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A novel quantum dynamical method to simulate vibronic reaction dynamics in molecules at metal surfaces is proposed. The method is based on the hierarchical quantum master equation approach and uses a discrete variable representation of the…

Chemical Physics · Physics 2019-12-05 A. Erpenbeck , M. Thoss

We propose a novel non-Hermitian adiabatic quantum optimization algorithm. One of the new ideas is to use a non-Hermitian auxiliary "initial'' Hamiltonian that provides an effective level repulsion for the main Hamiltonian. This effect…

Quantum Physics · Physics 2012-11-15 Gennady P. Berman , Alexander I. Nesterov

We study the application of a new method for simulating nonlinear dynamics of many-body spin systems using quantum measurement and feedback [Mu\~noz-Arias et al., Phys. Rev. Lett. 124, 110503 (2020)] to a broad class of many-body models…

Quantum Physics · Physics 2020-08-19 Manuel H. Muñoz-Arias , Ivan H. Deutsch , Poul S. Jessen , Pablo M. Poggi

Quantum simulation is a promising near term application for mesoscale quantum information processors, with the potential to solve computationally intractable problems at the scale of just a few dozen interacting quantum systems. Recent…

Quantum Physics · Physics 2014-08-14 David L. Hayes , Steven T. Flammia , Michael J. Biercuk

In this paper we construct a path integral formulation of quantum mechanics on noncommutative phase-space. We first map the system to an equivalent system on the noncommutative plane. Then by applying the formalism of representing a quantum…

High Energy Physics - Theory · Physics 2017-03-02 Sunandan Gangopadhyay , Aslam Halder

Mixed-quantum classical (MQC) methods for simulating the dynamics of molecules at metal surfaces have the potential to accurately and efficiently provide mechanistic insight into reactive processes. Here, we introduce simple two-dimensional…

Chemical Physics · Physics 2023-08-02 James Gardner , Scott Habershon , Reinhard J. Maurer

We introduce the coherent state mapping ring-polymer molecular dynamics (CS-RPMD), a new method that accurately describes electronic non-adiabatic dynamics with explicit nuclear quantization. This new approach is derived by using coherent…

Chemical Physics · Physics 2018-01-17 Sutirtha Chowdhury , Pengfei Huo

We present a non-perturbative framework for deriving effective Hamiltonians that describe low-energy excitations in quantum many-body systems. The method combines block diagonalization based on the Cederbaum--Schirmer--Meyer transformation…

Strongly Correlated Electrons · Physics 2025-05-19 Tsutomu Momoi , Owen Benton

We present a new non-adiabatic ring polymer molecular dynamics (NRPMD) method based on the spin mapping formalism, which we refer to as the spin-mapping NRPMD (SM-NRPMD) approach. We derive the path-integral partition function expression…

Chemical Physics · Physics 2021-06-02 Duncan Bossion , Sutirtha N. Chowdhury , Pengfei Huo

Preserving quantum coherence with the increase of a system's size and complexity is a major challenge. Molecules, with their diverse sizes and complexities and many degrees of freedom, are an excellent platform for studying the transition…

Quantum Physics · Physics 2024-09-23 Tamar Levin , Ziv Meir

Extensions of average Hamiltonian theory to quantum computation permit the design of arbitrary Hamiltonians, allowing rotations throughout a large Hilbert space. In this way, the kinematics and dynamics of any quantum system may be…

Quantum Physics · Physics 2009-10-31 C. H. Tseng , S. Somaroo , Y. Sharf , E. Knill , R. Laflamme , T. F. Havel , D. G. Cory

We introduce a general framework for realizing $\mathcal{PT}$-like phase transitions in non-Hermitian systems without imposing explicit parity--time ($\mathcal{PT}$) symmetry. The approach is based on constructing a Hamiltonian as the…

Optics · Physics 2025-11-18 Jacob L. Barnett , Ramy El-Ganainy

We propose a new way to perform path integrals in quantum mechanics by using a quantum version of Hamilton-Jacobi theory. In classical mechanics, Hamilton-Jacobi theory is a powerful formalism, however, its utility is not explored in…

High Energy Physics - Theory · Physics 2025-09-03 Mustafa Türe , Mithat Ünsal

Rydberg-atom quantum simulators are of keen interest because of their possibilities towards high-dimensional qubit architectures. Here we report three-dimensional conformation spectra of quantum-Ising Hamiltonian systems with programmed…

Quantum Physics · Physics 2021-01-04 Minhyuk Kim , Yunheung Song , Jaewan Kim , Jaewook Ahn

We derive the Hamiltonian in the rotating frame for NMR quantum computing with homonucleus molecules as its computational resource. The Hamiltonian thus obtained is different from conventional Hamiltonians that appear in literature. It is…

Quantum Physics · Physics 2007-05-23 Yasushi Kondo , Mikio Nakahara , Kazuya Hata , Shogo Tanimura

A path integral method, combined with atomistic spin dynamics simulations, has been developed to calculate thermal quantum expectation values using a classical approach. In this study, we show how to treat Hamiltonians with non-linear…

Quantum Physics · Physics 2024-08-12 Thomas Nussle , Pascal Thibaudeau , Stam Nicolis

Extension of Feynman's path integral to quantum mechanics of noncommuting spatial coordinates is considered. The corresponding formalism for noncommutative classical dynamics related to quadratic Lagrangians (Hamiltonians) is formulated.…

High Energy Physics - Theory · Physics 2009-11-10 Branko Dragovich , Zoran Rakic

We present a simple and accurate computational method, which facilitates ab-initio path-integral molecular dynamics simulations, where the quantum mechanical nature of the nuclei is explicitly taken into account, at essentially no…

Chemical Physics · Physics 2016-04-21 Chris John , Thomas Spura , Scott Habershon , Thomas D. Kühne

In recent decades the field of quantum computation has seen remarkable development. While much progress has been made toward the realization of a fully digital, scalable, and fault tolerant quantum computer, there are still many essential…

Quantum Physics · Physics 2025-07-31 Ian Pannemarsh

Modeling non-Hermitian Hamiltonians is increasingly important in classical and quantum domains, especially when studying open systems, $PT$ symmetry, and resonances. However, the quantum simulation of these models has been limited by the…

Quantum Physics · Physics 2025-02-20 Anastashia Jebraeilli , Michael R. Geller