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We develop the tight-binding model to study electronic and optical properties of graphane. The strong sp3 chemical bondings among the carbon and hydrogen atoms induce a special band structure and thus lead to the rich optical excitations.…

Materials Science · Physics 2016-10-31 M. H. Lee , H. C. Chung , J. M. Lu , C. P. Chang , M. F. Lin

We study alpha, beta, and gamma graphyne, a class of graphene allotropes with carbon triple bonds, using a first-principles density-functional method and tight-binding calculation. We find that graphyne has versatile Dirac cones and it is…

Mesoscale and Nanoscale Physics · Physics 2013-03-12 Bog G. Kim , Hyoung Joon Choi

Using density-functional theory and a tight-binding approach we investigate the physical origin of distinct favourable geometries of adsorbed hydrogen atoms in various graphyne structures, and the relation with electronic properties. In…

Materials Science · Physics 2014-02-07 Hunpyo Lee , Jahyun Koo , Massimo Capone , Yongkyung Kwon , Hoonkyung Lee

We present a tight-binding parametrization for penta-graphene that correctly describes its electronic band structure and linear optical response. The set of parameters is validated by comparing to ab-initio density functional theory…

Materials Science · Physics 2020-12-25 Sergio Bravo , J. D. Correa , Leonor Chico , M. Pacheco

In this paper, three different materials Si, ITO and graphene; and three different types of mode structures bulk, slot and hybrid; based on their electrooptical and electro absorptive aspects in performance are analyzed. The study focuses…

Mesoscale and Nanoscale Physics · Physics 2016-12-09 Rubab Amin , Can Suer , Zhizhen Ma , Jacob B. Khurgin , Ritesh Agarwal , Volker J. Sorger

We use large scale ab-initio calculations to describe electronic structures of graphene, graphene nanoribbons, and carbon nanotubes periodically perforated with nanopores. We disclose common features of these systems and develop a unified…

Mesoscale and Nanoscale Physics · Physics 2011-07-25 Artem Baskin , Petr Kral

Graphdiynes (GDYs) as two-dimensional carbon structures based on sp2 hybridized aromatic rings connected by sp-hybridized acetylenic linear links are gathering an increasing popularity, both for their peculiar properties and for the…

Materials Science · Physics 2021-08-03 Patrick Serafini , Alberto Milani , Matteo Tommasini , Carlo E. Bottani , Carlo S. Casari

The electronic properties of a material depend on the spatial freedom of the electron wavefunction. A well-known example is graphite, which is a conventional gapless semiconductor, while a single layer of it, graphene, exhibits extremely…

Mesoscale and Nanoscale Physics · Physics 2026-01-28 Mohammadamir Bazrafshan , Thomas. D. Kühne

The microstructure, electronic structure, and chemical bonding of chromium carbide thin films with different carbon contents have been investigated with high-resolution transmission electron microscopy, electron energy loss spectroscopy and…

Mesoscale and Nanoscale Physics · Physics 2012-05-04 Martin Magnuson , Matilda Andersson , Jun Lu , Lars Hultman , Ulf Jansson

The shortcomings of mono-component systems, e.g., the gapless nature of graphene, the lack of air-stability in phosphorene, etc. have drawn great attention toward stacked materials expected to show interesting electronic and optical…

Mesoscale and Nanoscale Physics · Physics 2020-12-24 Maryam Mahdavifar , Sima Shekarforoush , Farhad Khoeini

Electronic many-body correlation effects in one-dimensional (1D) systems such as carbon nanotubes have been predicted to modify strongly the nature of photoexcited states. Here we directly probe this effect using broadband elastic light…

In this paper, we perform large-scale electron-correlated calculations of optoelectronic properties of rectangular graphene-like polycyclic aromatic hydrocarbon molecules. Theoretical methodology employed in this work is based upon…

Materials Science · Physics 2019-05-29 Deepak Kumar Rai , Alok Shukla

This work presents a systematic review of the feature-rich essential properties in graphene-related systems using the first-principles method. The geometric and electronic properties are greatly diversified by the number of layers, the…

Chemical Physics · Physics 2017-02-14 Ngoc Thanh Thuy Tran , Shih-Yang Lin , Chiun-Yan Lin , Ming-Fa Lin

In this paper we present a computational study of linear optical absorption in phenacene class of polyaromatic hydrocarbons. For the purpose, we have employed a correlated-electron methodology based upon configuration-interaction (CI)…

Materials Science · Physics 2018-10-17 Deepak Kumar Rai , Alok Shukla

We investigate the electronic and optical properties of lateral heterostructures made of alternated armchair ribbons of graphene and hexagonal boron nitride. It is known that the gapwidth of these heterostructures can be classified into…

Materials Science · Physics 2026-01-22 Elisa Serrano Richaud , Sylvain Latil , Lorenzo Sponza

A review work is done for electronic and optical properties of graphene nanoribbons in magnetic, electric, composite, and modulated fields. Effects due to the lateral confinement, curvature, stacking, non-uniform subsystems and hybrid…

Mesoscale and Nanoscale Physics · Physics 2016-03-10 Hsien-Ching Chung , Cheng-Peng Chang , Chiun-Yan Lin , Ming-Fa Lin

The family of graphynes, novel two-dimensional semiconductors with various and fascinating chemical and physical properties, has attracted great interest from both science and industry. Currently, the focus of graphynes is on graphdiyne, or…

Materials Science · Physics 2021-04-01 Yang Li , Junhan Wu , Chunmei Li , Qiang Wang , Lei Shen

We study the electronic properties of a twisted trilayer graphene, where two of the layers have Bernal stacking and the third one has a relative rotation with respect to the AB-stacked layers. Near the Dirac point, the AB-twisted trilayer…

Mesoscale and Nanoscale Physics · Physics 2013-04-02 E. Suárez Morell , M. Pacheco , L. Chico , L. Brey

A few years ago, by means of first-principles calculations, Enyashin et al.(2011) proposed several novel monolayers of carbon containing rings other than hexagons. One of those monolayers containing tetragons and octagons was investigated…

Materials Science · Physics 2025-06-26 Arifa Nazir , Alok Shukla

The structures, cohesive energies and HOMO-LUMO gaps of graphene nanoflakes and corresponding polycyclic aromatic hydrocarbons for a large variety of size and topology are investigated at the density functional based tight-binding level.…

Materials Science · Physics 2013-02-27 Agnieszka Kuc , Thomas Heine , Gotthard Seifert
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