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The next generation of force fields for molecular dynamics will be developed using a wealth of data. Training systematically with experimental data remains a challenge, however, especially for machine learning potentials. Differentiable…

Biomolecules · Quantitative Biology 2025-04-16 Joe G Greener

Analytical nuclear gradients for fully internally contracted complete active space second-order perturbation theory (CASPT2) are reported. This implementation has been realized by an automated code generator that can handle spin-free…

Chemical Physics · Physics 2015-02-11 Matthew K. MacLeod , Toru Shiozaki

We report a method to convert discrete representations of molecules to and from a multidimensional continuous representation. This model allows us to generate new molecules for efficient exploration and optimization through open-ended…

Coded computing is a distributed paradigm that uses coding theory to introduce \textit{redundancy} and overcome bottlenecks in large-scale systems. In the same vein, randomized numerical linear algebra employs probabilistic methods to…

Distributed, Parallel, and Cluster Computing · Computer Science 2026-05-19 Neophytos Charalambides , Arya Mazumdar

Developing an efficient method to accelerate the speed of molecular dynamics is a central theme in the field of molecular simulation. One category among the methods are collective-variable-based methods, which rely on predefined collective…

Chemical Physics · Physics 2024-08-27 Jiahao Fan , Yanze Wang , Dongdong Wang , Linfeng Zhang

Group number selection is a key problem for group panel data modeling. In this work, we develop a cross-validation (CV) method to tackle this problem. Specifically, we split the panel data into two data folds on the time span, with group…

Methodology · Statistics 2025-05-19 Zhe Li , Xuening Zhu , Changliang Zou

Enhanced sampling methods typically require predefined collective variables (CVs) that presuppose knowledge of reaction coordinates, restricting the discovery of unanticipated transition mechanisms or intermediates. Here, we show that a…

Chemical Physics · Physics 2026-04-08 Xiangrui Li , Daniel Schwalbe-Koda

The present paper proposes an adaptive biasing potential for the computation of free energy landscapes. It is motivated by statistical learning arguments and unifies the tasks of biasing the molecular dynamics to escape free energy wells…

Mathematical Physics · Physics 2018-03-05 I. Bilionis , P. S. Koutsourelakis

The formation of the large-scale structure, the evolution and distribution of galaxies, quasars, and dark matter on cosmological scales, requires numerical simulations. Differentiable simulations provide gradients of the cosmological…

Instrumentation and Methods for Astrophysics · Physics 2022-11-21 Yin Li , Libin Lu , Chirag Modi , Drew Jamieson , Yucheng Zhang , Yu Feng , Wenda Zhou , Ngai Pok Kwan , François Lanusse , Leslie Greengard

We study how to generate molecule conformations (i.e., 3D structures) from a molecular graph. Traditional methods, such as molecular dynamics, sample conformations via computationally expensive simulations. Recently, machine learning…

Machine Learning · Computer Science 2021-04-01 Minkai Xu , Shitong Luo , Yoshua Bengio , Jian Peng , Jian Tang

The description of chemical processes at the molecular level is often facilitated by use of reaction coordinates, or collective variables (CVs). The CV measures the progress of the reaction and allows the construction of profiles that track…

Chemical Physics · Physics 2023-04-26 Johannes C. B. Dietschreit , Dennis J. Diestler , Rafael Gómez-Bombarelli

Computer vision and machine learning tools offer an exciting new way for automatically analyzing and categorizing information from complex computer simulations. Here we design an ensemble machine learning framework that can independently…

Computer Vision and Pattern Recognition · Computer Science 2021-09-06 Maarja Bussov , Joonas Nättilä

Derivatives play a critical role in computational statistics, examples being Bayesian inference using Hamiltonian Monte Carlo sampling and the training of neural networks. Automatic differentiation is a powerful tool to automate the…

Mathematical Software · Computer Science 2019-03-27 Charles C. Margossian

Variable sharing is a fundamental property in the static analysis of logic programs, since it is instrumental for ensuring correctness and increasing precision while inferring many useful program properties. Such properties include modes,…

Programming Languages · Computer Science 2025-01-22 Daniel Jurjo-Rivas , Jose F. Morales , Pedro López-García , Manuel V. Hermenegildo

Deriving system-level specifications from component specifications usually involves the elimination of variables that are not part of the interface of the top-level system. This paper presents algorithms for eliminating variables from…

Logic in Computer Science · Computer Science 2024-11-22 Inigo Incer , Albert Benveniste , Richard M. Murray , Alberto Sangiovanni-Vincentelli , Sanjit A. Seshia

We present ensmallen, a fast and flexible C++ library for mathematical optimization of arbitrary user-supplied functions, which can be applied to many machine learning problems. Several types of optimizations are supported, including…

Mathematical Software · Computer Science 2018-12-11 Shikhar Bhardwaj , Ryan R. Curtin , Marcus Edel , Yannis Mentekidis , Conrad Sanderson

Predicting molecular conformations (or 3D structures) from molecular graphs is a fundamental problem in many applications. Most existing approaches are usually divided into two steps by first predicting the distances between atoms and then…

Machine Learning · Computer Science 2025-01-07 Minkai Xu , Wujie Wang , Shitong Luo , Chence Shi , Yoshua Bengio , Rafael Gomez-Bombarelli , Jian Tang

We introduce the C++ library Wedge, based on GiNaC, for symbolic computations in differential geometry. We show how Wedge makes it possible to use the language C++ to perform such computations, and illustrate some advantages of this…

Differential Geometry · Mathematics 2008-04-22 Diego Conti

Hybrid quantum-classical approaches offer potential solutions to quantum chemistry problems, yet they often manifest as constrained optimization problems. Here, we explore the interconnection between constrained optimization and generalized…

Quantum Physics · Physics 2025-03-27 Muqing Zheng , Bo Peng , Ang Li , Xiu Yang , Karol Kowalski

Nowadays there are several classes of constrained codes intended for different applications. The following two large classes can be distinguished. The first class contains codes with local constraints; for example, the source data must be…

Information Theory · Computer Science 2024-05-27 Boris Ryabko