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Synthesis of a series of layered iron arsenides Ca1-xRExFeAs2 (112) was attempted by heating at 1000 C under a high-pressure of 2 GPa. The 112 phase successfully forms with RE = La, Ce, Nd, Sm, Eu and Gd, while Tb, Dy and Ho substituted and…

Exploration of new superconductors has always been one of the research directions in condensed matter physics. We report here a new layered heterostructure of [(Fe,Al)(OH)2][FeSe]1.2, which is synthesized by the hydrothermal ion-exchange…

In this investigation, we have synthesized BiFeO$_{3}$ nanoparticles by varying hydrothermal reaction temperatures from 200 $^{\circ}$C to 120 $^{\circ}$C to assess their visible-light-driven photocatalytic activity along with their…

Materials Science · Physics 2022-02-08 M. A. Basith , Nilufar Yesmin , Rana Hossain

Large-area ($\sim$cm$^2$) films of vertical heterostructures formed by alternating graphene and transition-metal dichalcogenide(TMD) alloys are obtained by wet chemical routes followed by a thermal treatment at low temperature (300…

High-entropy alloys (HEAs) with various promising applications have attracted significant interest. However, alloying immiscible metal elements while controlling the morphology and crystallinity remains extremely challenging. We report a…

Materials Science · Physics 2024-05-28 Qiubo Zhang , Yi Chen , Karen. C. Bustillo , Haimei Zheng

Nanocrystalline (Th1-xFex)O2-d particles with different Fe concentrations (x = 0.0, 0.05, 0.10, 0.15, 0.20 and 0.25) have been prepared by a gel combustion method. Rietveld refinement analyses of X-ray diffraction data revealed the…

Materials Science · Physics 2007-07-27 O. D. Jayakumar , I. K. Gopalakrishnan , A. Vinu , A. Asthana , A. K. Tyagi

We report on successful synthesis under high pressure of a series of polycrystalline GdFeAs O_{1-x}F_x high-Tc superconductors with different oxygen deficiency x=0.12 - 0.16 and also with no fluorine. We have found that the high-pressure…

Here we demonstrate the technique to stabilize the ErFeAsO-based superconductor with the smallest lattice constants in LnFeAsO1-y (Ln = lanthanide) series using hydrogen doping method. Polycrystalline samples were synthesized by heating…

Clean hydrogen production through efficient and cost-effective electrochemical water splitting is highly promising to meeting future global energy demands. The design of Earth-abundant materials with both high activity for hydrogen…

The synthesis and properties of LiFeAs, a high-Tc Fe-based superconducting stoichiometric compound, are reported. Single crystal x-ray studies reveal that it crystallizes in the tetragonal PbFCl type (P4/nmm) with a=3.7914(7) A and…

Superconductivity · Physics 2008-08-25 Joshua H. Tapp , Zhongjia Tang , Bing Lv , Kalyan Sasmal , Bernd Lorenz , Paul C. W. Chu , Arnold M. Guloy

We perform first-principles calculations to explore electronic, thermodynamic, and dielectric properties of two-dimensional (2D) layered, alkaline-earth hydroxides Ca(OH)2 and Mg(OH)2. We calculate the lattice parameters, exfoliation…

Materials Science · Physics 2022-04-12 Mehrdad Rostami Osanloo , Kolade A. Oyekan , William G. Vandenberghe

Despite high interest in compact and safe storage of hydrogen in the solid-state hydride form, the design of alloys that can reversibly and quickly store hydrogen at room temperature under pressures close to atmospheric pressure is a…

Materials Science · Physics 2023-01-10 Abbas Mohammadi , Yuji Ikeda , Parisa Edalati , Masaki Mito , Blazej Grabowski , Hai-Wen Li , Kaveh Edalati

We have synthesized an orthorhombic phase of nickel and silicon doped Fe$_{7}$C$_{3}$ at high-pressure and high temperature using a laser-heated diamond anvil cell. The synthesized material is characterized using X-ray diffraction (XRD),…

Materials Science · Physics 2023-04-04 Bishnupada Ghosh , Mrinmay Sahu , Pinku Saha , Nico Giordano , Goutam Dev Mukherjee

We present neutron powder diffraction results which give unambiguous evidence for the formation of the recently identified new crystalline ice phase[Lobban et al.,Nature, 391, 268, (1998)], labeled ice XII, at completely different…

Statistical Mechanics · Physics 2015-06-24 Michael Marek Koza , Helmut Schober , Thomas Hansen , Albert Toelle , Franz Fujara

The Lead-iron-niobate, (PbFe0.5Nb0.5O3 or PFN) was synthesized by low temperature sintering Single Step / Solid State Reaction Method. The 700 C / 2 hrs calcined powder was sintered at 1050 C / 1 hr. The sintered pellets were characterized…

Materials Science · Physics 2015-01-06 Shidaling Matteppanavar , Basavaraj Angadi , Sudhindra Rayprol

We propose two coupled electron-hole sheets of few-layer graphene as a new nanostructure to observe superfluidity at enhanced densities and enhanced transition temperatures. For ABC stacked few-layer graphene we show that the strongly…

Superconductivity · Physics 2014-12-10 M. Zarenia , A. Perali , D. Neilson , F. M. Peeters

The current search for room-temperature superconductivity is inspired by the unique properties of the electron-phonon interaction in metal superhydrides. Encouraged by the recently found highest-$T_C$ superconductor fcc-$LaH_{10}$, here we…

High entropy alloys (HEAs) are the new class of materials with an attractive combination of tunable mechanical and physicochemical properties. They crystallize mainly in cubic structures, however, for practical applications, HEAs with…

We investigate departures from LTE in the line formation of Fe for a number of well-studied late-type stars in different evolutionary stages. A new model of Fe atom was constructed from the most up-to-date theoretical and experimental…

Solar and Stellar Astrophysics · Physics 2015-06-05 Maria Bergemann , Karin Lind , Remo Collet , Zazralt Magic , Martin Asplund

A series of dual-phase high-entropy ultrahigh temperature ceramics (DPHE-UHTCs) are fabricated starting from N binary borides and (5-N) binary carbides powders. >~99% relative densities have been achieved with virtually no native oxides.…