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Controlling the internal degrees of freedom is a key challenge for applications of cold and ultracold molecules. Here, we demonstrate rotational-state cooling of trapped methyl fluoride molecules (CH3F) by optically pumping the population…

This article investigates entanglement of the motional states of massive coupled oscillators. The specific realization of an idealized diatomic molecule in one-dimension is considered, but the techniques developed apply to any massive…

Quantum Physics · Physics 2015-03-13 N. L. Harshman , W. F. Flynn

For conventional ion traps, the trapping potential is close to independent of the electronic state, providing confinement for ions dependent primarily on their charge-to-mass ratio $Q/m$. In contrast, storing ions within an optical dipole…

We are pursuing an experiment to measure the electric dipole moment of the electron using the molecule PbO. This measurement requires the ability to prepare quantum states with orientation of the molecular axis and, simultaneously,…

Atomic Physics · Physics 2013-05-29 S. Bickman , P. Hamilton , Y. Jiang , D. DeMille

An enduring challenge for contemporary physics is to experimentally observe and control quantum behavior in macroscopic systems. We show that a single trapped atomic ion could be used to probe the quantum nature of a mesoscopic mechanical…

Quantum Physics · Physics 2007-05-23 W. K. Hensinger , D. W. Utami , H. -S. Goan , K. Schwab , C. Monroe , G. J. Milburn

State-selected Coulomb-crystallized molecular ions were employed for the first time in ion-molecule reaction studies using the prototypical charge-transfer process $\mathrm{N_2^++N_2\rightarrow N_2+N_2^+}$ as an example. By preparing the…

Chemical Physics · Physics 2015-06-05 Xin Tong , Tibor Nagy , Juvenal Yosa Reyes , Matthias Germann , Markus Meuwly , Stefan Willitsch

One limit to the fidelity of quantum logic operations on trapped ions arises from heating of the ions' collective modes of motion. Sympathetic cooling of the ions during the logic operations may eliminate this source of errors. We discuss…

A novel method of ground state laser cooling of trapped atoms utilizes the absorption profile of a three (or multi-) level system which is tailored by a quantum interference. With cooling rates comparable to conventional sideband cooling,…

Quantum Physics · Physics 2010-03-26 F. Schmidt-Kaler , J. Eschner , G. Morigi , C. F. Roos , D. Leibfried , A. Mundt , R. Blatt

Ultracold molecules confined in optical lattices or tweezer traps can be used to process quantum information and simulate the behaviour of many-body quantum systems. Molecules offer several advantages for these applications. They have a…

Quantum Gases · Physics 2024-01-11 Simon L. Cornish , Michael R. Tarbutt , Kaden R. A. Hazzard

A general method for rotational microwave spectroscopy and control of polar molecular ions via direct microwave addressing is considered. Our method makes use of spatially varying AC Stark shifts, induced by far off-resonant, focused laser…

Atomic Physics · Physics 2015-06-16 M. Shi , P. F. Herskind , M. Drewsen , I. L. Chuang

Observing a physical quantity without disturbing it is a key capability for the control of individual quantum systems. Such back-action-evading or quantum-non-demolition measurements were first introduced in the 1970s in the context of…

Quantum Physics · Physics 2013-08-21 M. R. Vanner , J. Hofer , G. D. Cole , M. Aspelmeyer

Precise control over rotational angular momentum is at the heart of recent advances in quantum chemistry, quantum simulation, and quantum computation with ultracold bialkali molecules. Each rotational state comprises a rich manifold of…

Atomic Physics · Physics 2025-11-11 Tom R. Hepworth , Simon L. Cornish , Philip D. Gregory

In recent years, ultracold atoms have emerged as an exceptionally controllable experimental system to investigate fundamental physics, ranging from quantum information science to simulations of condensed matter models. Here we go one step…

Atomic Physics · Physics 2015-05-20 Christoph Zipkes , Lothar Ratschbacher , Stefan Palzer , Carlo Sias , Michael Köhl

Laser-cooled and trapped atomic ions form an ideal standard for the simulation of interacting quantum spin models. Effective spins are represented by appropriate internal energy levels within each ion, and the spins can be measured with…

Molecules and atomic highly charged ions provide powerful low-energy probes of the fundamental laws of physics: Polar molecules possess internal fields suitable to enhance fundamental symmetry violation by several orders of magnitudes,…

Trapped, laser-cooled atoms and ions are quantum systems which can be experimentally controlled with an as yet unmatched degree of precision. Due to the control of the motion and the internal degrees of freedom, these quantum systems can be…

Over the past years, radiofrequency ion traps have become an attractive platform for studying chemical reactions as they enable a high degree of control over ion-molecule dynamics. In this review, we summarize techniques for the trapping…

Chemical Physics · Physics 2025-10-13 Prerna Paliwal , Jutta Toscano , Stefan Willitsch

We revisit quantum state preparation of an oscillator by continuous linear position measurement. Quite general analytical expressions are derived for the conditioned state of the oscillator. Remarkably, we predict that quantum squeezing is…

Quantum Physics · Physics 2020-07-29 Chao Meng , George A. Brawley , James S. Bennett , Michael R. Vanner , Warwick P. Bowen

We propose and demonstrate a scalable scheme for the simultaneous determination of internal and motional states in trapped ions with single-site resolution. The scheme is applied to the study of polaritonic excitations in the Jaynes-…

Quantum Physics · Physics 2021-12-15 Silpa Muralidharan , Ryutaro Ohira , Shota Kume , Kenji Toyoda

Quantum technologies exploit entanglement to revolutionize computing, measurements, and communications. This has stimulated the research in different areas of physics to engineer and manipulate fragile many-particle entangled states.…

Quantum Physics · Physics 2018-11-13 Luca Pezzè , Augusto Smerzi , Markus K. Oberthaler , Roman Schmied , Philipp Treutlein
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