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A key challenge in materials discovery is to find high-temperature superconductors. Hydrogen and hydride materials have long been considered promising materials displaying conventional phonon-mediated superconductivity. However, the high…

The first-principle method of mathematical modeling was used to calculate the structural, electronic, phonon, and other characteristics of the normal metallic phase of hydrogen at a pressure of 500 GPa. It has been shown that metal hydrogen…

Superconductivity · Physics 2016-07-06 Nikolay Degtyarenko , Evgeny Mazur

Recent experimental developments in hydrogen-rich materials in high pressures have put this class of materials above others in the race toward room temperature superconductivity. As it is the basis of all the materials in this class, the…

Superconductivity · Physics 2022-02-03 Mehmet Dogan , Sehoon Oh , Marvin L. Cohen

As the simplest element in nature, unraveling the phase diagram of hydrogen is a primary task for condensed matter physics. As conjectured many decades ago, in the low-temperature and high-pressure part of the phase diagram, solid hydrogen…

Superconductivity · Physics 2023-11-14 Mehmet Dogan , Sehoon Oh , Marvin L. Cohen

Following long-standing predictions associated with hydrogen, high-temperature superconductivity has recently been observed in several hydride-based materials. Nevertheless, these high-$T_c$ phases only exist at extremely high pressures,…

Ab initio molecular dynamic method within the framework of density functional theory is applied to analyze the structural and electronic properties of crystalline molecular hydrogen at temperature 100\,K. Pressure, pair correlation function…

Materials Science · Physics 2022-01-12 I. Saitov

The possibility of metallic hydrogen was first mooted by Wigner and Huntington in 1935. Here it is show that the calculations from that paper are in remarkably good agreement with modern density functional theory results. The possibility…

Materials Science · Physics 2017-09-18 Graeme J Ackland

Hydrogen sulfide (H2S) is a prototype molecular system and a sister molecule of water. The phase diagram of solid H2S at high pressures remains largely unexplored arising from the challenges in dealing with the looser S-H bond and larger…

Superconductivity · Physics 2015-03-26 Yinwei Li , Jian Hao , Yanling Li , Yanming Ma

The insulator to metal transition in solid hydrogen was predicted over 70 years ago but the demonstration of this transition remains a scientific challenge. In this regard, a peak in the temperature vs. pressure melting line of hydrogen may…

Materials Science · Physics 2009-11-13 Shanti Deemyad , Isaac F. Silvera

A possibility of high, room-temperature superconductivity was predicted for metallic hydrogen in the 1960s. However, metallization and superconductivity of hydrogen are yet to be unambiguously demonstrated in the laboratory and may require…

The 2014-2015 prediction, discovery, and confirmation of record high temperature superconductivity above 200K in H$_3$S, followed by the 2018 extension to superconductivity in the 250-280K range in lanthanum hydride, marks a new era in the…

Superconductivity · Physics 2019-11-13 Yundi Quan , Soham S. Ghosh , Warren E. Pickett

Hydrogen-rich compounds have been extensively studied both theoretically and experimentally in the quest for novel high-temperature superconductors. Reports on sulfur-hydride attaining metallicity under pressure and exhibiting…

The present review covers the production of new materials under high pressures. A primary limitation on the use of pressures higher than 1 GPa is a small volume and mass of a produced material. Therefore, despite an extremely wide range of…

Materials Science · Physics 2015-06-25 V. V. Brazhkin

We present computer simulations of liquid and solid phases of condensed methane at pressures below 25 GPa, between 150 and 300 K, where no appreciable molecular dissociation occurs. We used molecular dynamics (MD) and metadynamics…

Materials Science · Physics 2015-05-13 Leonardo Spanu , Davide Donadio , Detlef Hohl , Giulia Galli

The appropriateness of including Hg among the transition metals has been debated for a long time. Although the synthesis of HgF$_{4}$ molecules in gas phase was reported before, the molecules show strong instabilities and dissociate.…

Materials Science · Physics 2012-06-14 Xiaoli Wang , Haiqing Lin , Yanming Ma , Mao-Sheng Miao

The primary challenge in the field of high-temperature superconductivity in hydrides is to achieve a superconducting state at ambient pressure rather than the extreme pressures that have been required in experiments so far. Here, we propose…

Hydrogen-rich materials are the most promising candidates for high-temperature conventional superconductors under ambient pressure. Multinary hydrides have abundant structural configurations and are more promising to find high-temperature…

Superconductivity · Physics 2025-08-18 Bo-Wen Yao , Zhenfeng Ouyang , Xiao-Qi Han , Chang-Jiang Wu , Peng-Jie Guo , Ze-Feng Gao , Zhong-Yi Lu

Metal hydrogen exhibiting electron delocalization properties has been recognized as an important prospect for achieving controlled nuclear fusion, but the extreme pressure conditions required exceeding hundreds of GPa remain a daunting…

Computational Physics · Physics 2025-06-05 Jia Fan , Chenxi Wan , Rui Liu , Zhen Gong , Hongbo Jing , Baiqiang Liu , Siyang Liu , Zhigang Wang

Liquid-liquid phase transition of hydrogen is at the center of hydrogen phase diagram as a promising route towards emergent properties such as the Wigner-Huntington metallization, superconductivity, and superfluidity. Here we report a study…

Materials Science · Physics 2022-06-27 Jianqing Guo , Bingqing Cheng , Limei Xu , Enge Wang , Ji Chen

The measurement of superconductivity at above 200K in compressed samples of hydrogen sulfide and lanthanum hydride at 250K is reinvigorating the search for conventional high temperature superconductors. At the same time it exposes a…

Superconductivity · Physics 2019-10-02 Chris J. Pickard , Ion Errea , Mikhail I. Eremets