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Finite-temperature properties of graphene monolayers under tensile stress have been studied by path-integral molecular dynamics (PIMD) simulations. This method allows one to consider the quantization of vibrational modes in these…

Materials Science · Physics 2018-02-14 Carlos P. Herrero , Rafael Ramirez

Thermal properties of graphene display peculiar characteristics associated to the two-dimensional nature of this crystalline membrane. These properties can be changed and tuned in the presence of applied stresses, both tensile and…

Materials Science · Physics 2018-06-07 Carlos P. Herrero , Rafael Ramirez

Thermodynamic properties of graphene bilayers are studied by path-integral molecular dynamics (PIMD) simulations, considering quantization of vibrational modes and anharmonic effects. Bilayer graphene has been studied at temperatures…

Materials Science · Physics 2020-01-10 Carlos P. Herrero , Rafael Ramirez

Path-integral molecular dynamics (PIMD) simulations have been carried out to study the influence of quantum dynamics of carbon atoms on the properties of a single graphene layer. Finite-temperature properties were analyzed in the range from…

Materials Science · Physics 2016-12-23 Carlos P. Herrero , Rafael Ramirez

Graphane is a quasi-two-dimensional material consisting of a single layer of fully hydrogenated graphene, with a C:H ratio of 1. We study nuclear quantum effects in the so-called chair-graphane by using path-integral molecular dynamics…

Chemical Physics · Physics 2020-08-24 Carlos P. Herrero , Rafael Ramirez

We study the structural and thermodynamic properties of bilayer graphene, a prototype two-layer membrane, by means of Monte Carlo simulations based on the empirical bond order potential LCBOPII. We present the temperature dependence of…

Materials Science · Physics 2015-05-18 K. V. Zakharchenko , J. H. Los , M. I. Katsnelson , A. Fasolino

Graphene bilayers display peculiar electronic and mechanical characteristics associated to their two-dimensional character and relative disposition of the sheets. Here we study nuclear quantum effects in graphene bilayers by using…

Materials Science · Physics 2019-06-17 Carlos P. Herrero , Rafael Ramirez

With use of simulated friction force microscopy, we study the effect of varying temperature on the frictional properties of suspended graphene. In contrast with the theory of thermally activated friction on the surfaces of three-dimensional…

Mesoscale and Nanoscale Physics · Physics 2015-03-18 A. Smolyanitsky

Proceeding from the model of a two-dimensional elastic continuum, we describe the characteristic features of thermal expansion of graphene using an approach that goes beyond the quasi-harmonic approximation. The negative value of the…

Mesoscale and Nanoscale Physics · Physics 2018-01-24 Viktor N. Bondarev , Vadym Adamyan , Volodymyr V. Zavalniuk

In this work, we have studied the phonon properties of multi-layered graphene with the use of Molecular Dynamics (MD) simulations and the k-space Autocorrelation Sequence (k-VACS) method. We calculate the phonon dispersion curves, densities…

Hydrogen and deuterium chemisorption on a single layer of graphene has been studied by path-integral molecular dynamics simulations. Finite-temperature properties of these point defects were analyzed in the range from 200 to 1500 K, by…

Materials Science · Physics 2015-05-13 Carlos P. Herrero , Rafael Ramirez

Graphene has become in last decades a paradigmatic example of two-dimensional and so-called van-der-Waals layered materials, showing large anisotropy in their physical properties. Here we study the elastic properties and mechanical…

Materials Science · Physics 2023-11-22 Carlos P. Herrero , Rafael Ramirez

Graphite, as a well-known carbon-based solid, is a paradigmatic example of the so-called van der Waals layered materials, which display a large anisotropy in their physical properties. Here we study quantum effects in structural and elastic…

Materials Science · Physics 2021-09-16 Carlos P. Herrero , Rafael Ramirez

Isotopic effects are relevant to understand several properties of solids, and have been thoroughly analyzed along the years. These effects may depend on the dimensionality of the considered solid. Here we assess their magnitude for…

Materials Science · Physics 2020-09-04 Carlos P. Herrero , Rafael Ramirez

The thermodynamic and kinetic properties of hydrogen adatoms on graphene are important to the materials and devices based on hydrogenated graphene. Hydrogen dimers on graphene with coverages varying from 0.040 to 0.111 ML (1.0 ML $=…

Materials Science · Physics 2011-11-10 Liang Feng Huang , Mei Yan Ni , Yong Gang li , Wang Huai Zhou , Xiao Hong Zheng , Ling Ju Guo , Zhi Zeng

We investigate the melting phenomena of pristine, free-standing infinite and finite size graphene sheets via molecular dynamics simulation using AIREBO potential as implemented in the LAMMPS package. In our simulations, the temperature of…

Materials Science · Physics 2016-11-22 Lian Ming Huei , Tiem Leong Yoon , Yee Yeen Soon , Thong Leng Lim

Thermal conduction was explored and discussed through a combined theoretical and simulation approach in this work. The thermal conductivity k of polycrystalline graphene was calculated by molecular dynamics simulations based on a hexagonal…

Materials Science · Physics 2014-06-05 Yanlei Wang , Zhigong Song , Zhiping Xu

Based on the first principles calculation combined with quasi-harmonic approximation, in this work we focus on the analysis of temperature dependent lattice geometries, thermal expansion coefficients, elastic constants and ultimate strength…

Materials Science · Physics 2015-06-04 Tianjiao Shao , Bin Wen , Roderick Melnik , Shan Yao , Yoshiyuki Kawazoe , Yongjun Tian

We present a simple analytical approach to study anharmonic effects in single layer, bilayer, and multilayer graphene. The coupling between in plane and out of plane modes leads to negative Gr\"uneisen coefficients and negative thermal…

Materials Science · Physics 2015-06-05 P. L. de Andres , F. Guinea , M. I. Katsnelson

In addition to its exotic electronic properties graphene exhibits unusually high intrinsic thermal conductivity. The physics of phonons - the main heat carriers in graphene - was shown to be substantially different in two-dimensional (2D)…

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