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In this work we investigate methods to improve the efficiency and scalability of quantum algorithms for quantum chemistry applications. We propose a transformation of the electronic structure Hamiltonian in the second quantization framework…

The calculations of electronic transport coefficients and optical properties require a very dense interpolation of the electronic band structure in reciprocal space that is computationally expensive and may have issues with band crossing…

Classical integrable Hamiltonian systems generated by elements of the Poisson commuting ring of spectral invariants on rational coadjoint orbits of the loop algebra $\wt{\gr{gl}}^{+*}(2,{\bf R})$ are integrated by separation of variables in…

High Energy Physics - Theory · Physics 2009-10-22 John Harnad , P. Winternitz

Simulation of quantum chemistry is expected to be a principal application of quantum computing. In quantum simulation, a complicated Hamiltonian describing the dynamics of a quantum system is decomposed into its constituent terms, where the…

Quantum Physics · Physics 2020-03-04 Yingkai Ouyang , David R. White , Earl T. Campbell

The recently proposed excitonic renormalization framework presents an alternative ansatz to elec- tronic structure theory of weakly interacting fragments. It makes use of absolutely localized orbitals and correlated states evaluated on…

Chemical Physics · Physics 2025-08-01 Marco Bauer , Patrick Norman , Andreas Dreuw , Anthony D. Dutoi

We present a model of electron transport through a random distribution of interacting quantum dots embedded in a dielectric matrix to simulate realistic devices. The method underlying the model depends only on fundamental parameters of the…

Mesoscale and Nanoscale Physics · Physics 2012-07-25 S. Illera , J. D. Prades , A. Cirera , A. Cornet

A general formalism of the problem of perfect state transfer is presented. We show that there are infinitely many Hamiltonians which may provide solution to this problem. In a first attempt to give a classification of them we investigate…

Quantum Physics · Physics 2007-05-23 V. Kost'ak , G. M. Nikolopoulos , I. Jex

We suggest an efficient method to resolve electronic cusps in electronic structure calculations by using an effective transcorrelated Hamiltonian. This effective Hamiltonian takes a simple form for plane wave bases, containing up to…

Computational Physics · Physics 2018-02-14 Hongjun Luo , Ali Alavi

By using the properties of orthogonal polynomials, we present an exact unitary transformation that maps the Hamiltonian of a quantum system coupled linearly to a continuum of bosonic or fermionic modes to a Hamiltonian that describes a…

Quantum Physics · Physics 2010-10-04 Alex W. Chin , Ángel Rivas , Susana F. Huelga , Martin B. Plenio

We propose a new driving scheme, when different parts of a system are driven with different, generally incommensurate, frequencies. Such driving provides a flexible handle to control various properties of the system and to obtain new types…

Optics · Physics 2018-03-01 Huanan Li , Tsampikos Kottos , Boris Shapiro

In the strong electron-electron (e-e) interaction limit each atomic site is constrained to be either empty or singly occupied. One can treat this scenario by fractionalizing the electrons into spin and charge degrees of freedom. We use the…

Strongly Correlated Electrons · Physics 2025-05-13 Kaushal Kumar Kesharpu , Evgenii A. Kochetov , Alvaro Ferraz

The exact solution of Schrodinger equation for atoms, molecules and extended systems continues to be a "Holy Grail" problem that the entire field has been striving to solve since its inception. Recently, breakthroughs have been made in the…

Quantum Physics · Physics 2016-11-04 Rongxin Xia , Teng Bian , Sabre Kais

We present a way of partly reincorporate the effects of the localized bonding electrons on the dynamics of their itinerant counterparts in Hubbard-like Hamiltonians. This is done by relaxing the constraint that the former should be entirely…

Strongly Correlated Electrons · Physics 2020-09-23 T. V. Trevisan , Gustavo M. Monteiro , A. O. Caldeira

Accurate modeling of driven light-matter interactions is essential for quantum technologies, where natural and synthetic atoms are used to store and process quantum information, mediate interactions between bosonic modes, and enable…

Quantum Physics · Physics 2025-09-04 Martin Jirlow , Kunal Helambe , Axel M. Eriksson , Simone Gasparinetti , Tahereh Abad

Perturbation theory with respect to the kinetic energy of the heavy component of a two-component quantum system is introduced. An effective Hamiltonian that is accurate to second order in the inverse heavy mass is derived. It contains a new…

Quantum Physics · Physics 2024-06-21 Ryan Requist

We construct a Hamiltonian whose dynamics simulate the dynamics of every other Hamiltonian up to exponentially long times in the system size. The Hamiltonian is time-independent, local, one-dimensional, and translation invariant. As a…

Quantum Physics · Physics 2017-10-26 Thomas C. Bohdanowicz , Fernando G. S. L. Brandão

The intraband electromagnetic transitions in the framework of collective Hamiltonian for chiral and wobbling modes are calculated. By going beyond the mean field approximation on the orientations of rotational axis, the collective…

Nuclear Theory · Physics 2021-06-08 X. H. Wu , Q. B. Chen , P. W. Zhao , S. Q. Zhang , J. Meng

The goal of the present account is to review our efforts to obtain and apply a ``collective'' Hamiltonian for a few, approximately decoupled, adiabatic degrees of freedom, starting from a Hamiltonian system with more or many more degrees of…

Nuclear Theory · Physics 2009-09-25 G. Do Dang , A. Klein , N. R. Walet

We propose a refined scheme of deriving an effective low-energy Hamiltonian for materials with strong electronic Coulomb correlations beyond density functional theory (DFT). By tracing out the electronic states away from the target degrees…

Strongly Correlated Electrons · Physics 2017-08-09 Motoaki Hirayama , Takashi Miyake , Masatoshi Imada , Silke Biermann

We present a systematic derivation of effective lattice spin Hamiltonians derived from a rotationally invariant multi-orbital Hubbard model including a term ensuring Hund's rule coupling. The Hamiltonians are derived down-folding the…

Mesoscale and Nanoscale Physics · Physics 2020-01-29 Markus Hoffmann , Stefan Blügel
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