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The concentration of nanosheet suspensions is an important technological parameter which is commonly measured by optical spectroscopy using the absorption coefficient to transform absorbance into concentration. However for all 2D materials,…

Mesoscale and Nanoscale Physics · Physics 2015-11-16 Keith R. Paton , Jonathan N. Coleman

The non-linear response of infinite periodic solids to homogenous electric fields and collective atomic displacements is discussed in the framework of density functional perturbation theory. The approach is based on the 2n + 1 theorem…

Materials Science · Physics 2007-05-23 M. Veithen , X. Gonze , Ph. Ghosez

Clarifying the contribution of various atoms and structural units formed in nonlinear optical (NLO) crystal materials to macroscopic optical response is crucial for NLO crystal design. In this work, the rigorous atomic space tessellating…

Optics · Physics 2024-10-08 Yang Chi

Two dimensional few-layer black phosphorus crystal structures have recently fabricated and demonstrated great potential in applications of electronics. In this work, we employed first principles density functional theory calculations to…

Materials Science · Physics 2014-10-09 Xihong Peng , Qun Wei , Andrew Copple

Nonmonotonic bending-induced changes of fundamental band gaps and quasiparticle energies are observed for realistic nanoscale phosphorene nanosheets. Calculations using stochastic many-body perturbation theory (sGW) show that even slight…

Materials Science · Physics 2019-06-12 Vojtech Vlcek , Eran Rabani , Roi Baer , Daniel Neuhauser

The possibility of an inhomogeneous charge density wave phase is investigated in a system of two coupled electron and hole monolayers separated by a hexagonal boron nitride insulating layer. The charge density wave state is induced through…

Mesoscale and Nanoscale Physics · Physics 2018-12-26 S. Saberi-Pouya , M. Zarenia , T. Vazifehshenas , F. M. Peeters

On the basis of many-body {\it ab-initio} calculations, using single-shot G$_0$W$_0$ method and Bethe-Salpeter equation, we study phosphorene nanoribbons (PNRs) in the two typical zigzag and armchair directions. The electronic structure,…

Mesoscale and Nanoscale Physics · Physics 2016-12-16 Zahra Nourbakhsh , Reza Asgari

Two-dimensional materials tend to become crumpled according to the Mermin-Wagner theorem, and the resulting ripple deformation may significantly influence electronic properties as observed in graphene and MoS2. Here we unveil by…

Materials Science · Physics 2015-04-09 Liangzhi Kou , Yandong Ma , Sean C. Smith , Changfeng Chen

The effect of increased electron-density (from adsorbed Li atoms) in polyacenes and in nano-ribbons with zig-zag edge is discussed in terms of resonance theoretical considerations and in terms edge-localized frontier molecular orbitals. The…

Chemical Physics · Physics 2025-11-10 Yenni P. Ortiz , Douglas J. Klein , Thomas H. Seligman

Phosphorene, a two-dimensional (2D) monolayer of black phosphorus, has attracted considerable theoretical interest, although the experimental realization of monolayer, bilayer, and few-layer flakes has been a significant challenge. Here we…

In this study, we analyze the band structure, the state characterization, and electronic transport of monolayer black phosphorus (phosphorene) zigzag nanoribbons (zPNRs) and armchair nanoribbons (aPNRs), using five-parameter tight-binding…

Mesoscale and Nanoscale Physics · Physics 2015-08-17 Esmaeil Taghizadeh Sisakht , Mohammad H. Zare , Farhad Fazileh

We investigate nonlinear optical absorption in diamond crystals containing high densities of nitrogen vacancy (NV) centers using open-aperture Z-scan measurements with 230 fs laser pulses at 1032 nm, within the transparency window of…

Systematic exploration of amorphous ABC heterostructures revealed that nanoscale morphological modifications markedly improved their artificial bulk second-order susceptibility. These amorphous birefringent heterostructures were fabricated…

Matrix elements of electron-light interactions for armchair and zigzag graphene nanoribbons are constructed analytically using a tight-binding model. The changes in wavenumber ($\Delta n$) and pseudospin are the necessary elements if we are…

Materials Science · Physics 2011-09-05 K. Sasaki , K. Kato , Y. Tokura , K. Oguri , T. Sogawa

Zigzag edges of neutral armchair-oriented Graphene Nano-Ribbons show states strongly localized at those edges. They behave as free radicals that can capture electrons during processing, increasing ribbon's stability. Thus, charging and its…

Mesoscale and Nanoscale Physics · Physics 2019-07-26 E. Louis , E. San-Fabian , G. Chiappe , J. A. Verges

A multifold Hopf semimetal is a topological point node semimetal possessing an anisotropy in the internal electronic structure, e.g., the dipole structure of the Berry curvature. In this paper, the unique features of threefold Hopf…

Mesoscale and Nanoscale Physics · Physics 2023-01-18 Tetsuro Habe

In this work, we study the electronic and transport properties of phosphorene nanorings in two perpendicular directions (zigzag and armchair directions) in the presence of zigzag metallic source and drain leads. Our results are based on the…

Mesoscale and Nanoscale Physics · Physics 2024-01-10 MohammadAmir Bazrafshan , Farhad Khoeini , Bartlomiej Szafran

The second-order nonlinear optical susceptibility ($\chi_{abc}^{(2)}$) and linear electro-optical coefficient ($r_{abc}$) of a large number of single-walled zigzag, armchair and chiral SiC nanotubes (SiC-NTs) as well as bulk SiC polytypes…

Materials Science · Physics 2009-11-13 I. J. Wu , G. Y. Guo

Graphene is known to possess strong optical nonlinearity. Its nonlinear response can be further enhanced by graphene plasmons. Here, we report a novel nonlinear electro-absorption effect observed in nanostructured graphene due to excitation…

Mesoscale and Nanoscale Physics · Physics 2018-02-14 D. Kundys , B. Van Duppen , O. P. Marshall , F. Rodriguez , I. Torre , A. Tomadin , M. Polini , A. N. Grigorenko

Photo-physical and nonlinear-optical properties of a new amphiphilic conjugated polymer: hydroxylated pyridyl para-phenylene (Py-PhPPP) both in CH2Cl2 solution and in thin films have been investigated. By using Z-scan technique with…

Materials Science · Physics 2007-05-23 W. Ji , Hendry Izaac Elim , Jun He , F. Fitrilawati , C. Baskar , S. Valiyaveettil , W. Knoll