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Solvent loss due to evaporation in a drying drop can drive capillary flows and solute migration. The flow is controlled by the evaporation profile and the geometry of the drop. We predict the flow and solute migration near a sharp corner of…

Soft Condensed Matter · Physics 2009-09-29 Rui Zheng , Yuri O. Popov , Thomas A. Witten

We use transition path sampling to study evaporation in the SPC/E model of liquid water. Based on thousands of evaporation trajectories, we characterize the members of the transition state ensemble (TSE), which exhibit a liquid-vapor…

Soft Condensed Matter · Physics 2014-09-05 Patrick Varilly , David Chandler

It is well-known that water in both liquid and vapor phases exhibits exceptionally weak absorption of light in the visible range. Recent experiments, however, have demonstrated that at the liquid-air interface, absorption in the visible…

Soft Condensed Matter · Physics 2025-01-16 Michael J. Landry , Chuliang Fu , James H. Zhang , Jiachen Li , Gang Chen , Mingda Li

We investigate experimentally the drying of a small volume of perfectly wetting liquid on two crossed fibers. We characterize the drying dynamics for the three liquid morphologies that are encountered in this geometry: drop, column and a…

Soft Condensed Matter · Physics 2015-03-12 François Boulogne , Alban Sauret , Beatrice Soh , Emilie Dressaire , Howard A. Stone

Drying of fluids undergoing sol-gel transition in porous media, a process crucial for the consolidation of damaged porous structures in cultural heritage, often leads to skin formation at the surface. This phenomenon significantly hinders…

Soft Condensed Matter · Physics 2025-09-29 Romane Le Dizès Castell , Marc Prat , Noushine Shahidzadeh , Sara Jabbari-Farouji

Evaporation of water droplets on a superhydrophobic substrate, on which the contact line is pinned, is investigated. While previous studies mainly focused on droplets with contact angles smaller than 90^\circ, here we analyze almost the…

The solvation of charged, nanometer-sized spherical solutes in water, and the effective, solvent-induced force between two such solutes are investigated by constant temperature and pressure Molecular Dynamics simulations of model solutes…

Soft Condensed Matter · Physics 2009-11-10 J. Dzubiella , J. -P. Hansen

Long liquid retention times in industrial gaps, due to capillary effects, significantly affect product lifetime by facilitating corrosion on solid surfaces. Concentration-driven evaporation plays a major role in mitigating this corrosion.…

Fluid Dynamics · Physics 2025-05-20 Phil Namesnik , Alexander Eifert , Anja Lippert , Louis Mett , Uwe Janoske

Evaporating suspensions of colloidal particles lead to the formation of a variety of patterns, ranging from a left-over ring of a dried coffee drop to uniformly distributed solid pigments left behind wet paint. To characterize the…

Soft Condensed Matter · Physics 2014-11-19 C. Nadir Kaplan , L. Mahadevan

We investigate the origin of the density depletion and enhanced density fluctuations that occur in water in the vicinity of an extended hydrophobic solute. We argue that both phenomena are remnants of the critical drying surface phase…

Soft Condensed Matter · Physics 2022-02-09 Mary K. Coe , Robert Evans , Nigel B. Wilding

The surface tension of a liquid, which drives most free surface flows at small scales, is often measured with the pendant drop method due to its simplicity and reliability. When the drop is suspended in air, controlling the ambient…

Fluid Dynamics · Physics 2025-08-12 Pim J. Dekker , Christian Diddens , Marjolein N. van der Linden , Detlef Lohse

Hydrophobic interactions are central to biological self-assembly and soft matter organization, yet their microscopic origins remain debated. A key hallmark is the strengthening of attraction between hydrophobic solutes with increasing…

Soft Condensed Matter · Physics 2025-09-25 Nigel B. Wilding , Francesco Turci

Our knowledge about the physical processes determining the activity of comets were mainly influenced by several extremely successful space missions, the predictions of theoretical models and the results of laboratory experiments. However,…

Earth and Planetary Astrophysics · Physics 2015-05-27 Bastian Gundlach , Yuri Skorov , Jürgen Blum

The distribution of liquid water in ice-free clouds determines their radiative properties, a significant source of uncertainty in weather and climate models. Evaporation and turbulent mixing cause a cloud to display large variations in…

Fluid Dynamics · Physics 2021-06-02 J. Fries , G. Sardina , G. Svensson , B. Mehlig

We characterize the water repartition within the partially saturated (two-phase) zone (PSZ) during evaporation out of mixed wettable porous media by controlling the wettability of glass beads, their sizes, and as well the surrounding…

Soft Condensed Matter · Physics 2017-12-27 C. Cejas , J. -C. Castaing , L. A. Hough , C. Fretigny , R. Dreyfus

In this paper, we present a mathematical model and numerical simulation of the evaporation and drying process of a liquid droplet containing suspended solids. This type of drying is commonly encountered in manufacturing processes such as…

Fluid Dynamics · Physics 2025-11-27 Anurag Bhattacharjee , Aswin Gnanaskandan

We investigate the curvature-dependence of water dynamics in the vicinity of hydrophobic spherical solutes using molecular dynamics simulations. For both, the lateral and perpendicular diffusivity as well as for H-bond kinetics of water in…

Soft Condensed Matter · Physics 2016-01-22 R. Gregor Weiß , Matthias Heyden , Joachim Dzubiella

A small amount of polymer dissolved in a droplet suppresses droplet rebound when it impinges on a supersolvophobic surface. This work investigates impacting dynamics of a droplet of dilute polymer solution depending on the molecular weight…

Soft Condensed Matter · Physics 2021-03-30 Eunsang Lee , Hari Krishna Chilukoti , Florian Müller-Plathe

In this paper, diffusion in polymer solutions undergoing evaporation of solvent is modeled as a coupled heat and mass transfer problem with moving boundary condition within the framework of nonequilibrium thermodynamics. The proposed…

Chemical Physics · Physics 2012-04-13 Siamak. Shams Es-haghi

A receding-front model for drying of porous material is proposed that explains their drying-rate curves based on the dynamics of the evaporation front. The falling-rate regime is attributed to the slowing down of the front's propagation…

Statistical Mechanics · Physics 2007-05-23 Reza Torabi , Mohammad Mehrafarin