Related papers: Electrode Reactions in Slowly Relaxing Media
Electrostatic reaction inhibition in heterogeneous catalysis emerges if charged reactants and products are adsorbed on the catalyst and thus repel the approaching reactants. In this work, we study the effects of electrostatic inhibition on…
Melting is an everyday phase transition that is determined by thermodynamic parameters like temperature and pressure. In contrast, ultrafast melting is governed by the microscopic response to a rapid energy input and, thus, can reveal the…
Applying a macroscopic reduction procedure on the improved quantum molecular dynamics (ImQMD) model, the energy dependences of the nucleus-nucleus potential, the friction parameter, and the random force characterizing a one-dimensional…
By studying fluctuations in the electrostatic potential of a single electrode immersed in a cold plasma, we were able to perform in situ electron spectroscopy. Electron exchange processes that occur at the surface of the electrode were…
We study various models of independent particles hopping between energy `traps' with a density of energy barriers $\rho(E)$, on a $d$ dimensional lattice or on a fully connected lattice. If $\rho(E)$ decays exponentially, a true dynamical…
The ultrarelativistic collisions of heavy ions provide rich spectrum of possibilities to discuss the response of the nucleus to photons. Newly published neutron and proton multiplicities measured in the ALICE experiment in ultraperipheral…
Ultracold plasmas are a promising candidate for the creation of strongly-coupled Coulomb systems. Unfortunately, the values of the coupling parameter Gamma_e actually achieved after photoionization of the neutral atoms remain relatively…
Molecular structures with multiple donor, bridge, or acceptor units can display quantum interference effects that influence electron and energy transfer (ET and EnT) rates. Recent experiments found a 4- to 5-fold increase in ET rates for…
The slow down of dynamics in glass forming liquids as the glass transition is approached has been characterised through the Adam-Gibbs relation, which relates relaxation time scales to the configurational entropy. The Adam-Gibbs relation…
Electrochemical energy systems rely on particulate porous electrodes to store or convert energies. While the three-dimensional porous structures were introduced to maximize the interfacial area for better overall performance of the system,…
We propose a scenario for the glass transition based on the cooperative nature of nucleation processes and entropic effects. The main point is the relation between the off-equilibrium energy dissipation and nucleation processes in…
We study the consequences of the constant-temperature behaviour of nuclei in the superfluid regime for the exchange of excitation energy between two nuclei in thermal contact. This situation is realized at the scission configuration of…
We consider weakly ionized plasma where frequent elastic scattering of electrons on neutrals change the individual acts and the rate of electron-electron collisions significantly. In this case, the kinetics of electron thermalization is…
We study the relaxation dynamics of laser-excited non-equilibrium electron distributions in the valence- and conduction band of a dielectric. We apply Boltzmann collision integrals to trace the influence of different scattering mechanisms…
The cross sections of the $^3$He($\alpha$,$\alpha$)$^3$He and $^3$He($\alpha$,$\gamma$)$^7$Be reactions are studied at low energies using a simple two-body model in combination with a double-folding potential. At very low energies the…
Exploring controllable interactions lies at the heart of quantum science. Neutral Rydberg atoms provide a versatile route toward flexible interactions between single quanta. Previous efforts mainly focused on the excitation…
We consider a class of reaction-diffusion equations with a stochastic perturbation on the boundary. We show that in the limit of fast diffusion, one can rigorously approximate solutions of the system of PDEs with stochastic Neumann boundary…
A phenomenological theory of electric double layer polarization of blocking electrode is presented solving modified Debye-Falkenhagen (MDF) equation for potential, under the impedance boundary condition. The dynamic impedance and…
A model is described, in which electrical breakdown in high-voltage systems is caused by stochastic fluctuations of the mobile dislocation population in the cathode. In this model, the mobile dislocation density normally fluctuates, with a…
Electron transfer organic reaction rates are considered employing the classic physical picture of Marcus wherein the heats of reaction are deposited as the energy of low frequency mechanical oscillations of reconfigured molecular positions.…