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Most numerical methods for time integration use real-valued time steps. Complex time steps, however, can provide an additional degree of freedom, as we can select the magnitude of the time step in both the real and imaginary directions. We…

Numerical Analysis · Mathematics 2026-01-13 Jithin D. George , Julian Koellermeier , Samuel Y. Jung , Niall M. Mangan

The $O(N)$ stochastic propagation method, which relies on the numerical solution of the time-dependent Schr\"odinger equation using random initial states, is widely used in large-scale first-principles calculations. In this work, we…

Computational Physics · Physics 2025-10-22 Zhichang Fu , Yunhai Li , Weiqing Zhou , Shengjun Yuan

We propose a method for solving the time independent Schr\"odinger equation based on the von Neumann (vN) lattice of phase space Gaussians. By incorporating periodic boundary conditions into the vN lattice [F. Dimler et al., New J. Phys.…

Quantum Physics · Physics 2015-06-03 Asaf Shimshovitz , David J. Tannor

We show how the highly accurate and efficient Constant Perturbation (CP) technique for steady-state Schr\"odinger problems can be used in the solution of time-dependent Schr\"odinger problems with explicitly time-dependent Hamiltonians,…

Numerical Analysis · Mathematics 2014-06-24 Veerle Ledoux , Marnix Van Daele

In this paper, we study the Schr\"odinger equation with a Gaussian random potential (SE-GP) and develop an efficient numerical method to approximate the expectation of physical observables. The unboundedness of Gaussian random variables…

Numerical Analysis · Mathematics 2025-11-11 Zhizhang Wu , Zhiwen Zhang , Xiaofei Zhao

We propose a numerical scheme to solve the time dependent linear Schr\"odinger equation. The discretization is carried out by combining a Runge-Kutta time-stepping scheme with a finite element discretization in space. Since the…

Numerical Analysis · Mathematics 2018-03-07 Jens Markus Melenk , Alexander Rieder

The configuration interaction approach provides a conceptually simple and powerful approach to solve the Schr\"odinger equation for realistic molecules and materials but is characterized by an unfavourable scaling, which strongly limits its…

Chemical Physics · Physics 2022-08-16 B. Herzog , B. Casier , S. Lebègue , D. Rocca

We present a method based on the Path Integral Monte Carlo formalism for the calculation of ground-state time correlation functions in quantum systems. The key point of the method is the consideration of time as a complex variable whose…

Statistical Mechanics · Physics 2015-06-24 Riccardo Rota , Joaquim Casulleras , Ferran Mazzanti , Jordi Boronat

In this work, we develop a localized numerical scheme with low regularity requirements for solving time-fractional integro-differential equations. First, a fully discrete numerical scheme is constructed. Specifically, for temporal…

Numerical Analysis · Mathematics 2025-12-02 Lijing Zhao , Rui Zhao , Wenyi Tian , Yufeng Nie

We address the problem of identifying the (nonstationary) quantum systems that admit supersymmetric dynamical invariants. In particular, we give a general expression for the bosonic and fermionic partner Hamiltonians. Due to the…

Quantum Physics · Physics 2009-11-07 Ali Mostafazadeh

The Schroedinger equation with an energy-dependent complex absorbing potential, associated with a scattering system, can be reduced for a special choice of the energy-dependence to a harmonic inversion problem of a discrete pseudo-time…

Chemical Physics · Physics 2009-11-07 A. Neumaier , V. A. Mandelshtam

We develop a real-time Full Configuration Interaction Quantum Monte Carlo approach for the modeling of driven-dissipative open quantum systems. The method enables stochastic sampling of the Liouville-von-Neumann time evolution of the…

Quantum Physics · Physics 2018-06-06 Alexandra Nagy , Vincenzo Savona

We analyze the accuracy and sample complexity of variational Monte Carlo approaches to simulate the dynamics of many-body quantum systems classically. By systematically studying the relevant stochastic estimators, we are able to: (i) prove…

Quantum Physics · Physics 2023-10-11 Alessandro Sinibaldi , Clemens Giuliani , Giuseppe Carleo , Filippo Vicentini

A derivation of stochastic Schrodinger equations is given using quantum filtering theory. We study an open system in contact with its environment, the electromagnetic field. Continuous observation of the field yields information on the…

Quantum Physics · Physics 2011-06-23 Luc Bouten , Madalin Guta , Hans Maassen

The goal of this paper is to provide an analysis of the ``toolkit'' method used in the numerical approximation of the time-dependent Schr\"odinger equation. The ``toolkit'' method is based on precomputation of elementary propagators and was…

Optimization and Control · Mathematics 2009-07-14 Lucie Baudouin , Julien Salomon , Gabriel Turinici

We present a detailed discussion of our novel diagrammatic coupled cluster Monte Carlo (diagCCMC) [Scott et al. J. Phys. Chem. Lett. 2019, 10, 925]. The diagCCMC algorithm performs an imaginary-time propagation of the similarity-transformed…

Chemical Physics · Physics 2020-10-28 Charles J. C. Scott , Roberto Di Remigio , T. Daniel Crawford , Alex J. W. Thom

Schr\"odinger equations with time-dependent potentials are of central importance in quantum physics and theoretical chemistry, where they aid in the simulation and design of systems and processes at atomic scales. Numerical approximation of…

Numerical Analysis · Mathematics 2018-06-04 Arieh Iserles , Karolina Kropielnicka , Pranav Singh

A fast and stable numerical method is formulated to compute the time evolution of a wave function in a magnetic field by solving the time-dependent Schroedinger equation. This computational method is based on the finite element method in…

Computational Physics · Physics 2009-11-06 Naoki Watanabe , Masaru Tsukada

Given access to accurate solutions of the many-electron Schr\"odinger equation, nearly all chemistry could be derived from first principles. Exact wavefunctions of interesting chemical systems are out of reach because they are NP-hard to…

Chemical Physics · Physics 2021-03-26 David Pfau , James S. Spencer , Alexander G. de G. Matthews , W. M. C. Foulkes

We present a program to simulate the dynamics of a wave packet interacting with a time-dependent potential. The time-dependent Schr\"odinger equation is solved on a one-, two-, or three-dimensional spatial grid using the split operator…

Computational Physics · Physics 2013-11-21 C. M. Dion , A. Hashemloo , G. Rahali