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We give a new reduction of a general diatomic molecular Hamiltonian, without modifying it near the collision set of nuclei. The resulting effective Hamiltonian is the sum of a smooth semiclassical pseudodifferential operator (the…

Mathematical Physics · Physics 2015-06-26 André Martinez , Vania Sordoni

A new computational method for finite-temperature properties of strongly correlated electrons is proposed by extending the variational Monte Carlo method originally developed for the ground state. The method is based on the path integral in…

Strongly Correlated Electrons · Physics 2016-06-10 Kensaku Takai , Kota Ido , Takahiro Misawa , Youhei Yamaji , Masatoshi Imada

A remarkable thermodynamic fermion-boson symmetry is found for the canonical ensemble of ideal quantum gases in harmonic oscillator potentials of odd dimensions. The bosonic partition function is related to the fermionic one extended to…

Statistical Mechanics · Physics 2015-06-25 H. -J. Schmidt , J. Schnack

We consider quantum-to-classical mapping for an arbitrary system of interacting spins at finite temperatures. We prove that, in the large-$S$ limit, the asymptotic form of the partition function coincides with that of a classical model for…

Statistical Mechanics · Physics 2026-02-19 A. El Mendili , M. E. Zhitomirsky

When studying the thermodynamic properties of mesoscopic systems the most appropriate microcanonical entropy is the volume entropy, i.e. the logarithm of the volume of phase space enclosed by the hypersurface of constant energy. For systems…

Statistical Mechanics · Physics 2007-09-10 Michele Campisi

Reconstructing Hamiltonians from local measurements is key to enabling reliable quantum simulation: both validating the implemented model, and identifying any left-over terms with sufficient precision is a problem of increasing importance.…

Quantum Physics · Physics 2024-07-09 Sourav Nandy , Markus Schmitt , Marin Bukov , Zala Lenarčič

We introduce a systematic classification method for the analogs of phase transitions in finite systems. This completely general analysis, which is applicable to any physical system and extends towards the thermodynamic limit, is based on…

Statistical Mechanics · Physics 2015-05-28 Stefan Schnabel , Daniel T. Seaton , David P. Landau , Michael Bachmann

An effective set of the Hartree-Fock (HF) equations are derived for electrons of the muonic systems, i.e., molecules containing a positively charged muon, conceiving the muon as a quantum oscillator, which are completely equivalent to the…

Atomic and Molecular Clusters · Physics 2018-02-12 Milad Rayka , Mohammad Goli , Shant Shahbazian

We present a simple and efficient method to incorporate anharmonic effects in the vibrational \textcolor{black}{analyses} of molecules within density functional theory (DFT) calculations. This approach is closely related to the traditional…

We propose a novel quantum Monte Carlo method in configuration space, which stochastically samples the contribution from a large secondary space to the effective Hamiltonian in the energy dependent partitioning of L\"owdin. The method…

Chemical Physics · Physics 2015-06-15 Seiichiro Ten-no

We apply the concept of a frequency-dependent effective temperature based on the fluctuation-dissipation ratio to a driven Brownian particle in a nonequilibrium steady state. Using this system as a thermostat for a weakly coupled harmonic…

Statistical Mechanics · Physics 2017-06-07 Robert Wulfert , Michael Oechsle , Thomas Speck , Udo Seifert

We propose a feasible and effective approach to study quantum thermal transport through anharmonic systems. The main idea is to obtain an {\it effective} harmonic Hamiltonian for the anharmonic system by applying the self-consistent phonon…

Statistical Mechanics · Physics 2016-10-19 Dahai He , Juzar Thingna , Jian-Sheng Wang , Baowen Li

The microscopic wave functions of the composite fermion theory can incorporate electron mass anisotropy by a trivial rescaling of the coordinates. These wave functions are very likely adiabatically connected to the actual wave functions of…

Strongly Correlated Electrons · Physics 2016-02-11 Ajit C. Balram , J. K. Jain

We discuss the potential advantages of calculating the effective mass of quasiparticles in the interacting electron liquid from the low-temperature free energy vis-a-vis the conventional approach, in which the effective mass is obtained…

Strongly Correlated Electrons · Physics 2017-07-26 F. G. Eich , Markus Holzmann , G. Vignale

We apply the effective potential analytic continuation (EPAC) method to one-dimensional asymmetric potential systems to obtain the real time quantum correlation functions at various temperatures. Comparing the EPAC results with the exact…

Quantum Physics · Physics 2009-11-10 Atsushi Horikoshi , Kenichi Kinugawa

A kink-based expression for the canonical partition function is developed using Feynman's path integral formulation of quantum mechanics and a discrete basis set. The approach is exact for a complete set of states. The method is tested on…

Statistical Mechanics · Physics 2009-11-07 Randall W. Hall

A time-dependent unitary (canonical) transformation is found which maps the Hamiltonian for a harmonic oscillator with time-dependent real mass and real frequency to that of a generalized harmonic oscillator with time-dependent real mass…

Quantum Physics · Physics 2009-10-30 Ali Mostafazadeh

An efficient Path Integral Monte Carlo procedure is proposed to simulate the behavior of quantum many-body dissipative systems described within the framework of the influence functional. Thermodynamic observables are obtained by Monte Carlo…

Statistical Mechanics · Physics 2009-11-07 Luca Capriotti , Alessandro Cuccoli , Andrea Fubini , Valerio Tognetti , Ruggero Vaia

The goal of this paper is to review several qualitative properties of well-known eigenvalue problems using a different perspective based on the theory of effective Hamiltonians, working exclusively on the Hopf-Cole transform of the…

Analysis of PDEs · Mathematics 2025-06-06 Idriss Mazari-Fouquer

A local embedding and effective downfolding scheme has been developed and implemented in the auxiliary-field quantum Monte Carlo (AFQMC) method. A local cluster in which electrons are fully correlated is defined and the frozen orbital…

Strongly Correlated Electrons · Physics 2019-07-24 Brandon Eskridge , Henry Krakauer , Shiwei Zhang