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In this study, we use first-principles calculations to investigate the stacking-dependent electronic properties of GaSe/GaTe van der Waals heterobilayers. By analyzing five representative stacking configurations--AA, AA$'$, A$'$C, A$'$B,…

Materials Science · Physics 2025-06-24 Hsin-Yi Liu , Jhao-Ying Wu

This work presents a survey of mechanical models describing van der Waals interactions between 2D materials, encompassing both continuous elastomer-like materials and discrete (crystalline) 2D materials such as graphene. These interactions…

Computational Physics · Physics 2025-12-30 Gourav Yadav , Shakti S. Gupta , Roger A. Sauer

Stacking mismatches in hexagonal boron nitride (h-BN) nanostructures affect their photonic, mechanical, and thermal properties. To access information about the stacked configuration of layered ensembles, highly sophisticated techniques like…

Materials Science · Physics 2021-03-03 Luigi Cigarini , Michal Novotný , František Karlický

In this work we demonstrate that a free-standing van der Waals heterostructure, usually regarded as a flat object, can exhibit an intrinsic buckled atomic structure resulting from the interaction between two layers with a small lattice…

Heterostructures made of stacked 2D materials with different electronic properties are studied for their potential in creating multifunctional devices. Graphene (G) and hexagonal boron nitride (h-BN) van der Waals (vdW) systems have been…

Materials Science · Physics 2023-03-16 D. P. de Andrade Deus , J. M. J. Lopes , Roberto H. Miwa

Intercalation reactions modify the charge density in van der Waals (vdW) materials through coupled electronic-ionic charge accumulation, and are susceptible to modulation by interlayer hybridization in vdW heterostructures. Here, we…

Recent progress in preparing well controlled 2D van der Waals heterojunctions has opened up a new frontier in materials physics. In this paper we address the intriguing energy gaps that are sometimes observed when a graphene sheet is placed…

Mesoscale and Nanoscale Physics · Physics 2015-02-23 Jeil Jung , Ashley DaSilva , Allan H. MacDonald , Shaffique Adam

Combining both vertical and in-plane two-dimensional (2D) heterostructures opens up the possibility to create an unprecedented architecture using 2D atomic layer building blocks. The thermal transport properties of such mixed…

Materials Science · Physics 2020-07-16 Ting Liang , Ping Zhang , Man Zhou , Peng Yuan , Daoguo Yang

There is enormous recent interest in weak, van der Waals-type (vdW) interactions due to their fundamental relevance for two-dimensional materials and the so-called vdW heterostructures. Tackling this problem using computer simulation is…

Materials Science · Physics 2019-08-20 Fabian Schulz , Peter Liljeroth , Ari Paavo Seitsonen

The dependence of the Raman spectrum on the excitation energy has been investigated for ABA-and ABC- stacked few-layer graphene in order to establish the fingerprint of the stacking order and the number of layers, which affect the transport…

Mesoscale and Nanoscale Physics · Physics 2014-04-23 The An Nguyen , Jae-Ung Lee , Duhee Yoon , Hyeonsik Cheong

Exchange-correlation functionals with corrections for van der Waals interactions (PBE-D2, PBE-D3, PBE-D3(BJ), PBE-TS, optPBE-vdW and vdW-DF2) are tested for graphene and hexagonal boron nitride, both in the form of bulk and bilayer. The…

Mesoscale and Nanoscale Physics · Physics 2018-08-22 Irina V. Lebedeva , Alexander V. Lebedev , Andrey M. Popov , Andrey A. Knizhnik

Single layers of transition-metal thiophosphates (2D-TMPS$_{3}$) van der Waals magnets are an ideal platform for studying antiferromagnetic interactions in two dimensions. However, the magnetic coupling mechanism between two or more…

Materials Science · Physics 2024-10-18 Andrea León , Beatriz Costa , Thomas Heine , Thomas Brumme

$\alpha$-graphyne is a two-dimensional sheet of $sp$-$sp^2$ hybridized carbon atoms in a honeycomb lattice. While the geometrical structure is similar to that of graphene, the hybridized triple bonds give rise to electronic structure that…

Materials Science · Physics 2017-08-04 Hyeondeok Shin , Jeongnim Kim , Hoonkyung Lee , Olle Heinonen , Anouar Benali , Yongkyung Kwon

The incommensurate stacking of multi-layered two-dimensional materials is a challenging problem from a theoretical perspective and an intriguing avenue for manipulating their physical properties. Here we present a multi-scale model to…

Mesoscale and Nanoscale Physics · Physics 2020-07-01 Ziyan Zhu , Paul Cazeaux , Mitchell Luskin , Efthimios Kaxiras

When two-dimensional atomic crystals are brought into close proximity to form a van der Waals heterostructure, neighbouring crystals can start influencing each others electronic properties. Of particular interest is the situation when the…

We identify qualitative trends in the stacking sequence dependence of carrier-carrier interaction phenomena in multilayer graphene. Our theory is based on a new approach which explicitly exhibits the important role in interaction phenomena…

Mesoscale and Nanoscale Physics · Physics 2016-09-30 Yunsu Jang , E. H. Hwang , A. H. MacDonald , Hongki Min

An anisotropic interlayer potential that can accurately describe the van der Waals interaction of the water-graphene interface is presented. The force field is benchmarked against the many-body dispersion-corrected density functional…

Chemical Physics · Physics 2022-12-22 Zhicheng Feng , Yuanpeng Yao , Jianxin Liu , Bozhao Wu , Ze Liu , Wengen Ouyang

We show that two graphene layers stacked directly on top of each other (AA stacking) form strong chemical bonds when the distance between planes is 0.156 nm. Simultaneously, C-C in-plane bonds are considerably weakened from partial…

Materials Science · Physics 2008-02-27 P. L. de Andres , R. Ramirez , J. A. Verges

Graphite and hexagonal boron nitride (h-BN) are two prominent members of the family of layered materials possessing a hexagonal lattice. While graphite has non-polar homo-nuclear C-C intra-layer bonds, h-BN presents highly polar B-N bonds…

Materials Science · Physics 2012-04-16 Oded Hod

We present a comprehensive first-principles investigation of the structural, electronic, and vibrational properties of four layered boron nitride (BN) polymorphs--AA-stacked ($e$-BN), AA$^\prime$-stacked ($h$-BN), ABC-stacked ($r$-BN), and…

Materials Science · Physics 2025-05-23 Priyanka Mishra , Nevill Gonzalez Szwacki