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Utilizing quantum computer to investigate quantum chemistry is an important research field nowadays. In addition to the ground-state problems that have been widely studied, the determination of excited-states plays a crucial role in the…

Computing excited-state properties of molecules and solids is considered one of the most important near-term applications of quantum computers. While many of the current excited-state quantum algorithms differ in circuit architecture,…

Quantum Physics · Physics 2024-03-19 Carlos L. Benavides-Riveros , Yuchen Wang , Samuel Warren , David A. Mazziotti

We give a prescription for finding optimized correlation functions for the extraction of the gap to the first excited state within quantum Monte Carlo simulations. We demonstrate that optimized correlation functions provide a more accurate…

Statistical Mechanics · Physics 2012-03-20 Itay Hen

Eigenvector continuation (EC) has recently attracted a lot attention in nuclear structure and reactions as a variational resummation tool for many-body expansions. While previous applications focused on ground-state energies, excited states…

Nuclear Theory · Physics 2022-06-09 Margarida Companys Franzke , Alexander Tichai , Kai Hebeler , Achim Schwenk

We develop a cubic scaling approach to excited-state-specific second order perturbation theory in which the completeness of a local correlation treatment is carefully matched between the ground and excited state. With this matching, the…

Chemical Physics · Physics 2025-05-14 Rachel Clune , Eric Neuscamman

We develop a variational principle to determine the quantum controls and initial state which optimizes the quantum Fisher information, the quantity characterizing the precision in quantum metrology. When the set of available controls is…

Quantum Physics · Physics 2022-04-27 Jing Yang , Shengshi Pang , Zekai Chen , Andrew N. Jordan , Adolfo del Campo

We present a detailed analysis of methods to reduce statistical errors and excited-state contamination in the calculation of matrix elements of quark bilinear operators in nucleon states. All the calculations were done on a 2+1 flavor…

High-quality random samples of quantum states are needed for a variety of tasks in quantum information and quantum computation. Searching the high-dimensional quantum state space for a global maximum of an objective function with many local…

Quantum Physics · Physics 2015-04-28 Jiangwei Shang , Yi-Lin Seah , Hui Khoon Ng , David John Nott , Berthold-Georg Englert

A notion of quantum natural evolution strategies is introduced, which provides a geometric synthesis of a number of known quantum/classical algorithms for performing classical black-box optimization. Recent work of Gomes et al. [2019] on…

Quantum Physics · Physics 2020-11-23 Tianchen Zhao , Giuseppe Carleo , James Stokes , Shravan Veerapaneni

A fundamental challenge in quantum physics is determining the ground-state properties of many-body systems. Whereas standard approaches, such as variational calculations, consist of writing down a wave function ansatz and minimizing over…

Quantum Physics · Physics 2026-04-03 Jie Wang , David Jansen , Irénée Frerot , Marc-Olivier Renou , Victor Magron , Antonio Acín

The famous, yet unsolved, Fermi-Hubbard model for strongly-correlated electronic systems is a prominent target for quantum computers. However, accurately representing the Fermi-Hubbard ground state for large instances may be beyond the…

A ubiquitous problem in quantum physics is to understand the ground-state properties of many-body systems. Confronted with the fact that exact diagonalisation quickly becomes impossible when increasing the system size, variational…

Quantum state tomography is an integral part of quantum computation and offers the starting point for the validation of various quantum devices. One of the central tasks in the field of state tomography is to reconstruct with high fidelity,…

Quantum Physics · Physics 2022-12-21 Rishabh Gupta , Manas Sajjan , Raphael D. Levine , Sabre Kais

Within the present noisy intermediate-scale quantum-computing era, hybrid quantum-classical-processor algorithms have emerged as promising avenues for tackling electronic-structure eigenproblems. Among them, the so-called…

Quantum Physics · Physics 2026-05-21 Christophe Soule , Bruno Senjean , Benjamin Lasorne

Recently developed tensor network methods demonstrate great potential for addressing the quantum many-body problem, by constructing variational spaces with polynomially, instead of exponentially, scaled parameters. Constructing such an…

Strongly Correlated Electrons · Physics 2015-06-15 Zhen Wang , Yongjian Han , Guang-Can Guo , Lixin He

Control variates are a well-established tool to reduce the variance of Monte Carlo estimators. However, for large-scale problems including high-dimensional and large-sample settings, their advantages can be outweighed by a substantial…

Machine Learning · Statistics 2021-07-22 Shijing Si , Chris. J. Oates , Andrew B. Duncan , Lawrence Carin , François-Xavier Briol

A statistical learning approach for parametric PDEs related to Uncertainty Quantification is derived. The method is based on the minimization of an empirical risk on a selected model class and it is shown to be applicable to a broad range…

Numerical Analysis · Mathematics 2020-01-07 Martin Eigel , Reinhold Schneider , Philipp Trunschke , Sebastian Wolf

In the last decade, sequential Monte-Carlo methods (SMC) emerged as a key tool in computational statistics. These algorithms approximate a sequence of distributions by a sequence of weighted empirical measures associated to a weighted…

Statistics Theory · Mathematics 2007-06-13 R. Douc , France E. Moulines

Variational techniques have long been at the heart of atomic, solid-state, and many-body physics. They have recently extended to quantum and classical machine learning, providing a basis for representing quantum states via neural networks.…

Quantum Physics · Physics 2025-04-10 Thomas Spriggs , Arash Ahmadi , Bokai Chen , Eliska Greplova

Monte Carlo methods are widely used importance sampling techniques for studying complex physical systems. Integrating these methods with deep learning has significantly improved efficiency and accuracy in high-dimensional problems and…

Disordered Systems and Neural Networks · Physics 2024-12-24 Yixiong Ren , Jianhui Zhou