Related papers: Electron Excitation of High Dipole Moment Molecule…
Utilising previous work by the authors on the spin-coupled rotational cross-sections for electron-CN collisions, data for the associated rate coefficients is presented. Data on rotational, fine-structure and hyperfine-structure transition…
The optically thin critical densities and the effective excitation densities to produce a 1 K km/s (or 0.818 Jy km/s $(\frac{\nu_{jk}}{100 \rm{GHz}})^2 \, (\frac{\theta_{beam}}{10^{\prime\prime}})^2$) spectral line are tabulated for 12…
HCN is considered a good tracer of the dense molecular gas that serves as fuel for star formation. However, recent large-scale surveys of giant molecular clouds (GMCs) have detected extended HCN line emission. Such observations often…
Rotational excitation of isotopologues of HCN and HNC by thermal electron-impact is studied using the molecular {\bf R}-matrix method combined with the adiabatic-nuclei-rotation (ANR) approximation. Rate coefficients are obtained for…
Magnetic precursors of C-shocks accelerate, compress and heat molecular ions, modifying the kinematics and the physical conditions of the ion fluid with respect to the neutral one. Electron densities are also expected to be significantly…
We consider excitation of highly charged hydrogen-like ions by the impact of equivelocity electrons and protons. The kinetic energy of the protons is more than three orders of magnitude larger than that of the equivelocity electrons. It is…
[This is truncated to suit the whims of the archivers ...] Parameter studies in LVG models are used to show how the low-lying rotational transitions of common polar molecules HCO+, HCN and CS vary with number density, column density and…
The electric dipole moments of $(H_{2}O)_{n}DCl$ ($n=3-9$) clusters have been measured by the beam deflection method. Reflecting the (dynamical) charge distribution within the system, the dipole moment contributes information about the…
Emission lines from highly-excited states (n >= 5) of H- and He-like ions have been detected in astrophysical sources and fusion plasmas. For such excited states, R-matrix or distorted wave calculations for electron-impact excitation are…
The dynamics of molecular electron excitation and ionisation is studied in real-time for ultra-short IR laser pulses of intensity I>10^{13} W/cm^{2}. The multi-electron molecule is modeled by a system of two active electrons moving in a…
The grating instruments on board Chandra and XMM-Newton now allow measurements of electron densities. These rely on the ratios of fluxes in emission lines, where one line depends on both collisional and radiative decay rates. The electron…
Modeling of molecular emission from interstellar clouds requires the calculation of rates for excitation by collisions with the most abundant species. The present paper focuses on the calculation of rate coefficients for rotational…
We present new observations of HCN and HCO+in the circumnuclear disk (CND) of the Galaxy, obtained with the APEX telescope. We have mapped emission in rotational lines of HCN J = 3-2, 4-3, and 8-7, as well as HCO+ J = 3-2, 4-3, and 9-8. We…
Observations of CO+ suggest column densities on the order 10^12 cm^-2 that can not be reproduced by many chemical models. CO+ is more likely to be destroyed than excited in collisions with hydrogen. An anomalous excitation mechanism may…
We present an observational and theoretical study of the ionization fraction in several massive cores located in regions that are currently forming stellar clusters. Maps of the emission from the J = 1-> O transitions of C18O, DCO+, N2H+,…
Photoionization by high-energy photons creates nonthermal electrons with a broad range of energies that heat and chemically transform the atmospheres of planets. The specifics of the interactions are notably different when the gas is atomic…
Soft x-ray radiation from the sun is responsible for the production of high energy photoelectrons in the D and E regions of the ionosphere, where they deposit most of their ionization energy. The photoelectrons created by this process are…
We present observations in CO(3-2) that, combined with previous observations in CO(2-1), constrain the physical properties of the filamentary molecular gas in the central $\sim$6.5 kpc of NGC 1275, the central giant elliptical galaxy of the…
Developing a detailed understanding for the role of core electron excitation in liquid water under proton irradiation has become important due to the growing use of proton beams in radiation oncology. Using a first-principles,…
Calculations of transition intensities for small molecules like H$_2$O, CO, CO$_2$ based on s high-quality potential energy surface (PES) and dipole moment surface (DMS) can nowadays reach sub-percent accuracy. An extension of this…