motion of ultracold atoms in an optical lattice. For different ground and excited state potentials the on-site coupling of excitations and…

Quantum Physics · Physics 2009-08-11 Hashem Zoubi , Helmut Ritsch

The properties of the electronic ground state of the polar and paramagnetic chromium--closed-shell-atom molecules have been investigated. State-of-the-art \textit{ab initio} techniques have been applied to compute the potential energy…

Atomic Physics · Physics 2013-07-31 Michał Tomza

Using the method of quantum-defect theory, we calculate the ultralong-range molecular vibrational states near the dissociation threshold of a diatomic molecular potential which asymptotically varies as $-1/R^3$. The properties of these…

Quantum Physics · Physics 2009-11-10 B. Deb , L. You

We present photodissociation of ultracold long-range Rydberg molecules as a tool to characterize their electronic properties. We photoassociate K2 37P molecules with highly entangled electronic and nuclear spins of the two bound atoms and…

Atomic Physics · Physics 2021-01-07 Michael Peper , Johannes Deiglmayr

Neutral molecules with sufficiently large dipole moments can bind electrons in diffuse nonvalence orbitals with most of their charge density far from the nuclei, forming so-called dipole-bound anions. Because long-range correlation effects…

Chemical Physics · Physics 2018-10-30 Hongxia Hao , James Shee , Shiv Upadhyay , Can Ataca , Kenneth D. Jordan , Brenda M. Rubenstein

We present the theory for retarded resonance interaction between two identical atoms at arbitrary positions near a metal surface. The dipole-dipole resonance interaction force that binds isotropically excited atom pairs together in free…

Materials Science · Physics 2013-04-10 Mathias Boström , Clas Persson , Barry W. Ninham , Patrick Norman , Bo E. Sernelius

We develop a collisional formalism adapted for the dynamics of ultracold dipolar particles in a confined geometry and in fields tilted relative to the confinement axis. Using tesseral harmonics instead of the usual spherical harmonics to…

Atomic Physics · Physics 2015-10-21 Goulven Quéméner , Maxence Lepers , Olivier Dulieu

We present first steps toward understanding the ultracold scattering properties of polar molecules in strong electric field-seeking states. We have found that the elastic cross section displays a quasi-regular set of potential resonances as…

Atomic Physics · Physics 2009-11-11 Christopher Ticknor , John L. Bohn

Physics of photons and electrons carrying orbital angular momentum (OAM) is an exciting field of research in quantum optics and electron microscopy. Usually, one considers propagation of these vortex beams in a medium or external fields and…

Quantum Physics · Physics 2012-04-13 I. P. Ivanov

Long-range Rydberg molecules (LRMs) form when a highly excited Rydberg electron scatters from ground-state atoms inside its orbit, creating oscillatory, long-range potentials. We present a combined theoretical and experimental study of…

We analyze the formation of maximally entangled Rydberg atom pairs subjected to Landau-Zener sweeps of the atom-light detuning. Though the populations reach a steady value at longer times, the phases evolve continuously, leading to periodic…

Quantum Physics · Physics 2023-04-19 Dhiya Varghese , Sebastian Wüster , Weibin Li , Rejish Nath

We explore the character of a novel set of ``field-linked'' states that were predicted in [A. V. Avdeenkov and J. L. Bohn, Phys. Rev. Lett. 90, 043006 (2003)]. These states exist at ultralow temperatures in the presence of an electrostatic…

Atomic Physics · Physics 2009-11-10 A. V. Avdeenkov , D. C. E. Bortolotti , J. L. Bohn