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Cadmium sulfide (CdS) is a well-known low-bandgap photocatalyst, but its efficiency is often hindered by rapid photo-generated carrier recombination and a limited number of active catalytic sites. To overcome these challenges, this study…

On basis of the first principle calculation we show that a crystalline structure of silicon, as a novel allotrope with nanotubular holes along two perpendicular directions, is stable. The calculations on geometrical and electronic…

Materials Science · Physics 2011-06-16 Chi-Pui Tang , Jie Cao , Shi-Jie Xiong

Understanding the covalent clathrate formation is a crucial point for the design of new superhard materials with intrinsic coupling of superhardness and metallic conductivity. Silicon clathrates have the archetype structures that can serve…

Halide double perovskites have recently been proposed as potential environmentally friendly alternatives to organic group and lead based hybrid halide perovskites. In particular, Cs2BiAgX6 have been synthesized and found to exhibit tunable…

Applied Physics · Physics 2019-05-03 Yunting Liang

We present state-of-the-art first-principle calculations of the electronic and optical properties of silicon allotropes with interesting characteristics for applications in thin-film solar cells. These new phases consist of distorted sp$^3$…

The endeavor to selectively fabricate a cubic diamond is challenging due to the formation of competing phases such as its hexagonal polymorph or others possessing similar free energy. The necessity to achieve this is of paramount importance…

Chemical Physics · Physics 2024-04-05 Łukasz Baran , Dariusz Tarasewicz , Daniel M. Kamiński , Wojciech Rżysko

Silicon is the most popular material used in electronic devices. However, its poor optical properties owing to its indirect band gap nature limit its usage in optoelectronic devices. Here we present the discovery of super-stable…

Materials Science · Physics 2015-04-17 Young Jun Oh , In-Ho Lee , Sunghyun Kim , Jooyoung Lee , K. J. Chang

The achievement of selectivity in the formation of cubic diamond is challenging due to the emergence of competing phases such as its hexagonal polymorph or clathrates possessing similar free energy. Although both polymorphs exhibit a…

Soft Condensed Matter · Physics 2025-01-14 Dariusz Tarasewicz , Edyta Raczyłło , Wojciech Rżysko , Łukasz Baran

Hybrid peroskite solar cells are newly emergent high-performance photovoltaic devices, which suffer from disadvantages such as toxic elements, short-term stabilities, and so on. Searching for alternative perovskites with high photovoltaic…

Materials Science · Physics 2023-08-02 Linkang Zhan , Danfeng Ye , Xinjian Qiu , Yan Cen

Nanostructures, especially of silicon, are of paramount importance for new generation solar cell applications. The key material requirements for solar cells are good electrical conductivity, confinement of excitons, and a tunable band-gap…

Highly-efficient water splitting based on solar energy is one of the most attractive research focuses in the energy field. Searching for more candidate photocatalysts that can work under visible-light irradiation are highly demanded.…

Materials Science · Physics 2024-09-17 Yun-Lai Zhu , Jun-Hui Yuan , Ya-Qian Song , Sheng Wang , Kan-Hao Xue , Ming Xu , Xiao-Min Cheng , Xiang-Shui Miao

We report on the formation and development of the photonic band gap in two-dimensional 8-, 10- and 12-fold symmetry quasicrystalline lattices of low index contrast. Finite size structures made of dielectric cylindrical rods were studied and…

Optics · Physics 2011-03-01 Priya Rose , E. Di Gennaro , G. Abbate , A. Andreone

The ability to selectively redirect specific wavelengths of light has attracted a lot attention for photonic crystal materials. Presently, there is a wealth of research relating to the fabrication and application of photonic crystal…

Optics · Physics 2022-08-23 Alex Lonergan , Colm O'Dwyer

Organic molecular crystals are appealing for next-generation optoelectronic applications, most notably due to their multiexciton generation process that can increase the efficiency of photovoltaic devices. However, a general understanding…

Materials Science · Physics 2021-11-01 Aaron R. Altman , Sivan Refaely-Abramson , Felipe H. da Jornada

Investigations of clathrate structures have gained a new impetus with the recent discovery of room-temperature superconductivity in metal hydrides. Here we report the finding, through density functional theory calculations, of a clathrate…

Materials Science · Physics 2021-08-02 Jorge Laranjeira , Leonel Marques , Manuel Melle-Franco , Karol Strutynski , Manuel Barroso

Crystal structure design is important for the discovery of new highly functional materials because crystal structure strongly influences material properties. Crystal structures are composed of space-filling polyhedra, which affect material…

Materials Science · Physics 2024-02-06 Tomoyasu Yokoyama , Kazuhide Ichikawa , Hisashi Naito

It is shown that small inclusions of a low absorbing metal can have a dramatic effect on the photonic band structure. In the case of diamond and zinc-blende photonic crystals, several complete photonic band gaps (CPBG's) can open in the…

Materials Science · Physics 2007-05-23 Alexander Moroz

Selenium is experiencing renewed interest as a promising candidate for the wide bandgap photoabsorber in tandem solar cells. However, despite the potential of selenium-based tandems to surpass the theoretical efficiency limit of single…

The photosensitivity of silicon is inherently very low in the visible electromagnetic spectrum, and it drops rapidly beyond 800 nm in near-infrared wavelengths. Herein, we have experimentally demonstrated a technique utilizing…

The long theorized two-dimensional allotrope of SiC has remained elusive amid the exploration of graphenelike honeycomb structured monolayers. It is anticipated to possess a large direct band gap (2.5 eV), ambient stability, and chemical…